Curable prepregs with surface openings

Patent metadata

Field	Value
Publication number	US-9802358-B2
Application number	US-201314135866-A
Country	US
Kind code	B2
Filing date	Dec 20, 2013
Priority date	Dec 21, 2012
Publication date	Oct 31, 2017
Grant date	Oct 31, 2017

Abstract

Curable prepregs possessing enhanced ability for the removal of gases from within prepregs and between prepreg plies in a prepreg layup prior to and/or during consolidation and curing. Each curable prepreg is a resin-impregnated, woven fabric that has been subjected to a treatment to create an array of openings in at least one major surface. Furthermore, the location of the openings is specific to the weave pattern of the fabric.

First claim

What is claimed is:

1. A curable prepreg comprising:
a woven fabric having two opposing faces and a weaving pattern in which one or more tows in a first weaving direction float over one or more tows in a second weaving direction, then pass under one or more tows in the second weaving direction;
wherein a pocket is defined in the fabric surface when a first tow in the first weaving direction passes over a second tow in the second weaving direction then under an adjacent third tow in the second weaving direction, or when the first tow passes under a second tow in the second weaving direction then over an adjacent third tow in the second weaving direction, and the pocket location is at a crossover under location in the weaving pattern, wherein the crossover/under location is defined by the portion of the first tow that is going up or going, down between the adjacent second and third tows
a curable, hot-melt resin film substantially covering one or both face(s) of the fabric and penetrating partially through the thickness of the fabric leaving an inner section of the fabric, in the thickness direction, substantially free of the resin film; and
an array of openings in the one or both resin film(s), each opening exposing a single pocket in the fabric surface at a single crossover/under location and configured to create a fluid flow path from the inner section of the fabric to at least one outer surface of the prepreg, or from at least one outer surface of the prepreg to the inner section, or from one outer surface of the prepreg to an opposite outer surface, or combination thereof.

2. The curable prepreg of claim 1 , wherein the weaving pattern of the woven fabric is satin weave or twill weave.

3. The curable prepreg of claim 1 , wherein the weaving pattern is satin weave, and the openings are formed through one or both surfaces of the prepreg.

4. The curable prepreg of claim 1 , wherein the hot-melt resin film is substantially solid at a temperature within the range of 20° C.−25° C. and becomes flowable at an elevated temperature below an onset curing temperature of the resin film.

5. The curable prepreg of claim 1 , wherein the hot-melt resin film comprises one or more thermoset resins as a major component, and is substantially free of any organic solvent.

6. The curable prepreg of claim 1 , wherein the hot-melt resin film comprises one or more epoxy resins, a curing agent, and at least one thermoplastic or elastomeric compound.

7. The curable prepreg of claim 1 , wherein each tow comprises a plurality of fiber filaments, which are formed of a material selected from: glass, carbon, aramid, polyethylene (PE), boron, quartz, basalt, ceramic, polyester, poly-p-phenylene-benzobisoxazole (PBO), and combinations thereof.

8. The curable prepreg of claim 1 , wherein the openings are substantially circular in cross-section with diameter within the range of 0.1-3 mm.

9. The curable prepreg of claim 1 , wherein the openings are approximately rectangular in cross-section with width and length within the range of 0.1 mm-3 mm.

10. A curable prepreg with an array of surface openings formed by a method comprising:
(a) partially impregnating a woven fabric with a curable, hot-melt resin such that a continuous resin film covers each face of the fabric and penetrates partially through the thickness of the fabric leaving an inner section of the fabric, in the thickness direction, substantially free of said resin,
wherein the woven fabric has two opposing faces and a weaving pattern in which one or more tows in a first weaving direction float over one or more tows in a second weaving direction, then pass under one or more tows in the second weaving direction,
wherein a pocket is defined in a face of the fabric when a first tow in the first weaving direction passes over a second tow in the second weaving direction then under an adjacent third tow in the second weaving direction, or when the first tow passes under a second tow in the second weaving direction then over an adjacent third tow, and the pocket location is at a crossover/under location in the weaving pattern, wherein the crossover/under location is defined by the portion of the first tow that is going up or going down between the adjacent second and third tows, and
wherein the partially impregnated fabric comprises a plurality of enclosed air pockets, each air pocket coincides with a pocket in the fabric; and
(b) heating the partially impregnated fabric so that the resin film on at least one face of the fabric becomes flowable, and subsequently, portions of the resin film over the air pockets break open, thereby creating openings in the resin film that correspond to locations of the air pockets, wherein each opening exposes a single pocket in the face of the fabric at a single crossover/under location,
wherein the openings are configured to provide fluid flow paths from the inner section of the fabric to at least one outer surface of the prepreg, or from at least one outer surface of the prepreg to the inner section, or from one outer surface of the prepreg to an opposite outer surface, or combination thereof.

11. The curable prepreg of claim 10 , wherein the weaving pattern of the woven fabric is satin weave or twill weave.

12. The curable prepreg of claim 10 , wherein the weaving pattern is satin weave, and the openings are formed through one or both surfaces of the prepreg.

13. A method for fabricating a curable composite material with an array of surface openings, the method comprising:
(a) partially impregnating a woven fabric with a curable, hot-melt resin such that a continuous resin film covers each face of the fabric and penetrates partially through the thickness of the fabric leaving an inner section of the fabric, in the thickness direction, substantially free of said resin,
wherein the woven fabric has two opposing faces and a weaving pattern in which one or more tows in a first weaving direction pass over one or more tows in a second weaving direction, then pass under one or more tows in the second weaving direction
wherein a pocket is defined on a face of the fabric when a first tow in the first weaving direction passes a second tow in the second weaving direction then under an adjacent third tow in the second weaving direction, or when the first tow passes under a second tow in the second weaving direction then over an adjacent third tow, and the pocket location is at a crossover/under location in the weaving pattern, wherein the crossover/under location is defined by the portion of the first tow that is going up or going down between the adjacent second and third tows, and
wherein the partially impregnated fabric comprises a plurality of enclosed air pockets, each air pocket coincides with a pocket in the fabric surface; and
(b) heating the partially impregnated fabric so that the resin film on at least one face of the fabric becomes flowable, and subsequently, portions of the resin film over the air pockets break open, thereby creating openings in the resin film that correspond to locations of the expanded air pockets, wherein each opening exposes a single pocket in the face of the fabric at a single crossover/under location,
wherein the openings are configured to provide fluid flow paths from the inner section of the fabric to at least one outer surface of the composite material or from at least one outer surface of the composite material to the inner section, or from one outer surface of the composite material to an opposite surface, or combination thereof.

14. The method of claim 13 , wherein the outer surface of the resin film is covered with a release paper or polyester film dur

Assignees

• Cytec Ind Inc

Inventors

• Roman Mark
• Howard Stephen J
• Boyd Jack D

Classifications

• B32B5/28

  impregnated with or embedded in a plastic substance {(not used)} · CPC title

• B32B2255/02

  on fibrous or filamentary layer · CPC title

• Y10T442/2926

  Coated or impregnated inorganic fiber fabric · CPC title

• B32B2262/101

  Glass fibres · CPC title

• D03D13/00

  Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft · CPC title