Lithium battery

Patent metadata

Field	Value
Publication number	US-9799922-B2
Application number	US-201313975548-A
Country	US
Kind code	B2
Filing date	Aug 26, 2013
Priority date	Sep 13, 2012
Publication date	Oct 24, 2017
Grant date	Oct 24, 2017

Abstract

A lithium battery including a negative electrode including a lithium metal or a lithium alloy; a positive electrode; and a polymer gel electrolyte contacting the negative electrode, wherein the polymer gel electrolyte has an ionic conductivity of about 10 −3 S/cm or greater, a lithium ion transference number of about 0.15 or greater, and a lithium ion mobility of about 10 −6 cm 2 /V×sec or greater, wherein the polymer gel electrolyte includes a lithium salt, a polymer capable of forming a complex with the lithium salt, an insulating inorganic filler, and an organic solvent, wherein the organic solvent is inert with respect to the lithium metal, wherein an anionic radius of the lithium salt is about 2.5 Angstroms or greater, and wherein a molecular weight of the lithium salt is about 145 or greater.

First claim

What is claimed is:

1. A lithium air battery comprising:
a negative electrode comprising a lithium metal or a lithium alloy;
a positive electrode comprising air as a positive electrode material; and
a polymer gel electrolyte contacting the negative electrode,
wherein the polymer gel electrolyte has
an ionic conductivity of 10 −3 Siemens/centimeter or greater,
a lithium ion transference number of 0.15 or greater, and
a lithium ion mobility of 10 −6 centimeters 2 /Volt×second or greater,

wherein the polymer gel electrolyte comprises
a lithium salt,
a polymer capable of forming a complex with the lithium salt,
an insulating inorganic filler, and
a non-carbonate organic solvent,

wherein the organic solvent is at least one selected from 1,4-dioxane, triethylamine, 1,2-dimethoxymethane, diethyl ether, diglyme, triglyme, tetrahydropyran, diisopropyl ether, tetraglyme, 1,3-dioxolane, tetrahydrofuran, 2-methyltetrahydrofuran, 2,2-dimethyltetrahydrofuran, 2,5-dimethyltetrahydrofuran, hexamethylphosphoric triamide, o-dimethoxybenzene, tetraglyme, anisole, N, N-diethyl acetamide, and tetramethylurea,
wherein an anionic radius of the lithium salt is 2.5 Angstroms or greater,
wherein a molecular weight of all of the lithium salt is 145 or greater, and
wherein a viscosity of a solution of the lithium salt in the organic solvent is about 0.02 Pascal×second or less at a concentration of the lithium salt of 1.5 moles per liter or less and at a temperature of 21° C.,
wherein the positive electrode is free of TiS 2 , LiMnO 2 , LiMn 2 O 4 , V 2 O 5 , CoS x (wherein, 0.8<x<4.5), NiS x (wherein, 0.8<x<4.5), V 3 O 16 , FeS, and FeS 2 .

2. The lithium air battery of claim 1 , wherein a reduction potential of the organic solvent in a liquid state with respect to the lithium metal is −0.5 Volts or less.

3. The lithium air battery of claim 1 , wherein the polymer gel electrolyte comprises PEO 18 Li(CF 3 SO 2 ) 2 N.

4. The lithium air battery of claim 1 , wherein an ionic conductivity of the organic solvent is 0.18 milliSiemens/centimeter or greater at a concentration of the lithium salt of 1.5 moles per liter or less and at a temperature of 21° C.

5. The lithium air battery of claim 1 , wherein the lithium salt is at least one selected from Li(FSO 2 ) 2 N, Li(CF 3 SO 2 ) 2 N, Li(C 2 F 5 SO 2 ) 2 N, LiN(C p F 2p+1 SO 2 )(C q F 2q+1 SO 2 ) (wherein p and q are different from each other, and p and q are each independently an integer of 1 to 20), LiN((SO 2 ) 2 C p F 2p ) (wherein, p is an integer of 1 to 10), Li(C 6 F 5 SO 2 ) 2 N, Li(C 10 F 7 SO 2 ) 2 N, Li(C 6 F 5 SO 2 )(C 10 F 7 SO 2 )N, LiN(C 6 F 5 SO 2 )(C p F 2p+1 SO 2 ) (wherein, p is an integer of 1 to 10), LiN(C 10 F 7 SO 2 )(C p F 2p+1 SO 2 ) (wherein, p is an integer of 1 to 10), LiC 4 F 9 SO 3 , Li(CF 3 SO 2 ) 3 C, Li(C 6 H 5 ) 4 B, and LiC 4 BO 8 .

6. The lithium air battery of claim 1 , wherein the polymer is at least one selected from a polyethylene oxide, a polypropylene, a polyacrylonitrile, a polyvinylidene-fluoride, and a polymethylmethacrylate.

7. The lithium air battery of claim 1 , wherein a molecular weight of the polymer is about 1×10 5 to about 1×10 7 .

8. The lithium air battery of claim 1 , wherein a diameter of the insulating inorganic filler is about 100 nanometers or less.

9. The lithium air battery of claim 1 , wherein an amount of the insulating inorganic filler is about 10 weight % or less based on a total weight of the polymer and the inorganic filler.

10. The lithium air battery of claim 1 , wherein the insulating inorganic filler is at least one selected from SiO 2 , BaTiO 3 , TiO 2 , Al 2 O 3 , and Li 2 CO 3 .

11. The lithium air battery of claim 1 , wherein
an ionic conductivity of the polymer gel electrolyte is about 2×10 −3 Siemens/centimeter or greater,
a lithium ion transference number is about 0.16 or greater, and
a lithium ion mobility is about 1.1×10 −6 centimeters 2 /Volt×second or greater.

12. The lithium air battery of claim 1 , further comprising a separator disposed between the positive electrode and the negative electrode.

13. The lithium air battery of claim 1 , wherein the positive electrode and the negative electrode each comprise the lithium metal and an overpotential of the lithium battery is about 0.2 Volts or less after 100 cycles of charge and discharge under a condition of a constant current of about 3 milliAmpere/centimeter 2 for about 4 hours per charge or discharge at a temperature of about 60° C.

Assignees

• Samsung Electronics Co Ltd
• Nat Univ Corp Mie Univ

Inventors

• Park Min-Sik
• Lee Dong-Joon
• Ma Sang-Bok
• Im Dong-Min
• Choi Won-Sung
• Yamamoto Osamu
• Imanishi Nobuyuki

Classifications

• Y02T10/7011

  Cross-Sectional Technologies · mapped topic

• H01M10/052

  Li-accumulators · CPC title

• H01M10/0565 Primary

  Polymeric materials, e.g. gel-type or solid-type · CPC title

• H01M4/38

  of elements or alloys · CPC title

• H01M10/0566

  Liquid materials · CPC title