Method of manufacturing three-dimensional structure and three-dimensional structure
US-2015375459-A1 · Dec 31, 2015 · US
US9796139B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9796139-B2 |
| Application number | US-201514886357-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 19, 2015 |
| Priority date | Oct 20, 2014 |
| Publication date | Oct 24, 2017 |
| Grant date | Oct 24, 2017 |
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A three-dimensional shaping composition of this invention is a three-dimensional shaping composition which is used for producing a three-dimensionally shaped article by laminating layers and contains particles having a hydrophilic surface and water-soluble monomers having a hydroxyl group. The water-soluble monomer is preferably at least one selected from the group consisting of 4-hydroxybutyl acrylate, 2-hydroxybutyl acrylate, 2-hydroxypropyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate, and phenol epoxy acrylate.
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What is claimed is: 1. A three-dimensional shaping composition, which is used for producing a three-dimensionally shaped article by laminating layers and discharging an ink containing a polymerization initiator to the layers, the three-dimensional shaping composition comprising: particles having a hydrophilic surface; and water-soluble monomers having a hydroxyl group, wherein the water-soluble monomer is at least one selected from the group consisting of 4-hydroxybutyl acrylate, 2-hydroxybutyl acrylate, and phenol epoxy acrylate. 2. The three-dimensional shaping composition according to claim 1 , wherein the water-soluble monomer is a radically polymerizable monomer or a cationically polymerizable monomer. 3. The three-dimensional shaping composition according to claim 1 , further comprising an aqueous solvent. 4. The three-dimensional shaping composition according to claim 1 , wherein the particles have at least one functional group selected from the group consisting of a hydroxyl group, a carboxyl group, and an amino group on the surface. 5. The three-dimensional shaping composition according to claim 1 , wherein a constituent material of the particles is at least one selected from the group consisting of silica, calcium carbonate, alumina, and titanium oxide.
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