Encapsulation of an acid precursor for oil field applications

Patent metadata

Field	Value
Publication number	US-9796919-B2
Application number	US-201514748783-A
Country	US
Kind code	B2
Filing date	Jun 24, 2015
Priority date	Jun 24, 2014
Publication date	Oct 24, 2017
Grant date	Oct 24, 2017

Abstract

The present application provides for an acid precursor capsule that includes an acid precursor that is a non-aqueous ester and a polymerized shell that encapsulates the acid precursor. In some embodiments, the acid precursor converts into an associated acid during a hydrolysis period while in contact with water at an elevated temperature. In further embodiments, the associated acid is soluble in water and forms an aqueous acid solution with water. In certain embodiments, the polymerized shell contains the acid precursor and prevents interaction between the acid precursor and water at the elevated temperature until the polymerized shell dissolves in the water during a dissolution period. An acid precursor capsule suspension can include the acid precursor capsule and a suspension fluid. In some embodiments, a method of treatment using acid precursor capsules is provided that includes the step of introducing an acid precursor capsule suspension into a well bore such that the acid precursor capsules contact water at an elevated temperature.

First claim

What is claimed is:

1. An acid precursor capsule comprising:
a non-aqueous ester acid precursor that is operable to convert into an associated acid during a hydrolysis period, such that the hydrolysis period is where the associated acid begins to form in the dispersion while in contact with water at an elevated temperature of greater than 150° F., where the associated acid is soluble in the water and is operable to form an aqueous acid solution with the water; and
a polymerized shell that encapsulates the non-aqueous ester acid precursor such that the polymerized shell contains the non-aqueous ester acid precursor and prevents interaction between the non-aqueous ester acid precursor and the water, where the polymerized shell is operable to dissolve during a dissolution period while in contact with the water at the elevated temperature;
where the acid precursor capsule has a mean diameter and has a mean thickness.

2. The acid precursor capsule of claim 1 , where the non-aqueous ester acid precursor is slightly soluble in the water at the elevated temperature.

3. The acid precursor capsule of claim 1 , where the mean capsule diameter is in a range of from 50 nanometers to 150 microns.

4. The acid precursor capsule of claim 1 , where the aqueous acid solution is operable to react with an acid-reactive constituent of a filter cake and a hydrocarbon-bearing formation.

5. An acid precursor capsule delivery system comprising:
an acid precursor capsule comprising
a non-aqueous ester acid precursor that is operable to convert into an associated acid during a hydrolysis period, such that the hydrolysis period is where the associated acid begins to form in the dispersion while in contact with water at an elevated temperature of greater than 150° F., where the associated acid is soluble in the water and is operable to form an aqueous acid solution with the water; and
a polymerized shell that encapsulates the non-aqueous ester acid precursor such that the polymerized shell contains the non-aqueous ester acid precursor and prevents interaction between the non-aqueous ester acid precursor and the water, where the polymerized shell is operable to dissolve during a dissolution period while in contact with the water at the elevated temperature;
where the acid precursor capsule has a mean diameter and has a mean thickness; and
a suspension fluid that is operable to suspend the acid precursor capsule during introduction.

6. The delivery system of claim 5 , where the suspension fluid is an aqueous suspension fluid having a temperature less than the elevated temperature.

7. The delivery system of claim 5 , where the suspension fluid is a non-aqueous hydrophilic fluid.

8. The acid precursor capsule of claim 1 , wherein the non-aqueous ester acid precursor is glycerol triacetate.

9. The delivery system of claim 5 , where the non-aqueous ester acid precursor is glycerol triacetate.

Assignees

• Saudi Arabian Oil Co

Inventors

• Chang Yun
• Kanj Mazen
• Thies Curt

Classifications

• C09K8/92 Primary

  characterised by their form or by the form of their components, e.g. encapsulated material (C09K8/70 takes precedence) · CPC title

• E21B37/00

  Methods or apparatus for cleaning boreholes or wells (E21B21/00 takes precedence) · CPC title

• C09K8/52

  Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning · CPC title

• C09K8/74

  combined with additives added for specific purposes · CPC title

• C09K8/72

  Eroding chemicals, e.g. acids · CPC title