High efficiency photovoltaic device employing cadmium sulfide telluride and method of manufacture

Patent metadata

Field	Value
Publication number	US-9799784-B2
Application number	US-201414209740-A
Country	US
Kind code	B2
Filing date	Mar 13, 2014
Priority date	Mar 15, 2013
Publication date	Oct 24, 2017
Grant date	Oct 24, 2017

Abstract

A photovoltaic device is disclosed including at least one Cadmium Sulfide Telluride (CdS x Te 1−x ) layer as are methods of forming such a photovoltaic device.

First claim

What is claimed is:

1. A photovoltaic device, comprising:
a buffer layer over a front contact, wherein the buffer layer comprises metal oxide; and
a CdS x Te 1−x layer between the buffer layer and a back contact, wherein x is greater than 0 and less than 1, wherein x changes over a thickness of the CdS x Te 1−x layer such that x is larger where the CdS x Te 1−x layer is nearer the front contact and x is smaller where the CdS x Te 1−x layer is nearer the back contact,
and wherein the photovoltaic device does not include a separate semiconductor absorber layer or a separate semiconductor window layer between the buffer layer and CdS x Te 1−x layer; and
a p-n junction between the buffer layer and the CdS x Te 1−x layer,
wherein the CdS x Te 1−x layer functions as a p-type absorber layer.

2. The photovoltaic device of claim 1 , wherein the CdS x Te 1−x layer is graded in sulfur and tellurium content over a thickness of the CdS x Te 1−x layer in a step-wise fashion.

3. The photovoltaic device of claim 1 , wherein the CdS x Te 1−x layer is graded in sulfur and tellurium content over a thickness of the CdS x Te 1−x layer in a gradual fashion.

4. The photovoltaic device of claim 1 , wherein the CdS x Te 1−x layer is a copper-doped CdS x Te 1−x layer.

5. The photovoltaic device of claim 1 , further comprising a semiconductor absorber layer between the CdS x Te 1−x layer and the back contact.

6. The photovoltaic device of claim 5 , wherein x is between about 0.01 to about 0.30.

7. The photovoltaic device of claim 5 , wherein the semiconductor absorber layer comprises sulfur provided by the CdS x Te 1−x layer.

8. The photovoltaic device of claim 5 , wherein the CdS x Te 1−x layer is a copper-doped CdS x Te 1−x layer.

9. The photovoltaic device of claim 5 , further comprising an additional sulfur-containing layer.

10. The photovoltaic device of claim 9 , wherein the additional sulfur-containing layer is positioned between the CdS x Te 1−x layer and the semiconductor absorber layer.

11. The photovoltaic device of claim 9 , wherein the additional sulfur-containing layer is positioned within the semiconductor absorber layer.

12. The photovoltaic device of claim 9 , wherein the additional sulfur-containing layer is positioned between the semiconductor absorber layer and the back contact.

13. The photovoltaic device of claim 9 , wherein x is between about 0.05 and 0.5.

14. The photovoltaic device of claim 9 , wherein the additional sulfur-containing layer comprises a material selected from the group consisting of: CdS, ZnS, ZnO x S y , and CdS x2 Te 1−x2 , where x2 <x.

15. A method forming a photovoltaic device, comprising:
depositing a CdS x Te 1−x layer over a buffer layer of a TCO stack deposited on a substrate, wherein the buffer layer comprises a metal oxide, whereby a separate semiconductor absorber layer or a separate semiconductor window layer is not disposed between the buffer layer and CdS x Te 1−x layer, wherein a p-n junction forms between the buffer layer and the CdS x Te 1−x layer, whereby the CdS x Te 1−x layer functions as a p-type absorber layer, wherein x is greater than 0 and less than 1, and wherein x changes over a thickness of the CdS x Te 1−x layer such that x is larger where the CdS x Te 1−x layer is nearer the front contact and x is smaller where the CdS x Te 1−x layer is nearer the back contact; and
depositing a semiconductor absorber layer over the CdS x Te 1−x layer;
wherein the CdS x Te 1−x layer and the semiconductor absorber layer are deposited using a vapor transport deposition (VTD) coater, and wherein the VTD coater has heater temperature settings such that a conveyance zone prior to a first distribution zone in which the CdS x Te 1−x layer is deposited, relative to a direction of movement of the substrate, has a higher temperature at a center of the conveyance zone and a lower temperature at sides of the conveyance zone.

16. The method of claim 15 , wherein the VTD coater has heater temperature settings such that a pre-heat zone located prior to the conveyance zone, relative to the direction of movement of the substrate, has a higher temperature at a center of the pre-heat zone and a lower temperature at sides of the pre-heat zone.

17. The method of claim 16 , wherein the temperature at the center of the conveyance zone is about 600° C. and the temperature at the sides of the conveyance zone is about 510° C., and wherein the temperature at the center of the pre-heat zone is about 625° C. and the temperature at the sides of the pre-heat zone is about 535° C.

18. The method of claim 17 , wherein a temperature at sides of the first distribution zone is about 640° C. and a temperature at a center of the first distribution zone is about 610° C.

19. The method of claim 18 , wherein the absorber layer is deposited at a second distribution zone, located after the first distribution zone, and wherein a temperature at sides of the second distribution zone is about 640° C. and a temperature at a center of the second distribution zone is about 610° C.

20. The method of claim 16 , wherein the VTD coater further has heater temperature settings such that the temperature at the sides of the pre-heat zone is varied, along the direction of movement of the substrate.

21. The method of claim 20 , wherein the temperature at the sides of the pre-heat zone is varied, along the direction of movement of the substrate, to be about 525° C., about 575° C., about 650° C., and about 675° C., in order, and the temperature at the center of the pre-heat zone is about 650° C.

22. The method of claim 15 , wherein the VTD coater further has heater temperature settings such that the temperature at the center of the conveyance zone is varied, along the direction of movement of the substrate.

23. The method of claim 22 , wherein the temperature at the center of the conveyance zone is varied, along the direction of movement of the substrate, to be about 560° C., about 590° C., about 650° C., and about 600° C., in order, and the temperatures at the sides of the conveyance zone are about 550° C.

24. The method of claim 15 , wherein the absorber layer is deposited at a third distribution zone, located after the first distribution zone of the coater, and wherein a temperature at sides of the third distribution zone is about 630° C. and a at a center of the third distribution zone is about 600° C.

25. The method of claim 24 , further comprising a fourth distribution zone, wherein the absorber layer is deposited at both the third and fourth distribution zones, and wherein a temperature at sides of the fourth distribution zone is about 630° C. and a at a center of the fourth distribution zone is about 600° C.

26. The photovoltaic device of claim 1 , wherein the metal oxide is selected from the group consisting of: tin oxide, zinc oxide, and combinations thereof.

Assignees

• First Solar Inc
• First Solar Inc

Inventors

• Allenic Arnold
• Ban Zhigang
• Buller Benyamin
• Gloeckler Markus
• Milliron Benjamin
• Peng Xilin
• Powell Rick C
• Trivedi Jigish
• Varghese Oomman K
• Wang Jianjun
• Zhao Zhibo

Classifications

• H01L31/073

  Electricity · mapped topic

• H01L31/03925

  Electricity · mapped topic

• Y02E10/543

  Solar cells from Group II-VI materials · CPC title

• H01L31/02963

  Electricity · mapped topic

• H01L31/0296 Primary

  Electricity · mapped topic