Methods and compositions for treating a subterranean formation with salt-tolerant cement slurries

Patent metadata

Field	Value
Publication number	US-9796905-B2
Application number	US-201314359476-A
Country	US
Kind code	B2
Filing date	Sep 20, 2013
Priority date	Sep 28, 2012
Publication date	Oct 24, 2017
Grant date	Oct 24, 2017

Abstract

Methods and compositions for treating a subterranean formation with salt-tolerant cement slurries including treating a salt-containing subterranean formation having sodium salts, potassium salts, magnesium salts, calcium salts, or any combination thereof comprising: providing a salt-tolerant cement slurry comprising: a base fluid, a cementitious material, a pozzolanic material, a salt-tolerant fluid loss additive, a salt additive, and optionally, an elastomer, a weight additive, a fluid loss intensifier, a strengthening agent, a dispersant, or any combination thereof; introducing the salt-tolerant cement slurry into the subterranean formation; and allowing the salt-tolerant cement slurry to set.

First claim

The invention claimed is:

1. A salt-tolerant cement slurry comprising:
a base fluid;
a cementitious material;
a pozzolanic material;
a salt-tolerant fluid loss additive comprising an amphoteric copolymer;
a salt additive;
an elastomer; and
optionally a weight additive, a fluid loss intensifier, a strengthening agent, a dispersant, or any combination thereof;
wherein the cementitious material is present in a range of about 5% to about 60% w/w of all components of the salt-tolerant cement slurry except the base fluid.

2. The salt-tolerant cement slurry of claim 1 , wherein the cementitious material is a hydraulic cement.

3. The salt-tolerant cement slurry of claim 1 , wherein the pozzolanic material is selected from the group consisting of silica fume; metakaolin; fly ash; diatomaceous earth; calcined diatomite; uncalcined diatomite; calcined fullers earth; pozzolanic clay; calcined volcanic ash; uncalcined volcanic ash; bagasse ash; pumice; pumicite; rice hull ash; natural zeolite; synthetic zeolite; slag; vitreous calcium aluminosilicate; and any combination thereof.

4. The salt-tolerant cement slurry of claim 1 , wherein salt tolerant cement slurry has a yield point in the range of about 5 to about 200 lb/100 ft2 and a plastic viscosity in the range of about 120 to about 500 cP.

5. The salt-tolerant cement slurry of claim 1 , wherein the pozzolanic material is present in a range of about 0.001% to about 60% w/w of all components of the salt-tolerant cement slurry except the base fluid.

6. The salt-tolerant cement slurry of claim 1 , wherein the salt-tolerant fluid loss additive is present in a range of about 0.001% to about 3% w/w of all components of the salt-tolerant cement slurry except the base fluid.

7. The salt-tolerant cement slurry of claim 1 , wherein the salt additive is selected from the group consisting of sodium chloride, potassium chloride, and any combination thereof.

8. The salt-tolerant cement slurry of claim 1 , wherein the salt additive is present in the range of about 15% to about 40% w/w of all components of the salt-tolerant cement slurry except the base fluid.

9. The salt-tolerant cement slurry of claim 1 , wherein the elastomer is selected from the group consisting of polypropylene; polyethylene; styrene divinyl benzene; polyisoprene; polybutadiene; polyisobutylene; polyurethane; a styrene-butadiene random copolymer; a styrene-butadiene block copolymer; acrylonitrile butadiene; acrylonitrile-styrene-butadiene; and any combination thereof.

10. The salt-tolerant cement slurry of claim 1 , wherein the elastomer is present in a range of about 0.001% to about 20% w/w of all components of the salt-tolerant cement slurry except the base fluid.

11. The salt-tolerant cement slurry of claim 1 , wherein the weight additive is selected from the group consisting of hausmannite ore; barite, hermatite; calcium carbonate; siderite; ilmenite; and any combination thereof.

12. The salt-tolerant cement slurry of claim 1 , wherein the weight additive is present in a range of about 0.001% to about 30% w/w of all components of the salt-tolerant cement slurry except the base fluid.

13. The salt-tolerant cement slurry of claim 1 , wherein the fluid loss intensifier is selected from the group consisting of 2-acrylamido-2-methylpropane sulfonic acid; N,N dimethyl acrylamide; acrylamide terpolymer; a copolymer thereof; any derivatives thereof; and any combination thereof.

14. The salt-tolerant cement slurry of claim 1 , wherein the fluid loss intensifier is present in a range of about 0.001% to about 2% w/w of all components of the salt-tolerant cement slurry except the base fluid.

15. The salt-tolerant cement slurry of claim 1 , wherein the strengthening agent is selected from the group consisting of silica flour; silica fume; and any combination thereof.

16. The salt-tolerant cement slurry of claim 1 , wherein the strengthening agent is present in a range of about 0.001% to about 40% w/w of all components of the salt-tolerant cement slurry except the base fluid.

17. The salt-tolerant cement slurry of claim 1 , wherein the dispersant is selected from the group consisting of sulfonated styrene maleic anhydride copolymer, sulfonated vinyltoluene maleic anhydride copolymer, sodium naphthalene sulfonate condensed with formaldehyde, sulfonated acetone condensed with formaldehyde, lignosulfonates and interpolymers of acrylic acid, allyloxybenzene sulfonate, allyl sulfonate and non-ionic monomers, and any combination thereof.

18. The salt-tolerant cement slurry of claim 1 , wherein the dispersant is present in a range of about 0.001% to about 4% w/w of all components of the salt-tolerant cement slurry except the base fluid.

Assignees

• Halliburton Energy Services Inc

Inventors

• Ravi Krishna M
• Patil Rahul Chandrakant
• Patil Sandip Prabhakar
• Bose Sohini
• Deshpande Abhimanyu

Classifications

• C04B18/146

  Silica fume · CPC title

• C04B2103/50

  Defoamers, air detrainers · CPC title

• C04B2103/0088

  Compounds chosen for their latent hydraulic characteristics, e.g. pozzuolanes · CPC title

• Y02W30/94

  Cross-Sectional Technologies · mapped topic

• C04B22/124

  Chlorides of ammonium or of the alkali or alkaline earth metals, e.g. calcium chloride · CPC title