Method for producing graphene

Patent metadata

Field	Value
Publication number	US-9802206-B2
Application number	US-201314401533-A
Country	US
Kind code	B2
Filing date	May 24, 2013
Priority date	May 30, 2012
Publication date	Oct 31, 2017
Grant date	Oct 31, 2017

Abstract

A dispersion of suspended single-layer graphene, multilayer graphene, and graphite is used. A magnetic field is applied to the dispersion to separate the single-layer graphene from the dispersion. By applying the magnetic field, the single-layer graphene, the multilayer graphene, and the graphite are situated at different locations in solvent by the difference in the diamagnetism strengths of the single-layer graphene, the multilayer graphene, and the graphite.

First claim

The invention claimed is:

1. A method for producing graphene, the method comprising:
applying a magnetic field using magnet to a dispersion comprising graphene, graphite, and a solvent, in a container, and locating the graphene and the graphite at different locations in the dispersion from each other; and
separating the graphene from the dispersion comprising the graphite by removing the graphene with the solvent from the dispersion,
wherein the graphene comprises single-layer graphene and multilayer graphene having in a range from two to 10 graphite layers, and the graphite is graphite having 11 or more graphite layers.

2. The method for producing graphene according to claim 1 ,
wherein the applying the magnetic field is performed by using a difference in diamagnetism strengths between the graphene and the graphite.

3. The method for producing graphene according to claim 1 ,
wherein, by the applying the magnetic field, the graphene is located in a region in the dispersion where the magnetic field is weak, and the graphite is located in a region in the dispersion where the magnetic field is strong.

4. The method for producing graphene according to claim 1 ,
wherein the applying the magnetic field is performed by applying the magnetic field from underneath of the container and distributing the graphite and the graphene vertically in this order from a bottom to a top of the container.

5. The method for producing graphene according to claim 1 ,
wherein a location of the graphene to be removed with the solvent in the separating the graphene is determined by strength of the magnetic field applied in the applying the magnetic field and buoyant force of the graphene used therein.

6. The method for producing graphene according to claim 1 ,
wherein the magnetic field applied in the applying thereof has magnetic force in a range of 0.05 tesla or more and less than 5tesla.

7. The method for producing graphene according to claim 1 ,
wherein the graphene and the graphite have been produced by pulverizing primary graphite.

8. The method for producing graphene according to claim 7 ,
wherein the pulverizing the primary graphite comprises: primary pulverizing so as to form a coarse powder of the primary graphite; and further secondary pulverizing the coarse powder into a fine powder of the primary graphite.

9. The method for producing graphene according to claim 8 ,
wherein the primary pulverizing is performed with a jet mill.

10. The method for producing graphene according to claim 7 , further comprising fractionating a powder of the pulverized primary graphite in an airflow so as to obtain the graphene and the graphite.

11. The method for producing graphene according to claim 1 ,
wherein in the applying of the magnetic field, the magnetic field is applied from underneath the container, and the graphene and the graphite are located at vertically different locations in the dispersion from each other.

12. The method for producing graphene according to claim 11 ,
wherein by the applying of the magnetic field using magnet to the dispersion, the graphene is located where gravity of the graphene, buoyant force of the graphene, and strength of the magnetic field are balanced, and is located at a different location from a location of the graphite, where gravity of the graphite, buoyant force of the graphite, and the strength of the magnetic field are balanced.

13. A method for producing graphene, the method comprising:
applying a magnetic field using magnet to a dispersion comprising: (i) a combination of single-layer graphene and multilayer graphene having in a range from two to 10 graphite layers; (ii) graphite having 11 or more graphite layers; and (iii) a solvent, in a container, and locating the single-layer graphene, the multilayer graphene, and the graphite at different locations in the dispersion from each other; and
separating at least one material selected from the group consisting of the single-layer graphene and the multilayer graphene, from the dispersion comprising the graphite by removing the at least one material with the solvent from the dispersion.

Assignees

• Panasonic Ip Man Co Ltd

Inventors

• Kitaura Hidetoshi
• Nishiki Naomi
• Nishikawa Kazuhiro
• Nakaya Kimiaki
• Tanaka Atsushi

Classifications

• C01B32/21

  After-treatment · CPC title

• C01B2204/02

  Single layer graphene · CPC title

• C01B32/184 Primary

  Preparation · CPC title

• C01B32/19

  by exfoliation · CPC title

• B02C23/08

  Separating or sorting of material, associated with crushing or disintegrating (B02C23/18 takes precedence {; beater mills combined with sifting devices B02C13/13, B02C13/14; for tumbling mills B02C17/1835}) · CPC title