Catalyst for preparing aviation fuel from Fischer-Tropsch products and method for preparing said catalyst

Patent metadata

Field	Value
Publication number	US-9795950-B2
Application number	US-201615350132-A
Country	US
Kind code	B2
Filing date	Nov 14, 2016
Priority date	May 14, 2014
Publication date	Oct 24, 2017
Grant date	Oct 24, 2017

Abstract

A catalyst for preparing aviation fuel from synthetic oil obtained by Fischer-Tropsch process, including: between 20 and 50 percent by weight of an amorphous aluminum silicate, between 5 and 20 percent by weight of alumina, between 20 and 60 percent by weight of a hydrothermally modified zeolite, between 0.5 and 1.0 percent by weight of a Sesbania powder, between 0.5 and 5 percent by weight of nickel oxide, and between 5 and 15 percent by weight of molybdenum oxide. The invention also provides a method for preparing the catalyst.

First claim

The invention claimed is:

1. A catalyst, comprising:
between 20 and 50 percent by weight of an amorphous aluminum silicate;
between 5 and 20 percent by weight of alumina;
between 20 and 60 percent by weight of a hydrothermally modified zeolite;
between 0.5 and 1.0 percent by weight of a Sesbania powder;
between 0.5 and 5 percent by weight of nickel oxide; and
between 5 and 15 percent by weight of molybdenum oxide.

2. The catalyst of claim 1 , comprising:
between 30 and 45 percent by weight of the amorphous aluminum silicate;
between 8 and 15 percent by weight of alumina;
between 25 and 50 percent by weight of the hydrothermally modified zeolite;
between 0.6 and 0.8 percent by weight of the Sesbania powder;
between 2.5 and 4.5 percent by weight of nickel oxide; and
between 8 and 12 percent by weight of molybdenum oxide.

3. The catalyst of claim 1 , wherein the hydrothermally modified zeolite is a steam-modified dealuminized ZSM-22 zeolite.

4. The catalyst of claim 1 , wherein the hydrothermally modified zeolite is a steam-modified dealuminized hydrogen-type ZSM-22 zeolite.

5. The catalyst of claim 4 , wherein the steam has a temperature of between 300 and 900° C., a pressure of between 0.1 and 2.0 megapascal, and holds for between 2 and 4 hrs.

6. The catalyst of claim 4 , wherein the steam has a temperature of between 500 and 800° C., a pressure of between 0.1 and 0.5 megapascal, and holds between 2 and 3.5 hrs.

7. The catalyst of claim 1 , wherein the catalyst has a specific area of between 200 and 300 m 2 /g; micropores of the catalyst having a pore volume of between 0.4 and 0.8 mL/g and a pore size distribution of between 4 and 10 nm accounts for between 65 and 85% of total pores; and a total acidity of the catalyst measured using a NH 3 -TPD method is between 0.4 and 1.0 mmol/g.

8. A method for preparing the catalyst of claim 4 , comprising:
1) adding a potassium-type ZSM-22 zeolite to a NH 4 NO 3 solution for ion exchange, filtering, washing, and drying a resulting zeolite;
2) repeating 1) for two or three times, and calcining the zeolite to yield a hydrogen-type ZSM-22 zeolite;
3) introducing steam to the hydrogen-type ZSM-22 zeolite for hydrothermal treatment to yield the dealuminized hydrogen-type ZSM-22 zeolite;
4) mixing the dealuminized hydrogen-type ZSM-22 zeolite with the amorphous aluminum silicate, adding alumina as the binder, adding a diluted nitric acid solution for modulation, and adding the Sesbania powder as an extrusion aid, mixing, kneading, and pressing to form masses, and extruding the masses to form strips;
5) drying and calcining the strips to yield a catalyst carrier;
6) mixing a soluble molybdenum salt and a soluble nickel salt to prepare an aqueous solution, dispersing the aqueous solution by an ultrasonic wave to acquire an active soaking solution; and
7) soaking the catalyst carrier into the active soaking solution to load active components on the carrier, aging, drying, and calcining to acquire a catalyst product.

