Self-healing coatings from recycled polymer blends

Patent metadata

Field	Value
Publication number	US-9796857-B2
Application number	US-201314654335-A
Country	US
Kind code	B2
Filing date	Sep 25, 2013
Priority date	Dec 19, 2012
Publication date	Oct 24, 2017
Grant date	Oct 24, 2017

Abstract

The present disclosure pertains to coatings with self-repairing capabilities. In some embodiments, the coatings may include a polymer blend, made up of at least two polymers. The coatings may further contain compatibilizers that are nanocontainer particles. The nanocontainers may be filled with self-healing agents. The self-healing agents may be agents that heal cracks formed in the coating or they may be anti-corrosion agents that reduce the corrosion of the underlying metal substrate.

First claim

What is claimed is:

1. A polymer coating comprising:
a polymer blend comprising at least a first polymer and a second polymer; and
at least one nanocontainer encapsulating at least one self-healing agent, wherein the at least one nanocontainer is a Janus particle comprising an oxide nanoparticle, a titania reservoir, a silicate particle coated with polyelectrolyte layers, a halloysite, a layered double hydroxide composite, a polyelectrolyte capsule, a poly(ureaformaldehyde), or a combination thereof, and comprising at least a first surface and a second surface, wherein the first surface interacts with the first polymer and the second surface interacts with the second polymer, and the at least one nanocontainer releases the at least one self-healing agent when the at least one nanocontainer contacts a corrosive surface or when exposed to a change in pH, and wherein the at least one self-healing agent is benzotriazole, 2-mercaptobenzothiazole, a silyl ester, an inorganic chromate, an inorganic nitrate, an organic nitrate, a polyaniline formaldehyde, 2,3-diphenyl benzoquinoxaline, mebendazole, an isoxazolidine, or a combination thereof; and
wherein the at least one nanocontainer is at least partially mixed with the polymer blend, and wherein the polymer coating is a self-healing coating.

2. The polymer coating of claim 1 , wherein the polymer blend comprises an alkyl methacrylate polymer, an allyl methacrylate polymer, a thioethyl methacrylate polymer, a vinyl methacrylate polymer, a vinyl benzene polymer, a 2-hydroxyethyl acrylate polymer, a butyl acrylate polymer, a 2-ethylhexyl acrylate polymer, a vinyltrimethoxysilane polymer, a vinyltriethoxysilane polymer, a vinyltoluene polymer, an α-methyl styrene polymer, a chlorostyrene polymer, a styrenesulfonic acid polymer, or a combination thereof.

3. The polymer coating of claim 1 , further comprising a solvent, a pigment, a coalescing agent, a rheology modifier, a plasticizer, a surfactant, or any combination thereof.

4. The polymer coating of claim 1 , wherein the coating is a decorative coating, an industrial coating, a protective coating, a self-cleaning coating, or any combination thereof.

5. A method of inhibiting corrosion of a substrate, the method comprising:
applying a polymer coating on the substrate, wherein the polymer coating comprises a polymer blend comprising at least a first polymer and a second polymer; and
at least one nanocontainer encapsulating at least one self-healing agent, wherein the at least one nanocontainer is a Janus particle comprising an oxide nanoparticle, a titania reservoir, a silicate particle coated with polyelectrolyte layers, a halloysite, a layered double hydroxide composite, a polyelectrolyte capsule, a poly(ureaformaldehyde), or a combination thereof, and comprising at least a first surface and a second surface, wherein the first surface interacts with the first polymer and the second surface interacts with the second polymer, and wherein the at least one self-healing agent is benzotriazole, 2-mercaptobenzothiazole, a silyl ester, an inorganic chromate, an inorganic nitrate, an organic nitrate, a polyaniline formaldehyde, 2,3-diphenyl benzoquinoxaline, mebendazole, an isoxazolidine, or a combination thereof; and
wherein the at least one nanocontainer is at least partially mixed with the polymer blend.

