Heat exchanger, reactor arrangement comprising this heat exchanger and method for controlling the temperature of a reactor

Patent metadata

Field	Value
Publication number	US-9797657-B2
Application number	US-201514661408-A
Country	US
Kind code	B2
Filing date	Mar 18, 2015
Priority date	Mar 18, 2014
Publication date	Oct 24, 2017
Grant date	Oct 24, 2017

Abstract

A heat exchanger ( 1 ) contains: a bundle of at least two heat exchanger tubes ( 3 ), a heat exchanger housing ( 5 ) surrounding the bundle of heat exchanger tubes ( 3 ), wherein a liquid heat-transfer medium ( 7 ) is passed around the bundle of heat exchanger tubes ( 3 ) in the heat exchanger housing ( 5 ), a heat exchanger cap ( 9 ) sealing the top of the heat exchanger housing ( 5 ), a heat exchanger bottom ( 11 ) sealing the bottom of the heat exchanger housing ( 5 ), a feed point ( 13 ) for the heat-transfer medium ( 7 ), an outlet ( 15 ) for the heat-transfer medium ( 7 ), an emergency relief port ( 17 ) disposed in proximity to the heat exchanger cap ( 9 ). The heat exchanger ( 1 ) contains a safety device ( 19 ) disposed in proximity to the heat exchanger bottom ( 11 ).

First claim

The invention claimed is:

1. A heat exchanger ( 1 ), comprising:
a bundle of at least two heat exchanger tubes ( 3 ), wherein the bundle of heat exchanger tubes ( 3 ) has been vertically oriented and is terminated at the bottom by a heat exchanger tube plate ( 31 ),
a heat exchanger housing ( 5 ) surrounding the bundle of heat exchanger tubes ( 3 ), wherein a liquid heat-transfer medium ( 7 ) is passed around the bundle of heat exchanger tubes ( 3 ) in the heat exchanger housing ( 5 ),
a heat exchanger cap ( 9 ) sealing the top of the heat exchanger housing ( 5 ),
a heat exchanger bottom ( 11 ) sealing the bottom of the heat exchanger housing ( 5 ),
a feed point ( 13 ) for the heat-transfer medium ( 7 ), wherein said feed point is provided on the heat exchanger housing ( 5 ) and leads into the heat exchanger ( 1 ),
an outlet ( 15 ) for the heat-transfer medium ( 7 ), wherein said outlet is provided on the heat exchanger housing ( 5 ) and leads out of the heat exchanger ( 1 ),
an emergency relief port ( 17 ) disposed in proximity to the heat exchanger cap ( 9 ),
wherein
the heat exchanger ( 1 ) comprises a safety device ( 19 ) which is essentially a pipe leading out of the heat exchanger housing ( 5 ) in proximity to the heat exchange bottom ( 11 ) and leading essentially vertically upwards such that the safety device reaches at least higher than a liquid level of the liquid heat-transfer medium ( 7 ) in the heat exchanger housing ( 5 ) and wherein the safety device is disposed in proximity to the heat exchanger bottom ( 11 ).

2. The heat exchanger ( 1 ) according to claim 1 , wherein a second safety device ( 19 ) is an emergency depressurization means.

3. The heat exchanger ( 1 ) according to claim 1 , wherein the ratio of a free cross sectional area of the safety device ( 19 ) to a free cross sectional area of a heat exchanger tube ( 3 ) is between 15 and 1600.

4. The heat exchanger ( 1 ) according to claim 1 , wherein the heat exchanger ( 1 ) comprises a containing means ( 21 ) for the heat transfer medium ( 7 ), wherein said containing means is connected downstream of the safety device ( 19 ) or the emergency relief port ( 17 ).

5. The heat exchanger ( 1 ) according to claim 1 , wherein the heat exchanger ( 1 ) comprises a device for removing the liquid heat-transfer medium ( 7 ) from a gaseous phase.

6. The heat exchanger ( 1 ) according to claim 1 , wherein between the safety device ( 19 ) and a containing means ( 21 ) the heat exchanger ( 1 ) comprises a separator ( 23 ) for a portion of the liquid heat-transfer medium ( 7 ).