9. The method of claim 8 , wherein in 1), the potassium-type ZSM-22 zeolite has a molar ratio of SiO 2 /Al 2 O 3 is between 20 and 160.

10. The method of claim 8 , wherein in 1), the molar ratio of SiO 2 /Al 2 O 3 of the potassium-type ZSM-22 zeolite is between 30 and 100.

11. The method of claim 8 , wherein in 1), a concentration of the NH 4 NO 3 solution is between 1.0 and 2.0 mol/L; and the potassium-type ZSM-22 zeolite was added in the NH 4 NO 3 solution for ion exchange, the ion exchange is performed in condition of water bath at a temperature of between 60 and 110° C. for between 1 and 4 hrs.

12. The method of claim 8 , wherein in 1), the concentration of the NH 4 NO 3 solution is between 1.0 and 1.5 mol/L; and the ion exchange is performed in condition of water bath at a temperature of between 80 and 100° C. for between 2 and 4 hrs.

13. The method of claim 8 , wherein in 3), the hydrothermal treatment of the hydrogen-type ZSM-22 zeolite by the steam is performed at a temperature of between 300 and 900° C. and a pressure of between 0.1 and 2.0 megapascal for between 2 and 4 hrs.

14. The method of claim 8 , wherein in 3), the hydrothermal treatment of the hydrogen-type ZSM-22 zeolite by the steam is performed at the temperature of between 500 and 800° C., the pressure of between 0.1 and 0.5 megapascal for between 2 and 3.5 hrs.

15. The method of claim 8 , wherein in 4), the amorphous aluminum silicate has a specific area of between 250 and 400 m 2 /g, and SiO 2 accounts for between 20 and 50 w.t % of a total weight of the amorphous aluminum.

16. The method of claim 8 , wherein in 4), the amorphous aluminum silicate has a specific area of between 250 and 300 m 2 /g, and SiO 2 accounts for between 30 and 50 w.t % of a total weight of the amorphous aluminum.

17. The method of claim 8 , wherein in 4), the dilute nitric acid solution has a concentration of between 3 and 8 percent by weight.

18. The method of claim 8 , wherein in 5), the strips are dried at a temperature of between 80 and 120° C. for between 6 and 24 hrs.

19. The method of claim 8 , wherein in 5), the strips are dried at a temperature of between 100 and 120° C. for between 6 and 12 hrs.

20. The method of claim 8 , wherein in 5), the strips are dried at a temperature of between 500 and 600° C. for between 4 and 8 hrs.

21. The method of claim 8 , wherein in 5), the catalyst carrier adopts a cylinder shape, a trefoil shape, or a quatrefoil shape.

22. The method of claim 8 , wherein in 6), the soluble molybdenum salt is ammonium molybdate or sodium molybdate; and the soluble nickel salt is nickel nitrate.

23. The method of claim 8 , wherein in 6), a time for the treatment of the ultrasonic wave is between 0.5 and 1.5 hrs.

24. The method of claim 8 , wherein in 7), the aging treatment is conducted at room temperature for between 12 and 24 hrs; the drying is conducted at a temperature of between 100 and 120° C. for between 10 and 14 hrs; and the calcination is conducted at a temperature of between 500 and 600° C. for between 4 and 8 hrs.

25. The method of claim 8 , wherein in 7), the aging treatment is conducted at room temperature for between 16 and 20 hrs; the drying is conducted at a temperature of between 110 and 120° C. for between 10 and 12 hrs; and the calcination is conducted at a temperature of between 550 and 600° C. for between 4 and 6 hrs.

Assignees

• Wuhan Kaidi Eng Tech Res Inst

Inventors

• Wang Wanwan
• Song Dechen
• Xu Li

Classifications

• B01J35/80

  characterised by their amorphous structures · CPC title

• B01J35/55

  Cylinders or rings · CPC title

• B01J35/50

  characterised by their shape or configuration · CPC title

• B01J35/026

  Operations & Transport · mapped topic

• B01J37/04

  Mixing {(B01J37/0009, B01J37/0018 take precedence)} · CPC title