Preparation of haloalkoxyarylhydrazines and intermediates therefrom
US-9108932-B2 · Aug 18, 2015 · US
US9796682B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9796682-B2 |
| Application number | US-201615370524-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 6, 2016 |
| Priority date | Oct 17, 2013 |
| Publication date | Oct 24, 2017 |
| Grant date | Oct 24, 2017 |
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The present application provides processes for making pesticidal compounds and compounds useful both as pesticides and in the making of pesticidal compounds.
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What is claimed is: 1. A process for the preparation of secondary amine (1d) which comprises reacting N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)acetamide (1c) with a suitable reducing agent in the presence of an acid. 2. The process of claim 1 , wherein the reducing agent is a hydride source. 3. The process of claim 1 , wherein the reducing agent is sodium borohydride. 4. The process of claim 1 , wherein the acid is a Brønsted acid. 5. The process of claim 1 , wherein the acid is a Lewis acid. 6. The process of claim 5 , wherein the Lewis acid is borontrifluoride etherate. 7. The process of claim 2 , wherein the acid is a Lewis acid. 8. The process of claim 7 , wherein the Lewis acid is borontrifluoride etherate. 9. The process of claim 3 , wherein the acid is a Lewis acid. 10. The process of claim 9 , wherein the Lewis acid is borontrifluoride etherate.
of an acyclic saturated carbon skeleton · CPC title
Acylated on said nitrogen atom · CPC title
1,2-Diazoles; Hydrogenated 1,2-diazoles · CPC title
directly linked by a ring-member-to-ring-member bond · CPC title
Nitrogen atoms (nitro radicals C07D231/16) · CPC title
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