Method of preparation of perovskite catalyst

Patent metadata

Field	Value
Publication number	US-9795947-B2
Application number	US-201514960107-A
Country	US
Kind code	B2
Filing date	Dec 4, 2015
Priority date	Jul 6, 2015
Publication date	Oct 24, 2017
Grant date	Oct 24, 2017

Abstract

A preparation method of perovskite catalyst, represented by the following Chemical Formula 1: La x Ag (1-x) MnO 3 (0.1≦x≦0.9), includes the steps of 1) preparing a metal precursor solution including a lanthanum metal precursor, a manganese metal precursor and a silver metal precursor, 2) adding maleic or citric acid to the metal precursor solution, 3) drying the mixture separately several times with sequentially elevating the temperature in the range of 160 to 210° C., and 4) calcining the dried mixture at 600 to 900° C. for 3 hours to 7 hours.

First claim

The invention claimed is:

1. A preparation method of perovskite catalyst, represented by the following Chemical Formula 1: La x Ag (1-x) MnO 3 (0.1≦x≦0.9), including the steps of:
1) preparing a metal precursor solution including a lanthanum metal precursor, a manganese metal precursor and a silver metal precursor;
2) adding citric acid to the metal precursor solution;
3) drying the mixture separately several times while sequentially elevating the temperature in the range of 160 to 210° C.; and
4) calcining the dried mixture at 600 to 900° C. for 3 hours to 7 hours.

2. The preparation method according to claim 1 , wherein the lanthanum metal precursor is La(NO 3 ) 3 .6H 2 O.

3. The preparation method according to claim 1 , wherein the manganese metal precursor is Mn(NO 3 ) 2 .6H 2 O.

4. The preparation method according to claim 1 , wherein the silver metal precursor is AgNO 3 .

5. The preparation method according to claim 1 , wherein a solvent of the metal precursor solution is distilled water.

6. The preparation method according to claim 1 , wherein the amount of citric acid added is 0.2 to 2.0 moles per the total mole of lanthanum, manganese and silver in the metal precursor solution.

7. The preparation method according to claim 1 , further including the step of stirring the solution at 70 to 90° C. for 6 to 10 hours and drying the same at 100 to 120° C. for 8 to 14 hours, between step 2) and step 3).

8. The preparation method according to claim 1 , wherein step 3) is carried out by the steps of:
3-1) heating the mixture to 163 to 167° C. and carrying out a primary dry for 2 to 6 hours;
3-2) heating the primary dried mixture to 168 to 172° C. and carrying out a secondary dry for 2 to 6 hours;
3-3) heating the secondary dried mixture to 170 to 174° C. and carrying out a tertiary dry for 2 to 6 hours;
3-4) heating the tertiary dried mixture to 173 to 177° C. and carrying out a quaternary dry for 2 to 6 hours; and
3-5) heating the quaternary dried mixture to 198 to 202° C. and carrying out a quinary dry for 1 to 3 hours.

9. The preparation method according to claim 8 , wherein the heating rate is 1° C./min to 10° C./min.

10. The preparation method according to claim 1 , wherein x is 0.3 to 0.7.

11. A preparation method of perovskite catalyst, represented by the following Chemical Formula 1: La x Ag (1-x) MnO 3 (0.1≦x≦0.9), including the steps of:
1) preparing a metal precursor solution including a lanthanum metal precursor, a manganese metal precursor and a silver metal precursor;
2) adding maleic acid to the metal precursor solution;
3) drying the mixture separately several times while sequentially elevating the temperature in the range of 160 to 210° C.; and
4) calcining the dried mixture at 600 to 900° C. for 3 hours to 7 hours.

12. The preparation method according to claim 11 , wherein the amount of maleic acid added is 0.2 to 2.0 moles per the total mole of lanthanum, manganese and silver in the metal precursor solution.

Assignees

• Hyundai Motor Co Ltd

Inventors

• Choung Jin Woo
• Kim Pyung Soon

Classifications

• B01J35/733

  Perovskite-type · CPC title

• B01J2235/15

  X-ray diffraction · CPC title

• B01J35/30

  characterised by their physical properties · CPC title

• B01J2523/3706

  Lanthanum · CPC title

• B01J23/002

  Mixed oxides other than spinels, e.g. perovskite · CPC title