Method of making corrosion resistant and glossy appearance coating for light metal workpiece

Patent metadata

Field	Value
Publication number	US-9797036-B2
Application number	US-201514670819-A
Country	US
Kind code	B2
Filing date	Mar 27, 2015
Priority date	Apr 8, 2014
Publication date	Oct 24, 2017
Grant date	Oct 24, 2017

Abstract

A metal workpiece, such as a wheel, and a method of providing an enhanced corrosion resistant surface coating on an exposed surface of a metal or alloy substrate (such as magnesium). A corrosion resistance basecoat is formed, including generating an oxide layer, and applying a first primer coating onto at least a portion of the oxide layer. The method may further include identifying highest corrosion prone areas on the substrate and designing a support rack that avoids contact with these corrosion prone areas. The method also includes forming a topcoat over at least a portion of the basecoat, by applying a second primer coating onto at least a portion of the first primer coating and depositing a sputtered metallic film onto the second primer coating using a physical vapor deposition technique. A clear coat layer may be applied over the metallic film.

First claim

What is claimed is:

1. A light metal workpiece with enhanced surface protection, comprising:
a light metal alloy or matrix having an exposed surface;
a corrosion resistance basecoat applied onto at least a portion of the exposed surface, the corrosion resistance basecoat including:
a pretreatment layer comprising an oxide layer having a thickness of from about 5 μm to about 20 μm and an average pore size of from about 0.1 μm to about 5 μm; and
a first primer coating applied onto the pretreatment layer comprising at least one of an electrostatic coating and a powder material coating;

a protective topcoat applied onto at least a portion of the corrosion resistance basecoat, the protective topcoat including:
a second primer coating applied onto the first primer coating comprising at least one of an electrostatic coating and a powder material coating;
a sputtered metallic film applied onto at least a portion of the second primer coating using a physical vapor deposition technique having a thickness of from about 5 nm to about 15 nm; and

a clear coat layer applied onto at least a portion of the metallic film.

2. The light metal workpiece of claim 1 , wherein the light metal alloy or matrix comprises magnesium, and the oxide layer comprises a magnesium oxide ceramic.

3. The light metal workpiece of claim 1 , wherein the oxide layer is formed having a thickness of from about 5 μm to about 20 μm, the first primer coating is applied having a thickness of from about 50 μm to about 150 μm, the second primer coating is applied having a thickness of from about 50 μm to about 150 μm, and the clear coat layer is applied having a thickness of from about 20 μm to about 30 μm.

4. The light metal workpiece of claim 1 , wherein the light metal or alloy matrix comprises at least one valve metal selected from the group consisting of aluminum, magnesium, titanium, and mixtures thereof.

5. The light metal workpiece of claim 1 , wherein the first primer coating and the second primer coating comprise the same material.

6. A magnesium metal wheel, comprising:
a magnesium metal matrix having an exposed surface;
a magnesium oxide ceramic layer formed on at least a portion of the exposed surface having a thickness of from about 5 μm to about 20 μm and an average pore size of from about 0.1 μm to about 5 μm;
a first primer coating applied onto at least a portion of the magnesium oxide ceramic layer having a thickness of from about 50 μm to about 150 μm;
a second primer coating applied onto at least a portion of the first primer coating the second primer coating having a thickness of from about 50 μm to about 150 μm;
a sputtered metallic film deposited onto at least a portion of the second primer coating using a physical vapor deposition technique, the sputtered metallic film having a thickness of from about 5 nm to about 15 nm; and
a clear coat layer applied onto at least a portion of the metallic film having a thickness of from about 20 μm to about 30 μm.

7. The magnesium metal wheel of claim 6 , wherein each of the first primer coating and the second primer coating comprises at least one of an electrostatic coating and a powder material coating.

8. A method of providing an enhanced surface coating on a metal or alloy substrate, the method comprising:
forming a corrosion resistance basecoat onto at least a portion of an exposed surface of a light metal or alloy substrate, including:
generating an oxide layer on the exposed surface of the substrate by immersing the substrate in an electrolyte bath and resting the substrate on a supporting rack member, wherein the generating of the oxide layer comprises at least one of micro-arc oxidation process and a plasma electrolytic oxidation process and the supporting rack member is configured to serve as a conductive cathode during at least one of the micro-arc oxidation process or the plasma electrolytic oxidation process; and
applying a first primer coating onto the oxide layer;
forming a protective topcoat onto at least a portion of the basecoat, including:
applying a second primer coating onto the first primer coating;
depositing a sputtered metallic film onto the second primer coating using a physical vapor deposition technique; and
applying a clear coat layer onto at least a portion of the sputtered metallic film.

9. The method of claim 8 , wherein the substrate comprises magnesium, and generating the oxide layer comprises generating a magnesium oxide ceramic.

10. The method of claim 8 , wherein generating the oxide layer on the exposed surface of the substrate comprises using at least one of a micro-arc oxidation and a plasma electrolytic oxidation process.

11. The method of claim 8 , wherein the supporting rack member is an independent component, removable from the electrolyte bath.

12. The method of claim 8 , wherein the supporting rack member is integral with a structure containing the electrolyte bath.

13. The method of claim 8 , further comprising identifying corrosion prone areas of the exposed surface, wherein the supporting rack member defines a plurality of support regions, and the resting of the substrate on the supporting rack member comprises aligning the support regions with predetermined contact regions of the substrate while avoiding contact with the corrosion prone areas.

14. The method of claim 13 , wherein the substrate comprises a magnesium wheel, and the predetermined contact regions are located on an outer rim of the magnesium wheel.

15. The method of claim 13 , wherein the substrate comprises a magnesium control arm suspension component or a magnesium door component.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Liu Ming
• Gao Lei

Classifications

• Y10T428/21

  Circular sheet or circular blank · CPC title

• B60B2360/106

  Magnesia · CPC title

• Y10T428/24967

  Absolute thicknesses specified · CPC title

• C23C28/345

  with at least one oxide layer · CPC title

• C25D11/30

  of magnesium or alloys based thereon · CPC title