6. The method of claim 5 , wherein applying the polymer coating on the substrate comprises applying the polymer coating comprising the polymer blend comprising at least the first polymer and the second polymer, and the at least one nanocontainer, wherein the at least one nanocontainer releases the at least one self-healing agent when the at least one nanocontainer contacts a corrosive surface or when the at least one nanocontainer is exposed to a change in pH.

7. The method of claim 5 , wherein the polymer coating composition is applied to the substrate by coating, brushing, dipping, spraying, rolling, or a combination thereof.

8. A method of preparing a self-healing coating, the method comprising:
generating at least one Janus nanoparticle comprising an oxide nanoparticle, a titania reservoir, a silicate particle coated with polyelectrolyte layers, a halloysite, a layered double hydroxide composite, a polyelectrolyte capsule, a poly(ureaformaldehyde), or a combination thereof, and comprising at least a first surface and a second surface, wherein the first surface interacts with a first polymer and the second surface interacts with a second polymer, and containing at least one self-healing agent, wherein the at least one self-healing agent is benzotriazole, 2-mercaptobenzothiazole, a silyl ester, an inorganic chromate, an inorganic nitrate, an organic nitrate, a polyaniline formaldehyde, 2,3-diphenyl benzoquinoxaline, mebendazole, an isoxazolidine, or a combination thereof; and
at least partially mixing the at least one Janus nanoparticle with a polymer blend comprising at least the first polymer and the second polymer.

9. The method of claim 8 , wherein generating the at least one Janus nanoparticle comprises generating the at least one Janus nanoparticle that releases the at least one self-healing agent when the at least one Janus particle contacts a corrosive surface or when the at least one Janus particle is exposed to a change in pH.

10. A coated article comprising:
an article;
a self-healing coating on surface of the article, wherein the self-healing coating comprises a polymer blend comprising at least a first polymer and a second polymer; and
at least one nanocontainer encapsulating at least one self-healing agent, wherein the at least one nanocontainer is a Janus particle comprising an oxide nanoparticle, a titania reservoir, a silicate particle coated with polyelectrolyte layers, a halloysite, a layered double hydroxide composite, a polyelectrolyte capsule, a poly(ureaformaldehyde), or a combination thereof, and comprising at least a first surface and a second surface, wherein the first surface interacts with the first polymer and the second surface interacts with the second polymer, and the at least one nanocontainer releases the at least one self-healing agent when the at least one nanocontainer contacts a corrosive surface or when exposed to a change in pH, and wherein the at least one self-healing agent is benzotriazole, 2-mercaptobenzothiazole, a silyl ester, an inorganic chromate, an inorganic nitrate, an organic nitrate, a polyaniline formaldehyde, 2,3-diphenyl benzoquinoxaline, mebendazole, an isoxazolidine, or a combination thereof; and
wherein the at least one nanocontainer being at least partially mixed with the polymer blend.

11. The article of claim 10 , wherein the at least one nanocontainer is a silicon dioxide particle coated with polyethyleneimine, polystyrene sulfonate, and benzotriazole.

12. The article of claim 10 , wherein the polymer blend comprises polyethylene, polypropylene, polystyrene, polyvinylchloride, polyethylene terephthalate, polyethylene methacrylate, polymethyl methacrylate, or a combination thereof.

13. The article of claim 10 , wherein the self-healing coating provides anti-corrosive property when coated on the article.

14. The polymer coating of claim 1 , wherein the size of the at least one nanocontainer is about 0.1 nanometer to about 500 micrometers in diameter or length, and of any shape.

15. The polymer coating of claim 1 , wherein the Janus particle is present at about 0.5 weight percent to about 10 weight percent of the polymer coating composition.

Assignees

• Empire Technology Dev Llc

Inventors

• Sjong Angele

Classifications

• C09D7/1266

  Chemistry & Metallurgy · mapped topic

• C08L101/00

  Compositions of unspecified macromolecular compounds · CPC title

• C08K2201/011

  Nanostructured additives · CPC title

• C09D167/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C09D167/06 takes precedence) · CPC title

• C08J11/04

  of polymers · CPC title