Reactor for homogeneous regeneration of spent ionic liquid

Patent metadata

Field	Value
Publication number	US-9802186-B2
Application number	US-201615010236-A
Country	US
Kind code	B2
Filing date	Jan 29, 2016
Priority date	Jan 29, 2016
Publication date	Oct 31, 2017
Grant date	Oct 31, 2017

Abstract

We provide a segmented reactor for regenerating a spent acidic ionic liquid via hydrogenation and hydrocracking, comprising: no solid hydrogenation catalyst; a gas inlet for feeding a gas feed comprising a hydrogen; a liquid inlet for feeding a spent acidic ionic liquid; partitions along an axis of the reactor that create segments, wherein each segment functions as a bubble column reactor; and an outlet from which a regenerated acidic ionic liquid flow out of the segmented reactor. We also provide a process for regenerating a spent acidic ionic liquid, comprising contacting the spent acidic ionic liquid with hydrogen and without an addition of a solid hydrogenation catalyst in the segmented reactor.

First claim

It is claimed:

1. A segmented reactor for regenerating a spent acidic ionic liquid via a hydrogenation and a hydrocracking, comprising: no solid hydrogenation catalyst; a gas inlet for feeding a gas feed comprising a hydrogen; a liquid inlet for feeding a spent acidic ionic liquid; partitions along an axis of the segmented reactor that create segments, wherein each segment functions as a bubble column reactor; and an outlet from which a regenerated acidic ionic liquid flows out of the segmented reactor.

2. The segmented reactor of claim 1 , wherein the axis is vertical.

3. The segmented reactor of claim 1 , wherein the gas inlet and the liquid inlet are at the bottom of the segmented reactor and the outlet is above the bottom of the segmented reactor.

4. The segmented reactor of claim 1 , wherein the gas feed and the spent acidic ionic liquid flow upwardly through the segmented reactor and do not flow back from an upper segment to a lower segment in the segmented reactor.

5. The segmented reactor of claim 1 , wherein openings in the partitions provide a high gas-liquid velocity of at least 10 mm/s.

6. The segmented reactor of claim 1 , wherein the partitions in the segmented reactor provide an overall plug flow pattern in the reactor.

7. The segmented reactor of claim 1 , wherein the partitions are the only internals in the segmented reactor.

8. The segmented reactor of claim 1 , wherein the partitions are perforated plates.

9. The segmented reactor of claim 1 , wherein the partitions have openings that are 0.1 to 2.5 cm in diameter.

10. The segmented reactor of claim 1 , wherein a layer of a particulate filter medium that is 2.5 to 15 cm thick and having a pore size greater than 0.005 cm is placed at the top of one or more of the partitions, wherein the layer removes solid impurities in the system and improves the dispersion of gas bubbles.

11. The segmented reactor of claim 1 , wherein the partitions distribute gas bubbles uniformly across an entire cross-section of the segmented reactor.

12. The segmented reactor of claim 1 , wherein the partitions are inserted into a conventional bubble column reactor.

13. The segmented reactor of claim 1 , additionally comprising a vent at the top of the segmented reactor that collects paraffinic light gases that are formed during a contacting of the hydrogen and the spent acidic ionic liquid.

14. The segmented reactor of claim 1 , additionally comprising a level control valve or a lateral effluent outlet, which maintains a steady level of a liquid in the segmented reactor.

15. The segmented reactor of claim 1 , additionally comprising a temperature controller that maintains a temperature in the segmented reactor from 100° C. to 350° C.

16. The segmented reactor of claim 1 , additionally comprising a pressure controller that maintains a pressure in the segmented reactor from 50 to 5000 psig (446 to 34600 kpa).

17. The segmented reactor of claim 1 , additionally comprising a fluid connection between the outlet that elutes the regenerated acidic ionic liquid and an alkylation reactor outlet, wherein an extracted conjunct polymer naphtha produced in the segmented reactor is mixed with an alkylate gasoline made in an alkylation reactor, to make a blended alkylate gasoline.

18. The segmented reactor of claim 1 , additionally comprising a recycle loop that feeds the regenerated acidic ionic liquid back to a hydrocarbon conversion reactor that produced the spent acidic ionic liquid.

19. A process for regenerating a spent acidic ionic liquid via a hydrogenation and a hydrocracking, comprising contacting the spent acidic ionic liquid with a hydrogen and without an addition of a solid hydrogenation catalyst in a segmented reactor defined by claim 1 , comprising multiple segments wherein each of the multiple segments functions as a bubble column reactor; and wherein a concentration of a conjunct polymer in the spent acidic ionic liquid is decreased to produce a regenerated acidic ionic liquid.

20. The process of claim 19 , wherein paraffinic light gases are formed during the contacting.

Assignees

• Chevron Usa Inc

Inventors

• Luo Huping
• Girgis Michael John
• Timken Hye-Kyung

Classifications

• B01J38/10

  using elemental hydrogen · CPC title

• B01J31/0277

  comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature · CPC title

• B01J31/40 Primary

  Regeneration or reactivation · CPC title

• B01J31/0284

  of an aromatic ring, e.g. pyridinium · CPC title

• B01J31/0288

  Phosphorus · CPC title