Process for producing olefin polymer and olefin polymer
US-2015239996-A1 · Aug 27, 2015 · US
US9796799B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9796799-B2 |
| Application number | US-201615195340-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 28, 2016 |
| Priority date | Sep 25, 2012 |
| Publication date | Oct 24, 2017 |
| Grant date | Oct 24, 2017 |
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[Object] To provide transition metal compounds with excellent catalytic activity which can afford olefin polymers such as propylene polymers that have high stereoregularity and high molecular weight and may be easily crystallized into a β-phase. [Solution] The transition metal compound is represented by General Formula [I] or is an enantiomer thereof: [in Formula [I], R 1 , R 3 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , R 13 , R 14 , R 15 and R 16 are each independently a hydrogen atom, a hydrocarbon group, a hetero atom-containing hydrocarbon group, or a silicon-containing group; R 2 is a hydrocarbon group, a hetero atom-containing hydrocarbon group, or a silicon-containing group; R 4 is a hydrogen atom; any two substituents of the substituents R 1 to R 16 except R 4 may be bonded to each other to form a ring; M is a Group IV transition metal; Q is a structure such as a halogen atom; and j is an integer of 1 to 4].
Opening claim text (preview).
The invention claimed is: 1. A propylene polymer having a meso pentad fraction of 97.0% to 99.5% and a total fraction of 2,1-insertions and 1,3-insertions of propylene monomers of 0.01 mol % to 0.06 mol % relative to all propylene-derived structural units as measured by 13 C-NMR, wherein the propylene polymer shows one or more melting peaks assigned to α-phases in the range of 160° C. or more, and also shows one or more melting peaks assigned to β-phases in the range of 140° C. to less than 160° C. 2. A shaped article comprising the propylene polymer described in claim 1 .
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