Production of heavy API group II base oil

Patent metadata

Field	Value
Publication number	US-9796936-B2
Application number	US-201514848917-A
Country	US
Kind code	B2
Filing date	Sep 9, 2015
Priority date	Sep 9, 2015
Publication date	Oct 24, 2017
Grant date	Oct 24, 2017

Abstract

A process for heavy base oil production, comprising: a. performing an aromatic extraction of a first hydrocarbon feed to produce an aromatic extract, and a waxy raffinate; b. mixing the aromatic extract with a second hydrocarbon feed to make a mixed feed having greater than 2,000 wt ppm sulfur; c. feeding the mixed feed to a hydroprocessing unit to produce a heavy API Group II base oil having a kinematic viscosity at 70° C. from 22.6 to 100 mm 2 /s. An integrated refinery process unit for making heavy base oils, comprising: a. an aromatic extraction unit fluidly connected to a solvent dewaxing unit and a hydroprocessing unit; b. a first line from the aromatic extraction unit, that feeds an aromatic extract to a second hydrocarbon feed to make a mixed feed having greater than 2,000 wt ppm sulfur; and c. a connection that feeds the mixed feed to the hydroprocessing unit.

First claim

It is claimed:

1. A process for heavy base oil production, comprising:
a. performing an aromatic extraction of a first hydrocarbon feed to produce an aromatic extract, and a waxy raffinate for further solvent dewaxing;
b. mixing the aromatic extract with a second hydrocarbon feed to make a mixed feed having greater than 2,000 wt ppm sulfur;
c. feeding the mixed feed to a hydroprocessing unit configured to produce a heavy API Group II base oil having a kinematic viscosity at 70° C. from 22.6 to 100 mm 2 /s; and
d. distilling the heavy API Group II base oil to produce a bright stock.

2. The process of claim 1 , wherein the aromatic extract comprises from 30 to 80 vol % aromatics.

3. The process of claim 1 , wherein the hydroprocessing unit performs hydrotreating, catalytic dewaxing, and hydrofinishing.

4. The process of claim 1 , wherein the waxy raffinate is solvent dewaxed and hydrofinished to produce a heavy API Group I base oil.

5. The process of claim 1 , wherein the mixed feed has an initial boiling point less than 340° C.

6. The process of claim 1 , wherein the mixed feed comprises from 5 to 20 wt % of the aromatic extract.

7. The process of claim 1 , wherein the heavy API Group II base oil has a VI of 100 to 120.

8. The process of claim 1 , wherein the heavy API Group II base oil has less than 1.5 wt ppm nitrogen and an aniline point less than 260° F. (126.7° C.).

9. The process of claim 1 , wherein the bright stock has an ISO-VG of ISO-VG 320 or ISO-VG 460.

10. The process of claim 1 , wherein an operating temperature in the hydroprocessing unit is less than 750° F. (399° C.).

11. The process of claim 1 , additionally comprising separating a stripper bottoms from an effluent of a combined hydrotreating and hydrocracking unit located within the hydroprocessing unit, wherein the combined hydrotreating and hydrocracking unit is operated under hydroprocessing conditions and using one or more hydrocracking catalysts to produce the stripper bottoms comprising 1 to 15 lv % aromatic hydrocarbons, 70 to 90 lv % naphthenic carbons, and 1 to 25 lv % paraffinic hydrocarbons, and having the kinematic viscosity at 70° C. greater than 22.6 mm 2 /s.

Assignees

• Chevron Usa Inc

Inventors

• Lei Guan-Dao
• Bhattacharya Subhasis
• Brait Axel

Classifications

• C10G67/0418

  The hydrotreatment being a hydrorefining · CPC title

• C10G2400/08

  Jet fuel · CPC title

• C10G2300/1096

  Aromatics or polyaromatics · CPC title

• C10M177/00

  Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes · CPC title

• C10G53/06 Primary

  including only extraction steps, e.g. deasphalting by solvent treatment followed by extraction of aromatics · CPC title