Hydrocarbon fluid flow improver

Patent metadata

Field	Value
Publication number	US-9796917-B2
Application number	US-201214236050-A
Country	US
Kind code	B2
Filing date	Jul 30, 2012
Priority date	Jul 29, 2011
Publication date	Oct 24, 2017
Grant date	Oct 24, 2017

Abstract

Disclosed herein is a fluid flow improver comprising a branched dendritic core comprising a first quaternary carbon center bonded to four second carbon atoms, wherein at least three of the four second carbon atoms are individually bonded to one or more chain extender ligands to produce the branched dendritic core, wherein the branched dendritic core has greater than or equal to about 16 terminal hydroxyl groups, and wherein at least one of the terminal hydroxyl groups is esterified with at least one carboxylic acid moiety comprising from 6 to 30 carbon atoms. Methods of inhibiting deposition of paraffin and reducing pour point temperature of a hydrocarbon fluid are also disclosed.

First claim

We claim:

1. A method comprising:
adding a flow improver to a first hydrocarbon fluid to produce a second hydrocarbon fluid, wherein the flow improver comprises a dendrimer comprising a branched dendritic core comprising a first quaternary carbon center bonded to four second carbon atoms, wherein at least three of the four second carbon atoms are individually bonded to one or more chain extender ligands to produce the branched dendritic core, wherein the branched dendritic core has greater than or equal to about 16 terminal hydroxyl groups, and wherein at least one of the terminal hydroxyl groups is esterified with at least one carboxylic acid moiety comprising from 6 to 30 carbon atoms, at least one substituted carboxylic acid moiety comprising from 6 to 30 carbon atoms, or a combination thereof, wherein the substituted carboxylic acid moiety comprises at least one functional group comprising elements from Groups 13 to 17 of the periodic table of the elements.

2. The method of claim 1 , wherein the first hydrocarbon fluid is a hydrocarbon fluid produced during extraction of hydrocarbons from a well, crude oil, a crude oil condensate, a middle distillate, a fuel oil, diesel, or a combination thereof.

3. The method of claim 1 , wherein essentially all of the terminal hydroxyl groups are each individually esterified with a corresponding number of carboxylic acid moieties, substituted carboxylic acid moieties, or a combination thereof, each having from 8 to 24 carbon atoms.

4. The method of claim 1 , wherein the flow improver is added to the first hydrocarbon fluid as a solution having a concentration of greater than or equal to about 20 wt % of the dendrimer dissolved in a solvent.

5. The method of claim 1 further comprising adding flow improver to the first hydrocarbon fluid in a well.

6. A method comprising:
extracting a hydrocarbon fluid from a well;
adding a flow improver to the hydrocarbon fluid, the flow improver comprising a dendrimer comprising a branched dendritic core comprising a first quaternary carbon center bonded to four second carbon atoms, wherein at least three of the four second carbon atoms are individually bonded to one or more chain extender ligands to produce the branched dendritic core, wherein the branched dendritic core has greater than or equal to about 16 terminal hydroxyl groups, and wherein at least one of the terminal hydroxyl groups is esterified with at least one carboxylic acid moiety comprising from 6 to 30 carbon atoms, at least one substituted carboxylic acid moiety comprising from 6 to 30 carbon atoms, or a combination thereof, wherein the substituted carboxylic acid moiety comprises at least one functional group comprising elements from Groups 13 to 17 of the periodic table of the elements.

7. The method of claim 6 , wherein the flow improver is added to the hydrocarbon fluid prior to the hydrocarbon fluid being extracted from the well.

8. The method of claim 6 , wherein the flow improver is added to the hydrocarbon fluid after the hydrocarbon fluid has been extracted from the well.

9. The method of claim 6 , wherein the well is located underwater.

10. The method of claim 6 , wherein the flow improver is added to the hydrocarbon fluid while the hydrocarbon fluid is extracted from the well.

Assignees

• Khandekar Chandrashekhar Yeshwant
• Nordvik Tore
• Grinrod Anders
• M-I L L C
• Schlumberger Norge As

Inventors

• Khandekar Chandrashekhar Yeshwant
• Nordvik Tore
• Grinrod Anders

Classifications

• C09K8/035 Primary

  Organic additives · CPC title

• C10G29/22

  containing oxygen as the only hetero atom · CPC title

• C10G2300/302

  Viscosity · CPC title

• C10L1/1985

  polyethers, e.g. di- polygylcols and derivatives; ethers - esters · CPC title

• C09K8/524

  organic depositions, e.g. paraffins or asphaltenes · CPC title