Propylene-based copolymer composition for pipes

Patent metadata

Field	Value
Publication number	US-9796840-B2
Application number	US-201515313306-A
Country	US
Kind code	B2
Filing date	Apr 28, 2015
Priority date	May 28, 2014
Publication date	Oct 24, 2017
Grant date	Oct 24, 2017

Abstract

A polyolefin composition made using a propylene/ethylene copolymer (90.0 wt % to 99.0 wt %) and a heterophasic (second) propylene/ethylene copolymer (1.0 wt % to 10.0 wt %). The composition is useful for the production of pressure pipes, e.g., for use at low temperature, and of pipes for use in heat radiating systems, among other applications. The propylene/ethylene copolymer has between 1.0 wt % and 8.0 wt % ethylene derived units. The second propylene/ethylene copolymer is made using (1) a propylene homopolymer or a propylene/ethylene copolymer (12 wt % to 52 wt %) and (2) a propylene ethylene copolymer (48 wt % to 88 wt %) that has a content of ethylene derived units ranging from 15.0 wt % to 42.0 wt %.

First claim

What is claimed is:

1. A polyolefin composition comprising:
A) from 90.0 wt % to 99.0 wt %; of a first propylene/ethylene copolymer wherein:
i) the content of ethylene derived units is comprised between 1.0 wt % and 8.0 wt %;
(ii) the melting temperature ranges from 135° C. to 155° C.;
(iii) the melt flow rate (230° C./5 kg; ISO 1133) ranging from 0.2 g/10 min to 3.5 g/10 min;
(iv) the xylene solubles at 25° C. ranges from 20 0.0 wt % to 4.0 wt %;
(v) the polydispersity index, PI, ranges from 3.0 to 7.0;
B) from 1.0 wt % to 10.0 wt %; of a second propylene/ethylene copolymer composition comprising:
b1) from 12 wt % to 52 wt %; of a propylene homopolymer or a propylene/ethylene copolymer having a content of ethylene derived units ranging from 0.1 wt % to 4.5 wt %; and having a xylene soluble content measured at 25° C. lower than 10 wt %;
b2) from 48 wt % to 88 wt % of a propylene/ethylene copolymer having a content of ethylene derived units ranging from 15.0 wt % to 42.0 wt %;
wherein the resulting polyolefin composition has an melt flow rate (230° C./5 kg; ISO 1133) ranging from 0.2 g/10 min to 4.0 g/10 min; the sum A+B being 100, based on the weight percentages of A and B, and the sum b1+b2 being 100, based on the weight percentages of b1 and b2.

2. The polyolefin composition according to claim 1 wherein the content of ethylene derived units ranges from 2.0 wt % to 8.0 wt %.

3. The polyolefin composition according to claim 1 wherein the component b2) is a propylene/ethylene copolymer having an content of ethylene derived units ranging from 18 wt % to 38 wt %, the propylene/ethylene copolymer having an intrinsic viscosity of the xylene soluble fraction at 25° C. ranging from 2.0 dl/g to 5.0 dl/g.

4. The polyolefin composition according to claim 1 wherein the melt flow rate (MFR) (230° C./5 kg; ISO 1133) ranges from 0.4 to 3.0 g/10 min.

5. Pipe systems and sheets comprising a polyolefin composition according to claim 1 .

6. Pressure pipe systems according to claim 5 .

7. Mono- or multilayer pipes and sheets wherein at least one layer comprises the polyolefin composition according to claim 1 .

8. Fitting for pipe systems comprising a polyolefin composition according to claim 1 .

9. Heat radiating pipe system comprising at least one pipe system according to claim 5 .

Assignees

• Basell Poliolefine Italia Srl

Inventors

• Galvan Monica
• Tisi Francesca
• Pellegatti Giampaolo
• Bolognesi Sandro
• Neumann Andreas

Classifications

• C08L23/16

  Ethylene-propylene or ethylene-propylene-diene copolymers · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08L23/14 Primary

  Copolymers of propene (C08L23/16 takes precedence) · CPC title

• C08L23/12

  Polypropene · CPC title

• C08L2203/18

  used for pipes · CPC title