Gasifier having integrated fuel cell power generation system

Patent metadata

Field	Value
Publication number	US-9793563-B2
Application number	US-201514610533-A
Country	US
Kind code	B2
Filing date	Jan 30, 2015
Priority date	Jun 2, 2009
Publication date	Oct 17, 2017
Grant date	Oct 17, 2017

Abstract

A direct carbonaceous material to power generation system integrates one or more solid oxide fuel cells (SOFC) into a fluidized bed gasifier. The fuel cell anode is in direct contact with bed material so that the H 2 and CO generated in the bed are oxidized to H 2 O and CO 2 to create a push-pull or source-sink reaction environment. The SOFC is exothermic and supplies heat within a reaction chamber of the gasifier where the fluidized bed conducts an endothermic reaction. The products from the anode are the reactants for the reformer and vice versa. A lower bed in the reaction chamber may comprise engineered multi-function material which may incorporate one or more catalysts and reactant adsorbent sites to facilitate excellent heat and mass transfer and fluidization dynamics in fluidized beds. The catalyst is capable of cracking tars and reforming hydrocarbons.

First claim

What is claimed is:

1. A method of steam reforming carbonaceous material to produce H2 and CO while simultaneously producing power, the method comprising:
providing a steam reformer vessel having a fluidized bed containing bed material;
providing at least one fuel cell element which protrudes into the fluidized bed, the at least one fuel cell element comprising an outer anode and an inner cathode with the outer anode being in direct contact with the bed material and the cathode being supplied with an oxidant;
introducing carbonaceous material and superheated steam into the fluidized bed; and
operating the fluidized bed such that:
(i) the fuel cell element outputs power;
(ii) the superheated steam reacts endothermically with the carbonaceous material to produce hydrogen and carbon monoxide in the fluidized bed, by steam reforming;
(iii) oxygen is transported from the cathode to the anode and reacts exothermically with hydrogen in the fluidized bed to produce additional steam and heat which are then used in said steam reforming to produce additional hydrogen and carbon monoxide in the fluidized bed; and
(iv) the bed material operates at a temperature of about 600° C. to about 1,000° C.

2. The method according to claim 1 , comprising operating the bed material at a temperature of about 700° C. to about 800° C.

3. The method according to claim 1 , wherein the carbonaceous material is selected from the group consisting of a gaseous fuel, liquid fuel and solid fuel.

4. The method according to claim 1 , wherein the carbonaceous material is selected from the group consisting of natural gas, propane, methanol, ethanol, dimethyl ether, biomass and other organic feedstocks, and mixtures thereof.

5. The method according to claim 1 , comprising:
providing at least one indirect heater element that protrudes into the fluidized bed; and
heating the bed material with the at least one indirect heater element to assist with startup of the fluid bed reactions;
wherein:
the at least one indirect heater element plays no role in sustaining reactions during steady state operation of the fluidized bed.

6. The method according to claim 1 , comprising:
introducing the carbonaceous material into a zone between two clusters of fuel cell elements which are spaced apart from one another within the steam reformer vessel.

7. A method of converting a carbonaceous material into a product gas comprising H2 and CO while simultaneously generating power, the method comprising:
providing an integrated system, comprising:
a gasifier chamber having a longitudinal axis, the gasifier chamber suitable for receiving a feedstock comprising a carbonaceous material and producing said product gas from the carbonaceous material; and
a plurality of fuel cell elements which protrude into the gasifier chamber, the fuel cell elements configured to conduct an exothermic reaction and provide heat sufficient to gasify said carbonaceous material and produce product gas;

introducing superheated steam as a fluidization medium into the bed material of the gasifier chamber;
introducing a carbonaceous material into a drying and devolatilization zone within the gasifier chamber; and
steam reforming the carbonaceous material with the superheated steam to produce H2 and CO in the fluidized bed and operating the fuel cell elements to create steam and heat sufficient to further steam reform said carbonaceous material, while simultaneously generating power.

8. The method according to claim 7 , comprising:
prior to operating the fuel cell elements to create heat sufficient to gasify said carbonaceous material, operating indirect heaters to bring a fluidized bed within the gasifier chamber to a temperature sufficient to gasify said carbonaceous material.

9. The method according to claim 8 , wherein:
the indirect heaters generally play no role in supplying heat to sustain gasification reactions, during steady state operation of the gasifier chamber.

10. The method according to claim 7 , directly contacting anodes of the fuel cell elements with bed material so that the H2 and CO generated in the bed are oxidized to H2O and CO2, and the H2O and CO2 react with carbonaceous material to generate H2 and CO to create a push-pull reaction environment.

Assignees

• Thermochem Recovery Int Inc

Inventors

• Chandran Ravi

Classifications

• C01B3/42

  using moving solid particles, e.g. fluidised bed technique · CPC title

• C01B2203/0283

  containing a CO-shift step, i.e. a water gas shift step · CPC title

• C01B2203/066

  with fuel cells · CPC title

• C10J2300/0916

  Biomass · CPC title

• C10J3/726

  Start-up · CPC title