7. The heat exchanger ( 1 ) according to claim 1 , wherein the heat exchanger ( 1 ) comprises internals ( 25 ) for deflecting the liquid heat-transfer medium ( 7 ) and the internals ( 25 ) are positioned at or between the individual heat exchanger tubes ( 3 ) or at or between the individual heat exchanger tubes ( 3 ) and the heat exchanger housing ( 5 ).

8. The heat exchanger ( 1 ) according to claim 1 , wherein the heat exchanger ( 1 ) is a salt bath heat exchanger or the liquid heat-transfer medium ( 7 ) is a salt melt.

9. A reactor arrangement ( 101 ), comprising:
a reactor ( 27 ),
a heat exchanger ( 1 ) according to claim 1 connected to the reactor ( 27 ),
a pump ( 29 ) for circulating at least some of the liquid heat-transfer medium ( 7 ), wherein said pump is connected to the reactor ( 27 ) or the heat exchanger ( 1 ).

10. The reactor arrangement ( 101 ) according to claim 9 , wherein the reactor ( 27 ) is a shell-and-tube reactor for carrying out exothermic or endothermic reactions.

11. A method for controlling the temperature of a reactor ( 27 ), comprising:
a) introducing, via a feed point, into the heat exchanger ( 1 ) according to claim 1 at least some of a liquid heat-transfer medium ( 7 ) discharged from the reactor ( 27 ) at a first temperature T 1 ,
b) passing the liquid heat-transfer medium ( 7 ) around the heat exchanger tubes ( 3 ) of the heat exchanger ( 1 ) to exchange heat between the heat-transfer medium ( 7 ) and the heat exchanger tubes ( 3 ),
c) draining the liquid heat-transfer medium ( 7 ) from the heat exchanger ( 1 ) at a second temperature T 2 and supplying the liquid heat-transfer medium ( 7 ) to the reactor ( 27 ),
wherein in the event of a pressure increase in the heat exchanger ( 1 ), the overpressure which arises is reduced via at least one safety device ( 19 ) which is essentially a pipe leading out of the heat exchanger housing ( 5 ) in proximity to the heat exchanger bottom ( 11 ) and leading essentially vertically upwards such that the safety device reaches at least higher than a liquid level of the liquid heat-transfer medium ( 7 ) in the heat exchanger housing ( 5 ).

12. The method according to claim 11 , wherein in step b) the heat-transfer medium ( 7 ) meanders between the heat exchanger tubes ( 3 ).

13. The method according to claim 11 , wherein the reactor ( 27 ) is a shell-and-tube reactor for carrying out exothermic or endothermic reactions.

14. The method according to claim 11 , wherein the reaction carried out in the reactor ( 27 ) is a partial gas phase oxidation.

15. The method according to claim 14 , wherein the partial gas phase oxidation comprises the oxidation of propene to acrolein, isobutene to methacrolein, acrolein to acrylic acid, methacrolein to methacrylic acid and o-xylene to phthalic anhydride.

16. A method for cooling a reactor ( 27 ), comprising:
carrying out an exothermic reaction cooling said reactor with the heat exchanger ( 1 ) according to claim 1 , wherein the reactor ( 27 ) is a shell-and-tube reactor and the liquid heat-transfer medium ( 7 ) is a salt melt.

Assignees

• Basf Se

Inventors

• Hammon Ulrich
• Walter Thomas
• Schraut Armin

Classifications

• F28D2021/0022

  for chemical reactors · CPC title

• F28D7/16 Primary

  the conduits being arranged in parallel spaced relation ({F28D7/0008 - F28D7/0058 take precedence}; F28D7/02 - F28D7/10 take precedence) · CPC title

• B01J8/067

  Heating or cooling the reactor (B01J8/062 takes precedence) · CPC title

• F28F27/00 Primary

  Control arrangements or safety devices specially adapted for heat-exchange or heat-transfer apparatus (control arrangements in general G05) · CPC title

• F28D2021/0064

  Vaporizers, e.g. evaporators · CPC title