Pyroelectric detector using graphene electrode

Patent metadata

Field	Value
Publication number	US-9797779-B2
Application number	US-201415101196-A
Country	US
Kind code	B2
Filing date	Dec 5, 2014
Priority date	Dec 5, 2013
Publication date	Oct 24, 2017
Grant date	Oct 24, 2017

Abstract

Graphene and ferroelectric materials are used as tunable sensors for detecting and measuring radiation, such as infrared radiation. The low absorption and reflectance of graphene and interconnected graphene networks, for example in the infrared, are exploited for use in such tunable sensors. The active layer makes use of a unique property of ferroelectric materials, known as the pyroelectric effect, for measuring the intensity of impinging radiation. Using graphene electrodes may offer a significant increase in sensitivity, tunability and mechanical flexibility of sensors, such as infrared sensors. In one method, intensity of radiation is measured using variations in the doping level of the graphene electrode.

First claim

What is claimed is:

1. A pyroelectric detector configured to measure intensity of at least one wavelength of electromagnetic radiation impinging on the pyroelectric detector, the detector comprising:
at least one pyroelectric active layer configured to undergo a reorientation of dipoles in response to the at least one wavelength of the electromagnetic radiation; and
at least one graphene electrode transparent to the at least one wavelength of the electromagnetic radiation,
the at least one pyroelectric active layer configured to directly absorb the at least one wavelength of the electromagnetic radiation, the at least one wavelength having been transmitted through the at least one graphene electrode transparent to the at least one wavelength of the electromagnetic radiation.

2. The pyroelectric detector of claim 1 , further comprising:
at least one back substrate.

3. The pyroelectric detector of claim 2 , wherein the at least one back substrate comprises a transparent and flexible material.

4. The pyroelectric detector of claim 3 , wherein the at least one back substrate comprises polyethylene terephthalate.

5. The pyroelectric detector of claim 2 , further comprising a conductive coating on the at least one back substrate.

6. The pyroelectric detector of claim 5 , wherein the conductive coating comprises a conductive coating transparent to the at least one wavelength of the electromagnetic radiation.

7. The pyroelectric detector of claim 5 , wherein the conductive coating comprises a conductive coating that is reflective of the at least one wavelength of the electromagnetic radiation.

8. The pyroelectric detector of claim 1 , wherein the at least one graphene electrode comprises at least one of: single layer graphene, bilayer graphene, multilayer graphene, reduced graphene oxide, graphene platelets, and an interconnected graphene network.

9. The pyroelectric detector of claim 8 , wherein the at least one graphene electrode comprises an interconnected graphene network, and wherein the interconnected graphene network comprises at least one of: (i) a graphene foam and (ii) a graphene array.

10. The pyroelectric detector of claim 1 , wherein the at least one pyroelectric layer comprises at least one of: (i) polyvinylidene fluoride and (ii) a copolymer of polyvinylidene fluoride.

11. The pyroelectric detector of claim 1 , wherein the at least one pyroelectric layer comprises lead zirconium titanate.

12. The pyroelectric detector of claim 1 , wherein the at least one graphene electrode comprises a graphene foam, wherein the at least one pyroelectric active layer comprises a surrounding coating on at least a portion of the graphene foam, and wherein the detector comprises an outer conducting layer surrounding the at least a portion of the at least one pyroelectric active layer.

13. The pyroelectric detector of claim 1 , wherein the at least one graphene electrode is configured to undergo a change in sheet resistance in response to the at least one wavelength of the electromagnetic radiation.

14. The pyroelectric detector of claim 13 , further comprising:
a voltage source configured to pass a current across a surface of the at least one graphene electrode; and
a voltage probe configured to measure a voltage across the surface of the at least one graphene electrode, the voltage across the surface being proportional to the changed sheet resistance of the at least one graphene electrode.

15. The pyroelectric detector of claim 13 , wherein the detector comprises only one electrode.

16. The pyroelectric detector of claim 13 , wherein the detector comprises:
a substrate transparent to the at least one wavelength of the electromagnetic radiation, the substrate configured to receive the electromagnetic radiation; and
at least one back substrate.

17. The pyroelectric detector of claim 1 , wherein the detector is mechanically flexible.

18. The pyroelectric detector of claim 1 , wherein the detector comprises only one electrode, the electrode being only one graphene electrode,
the only one graphene electrode being configured to undergo a change in sheet resistance in response to the at least one wavelength of the electromagnetic radiation,
the pyroelectric detector further comprising:
a voltage source configured to pass a current across a surface of the at least one graphene electrode;
a voltage probe configured to measure a voltage across the surface of the at least one graphene electrode, the voltage across the surface being proportional to the changed sheet resistance of the at least one graphene electrode.

19. The pyroelectric detector of claim 1 , wherein absorption characteristics of the at least one pyroelectric active layer define a spectral response of the pyroelectric detector.

20. The pyroelectric detector of claim 1 , wherein the at least one wavelength comprises an infrared wavelength.

Assignees

• Nat Univ Singapore

Inventors

• Ozyilmaz Barbaros
• Kulkarni Eeshan Sandeep
• Heussler Sascha Pierre
• Castro Neto Antonio Helio

Classifications

• G01J5/34 Primary

  using capacitors, e.g. pyroelectric capacitors · CPC title

• G01J5/046

  Materials; Selection of thermal materials · CPC title