Epoxy-based composition, adhesive film, dicing die-bonding film and semiconductor device

Patent metadata

Field	Value
Publication number	US-9793103-B2
Application number	US-201313915176-A
Country	US
Kind code	B2
Filing date	Jun 11, 2013
Priority date	Apr 25, 2008
Publication date	Oct 17, 2017
Grant date	Oct 17, 2017

Abstract

Provided are an epoxy composition, an adhesive film, a dicing die bonding film and a semiconductor device using the same. Specifically, the epoxy composition and a use thereof are provided, wherein the epoxy composition has a gel content of 5˜20%, measured under certain conditions. The epoxy composition according to the present invention, as an adhesive agent, shows excellent elastic properties, when prepared to have a low glass transition temperature, exhibiting good adhesion at high temperature and having minimal occurrence of burrs during processing. According to the present invention, it is therefore possible to prevent defects owing to die cut shift, during a wire bonding or molding process at high temperature, and obtain a highly reliable semiconductor device owing to the excellent adhesiveness and workability of the adhesive agent.

First claim

The invention claimed is:

1. An epoxy composition comprising:
(a) a thermoplastic resin which has an internally-crosslinked structure and is a polymer of monomers comprising (meth)acrylic acid,
(b) an epoxy resin, and
(c) a hardening agent,
wherein the epoxy composition satisfies the following general formula 1:
X =5% to 20% by weight  [General formula 1]

wherein X is the content of gel measured after drying the epoxy composition at a temperature of 110° C. for 3 minutes.

2. The epoxy composition according to claim 1 , wherein the gel content is not less than 5% by weight and less than 20% by weight.

3. The epoxy composition according to claim 1 , wherein the thermoplastic resin has a glass transition temperature of −30° C. to 50° C. before hardening.

4. The epoxy composition according to claim 1 , wherein (a) the theoplastic resin has a weight average molecular weight of 100,000 to 2,500,000.

5. The epoxy composition according to claim 1 , wherein the monomers further comprise at least one monomer selected from the group consisting of a glycidyl-group containing monomer, a hydroxyl-group containing monomer, a carboxyl-group containing monomer and a nitrile-group containing monomer.

6. The epoxy composition according to claim 1 , wherein (b) the epoxy resin has a softening temperature of 50° C. to 100° C. before hardening.

7. The epoxy composition according to claim 1 , wherein (b) the epoxy resin has an epoxy equivalent weight of 180 to 1,000.

8. The epoxy composition according to claim 1 , wherein (b) the epoxy resin is one or more selected from the group consisting of cresol novolak epoxy resins, bisphenol A novolak epoxy resins, phenol novolak epoxy resins, 4-functional epoxy resins, biphenyl epoxy resins, triphenolmethane epoxy resins, alkyl-modified triphenolmethane resins, naphthalene epoxy resins, dicyclopentadiene epoxy resins and dicyclopentadiene-modified phenol epoxy resins.

9. The epoxy composition according to claim 1 , wherein (b) the epoxy resin is comprised in an amount of 10 to 200 parts by weight, relative to 100 parts by weight of (a) the thermoplastic resin.

10. The epoxy composition according to claim 1 , wherein (c) the hardening agent is a polyfunctional phenol resin having a hydroxyl-group equivalent weight of 100 to 1,000.

11. The epoxy composition according to claim 10 , wherein (c) the hardening agent has a softening temperature of 50° C. to 150° C.

12. The epoxy composition according to claim 10 , wherein the polyfunctional phenol resin is one or more selected from the group consisting of bisphenol A resin, phenol novolak resin, cresol novolak resin, bisphenol A novolak resin, phenol aralkyl resin, multifunction novolak resin, dicyclopentadiene phenol novolak resin, amino triazine phenol novolak resin, polybutadiene phenol novolak resin and biphenyl resin.

13. The epoxy composition according to claim 1 , wherein (c) the hardening agent is comprised in an equivalent ratio of 0.4 to 2, relative to an epoxy equivalent weight of (b) the epoxy resin.

Assignees

• Lg Chemical Ltd

Inventors

• Yoo Hyun Jee
• Kho Dong Han
• Kim Jang Soon
• Park Hyo Soon
• Hong Jong Wan
• Joo Hyo Sook

Classifications

• Y10T428/31515

  As intermediate layer · CPC title

• Y10T428/287

  including epoxy group or epoxy polymer · CPC title

• C08L33/066

  containing -OH groups · CPC title

• C08L63/00

  Compositions of epoxy resins; Compositions of derivatives of epoxy resins · CPC title

• C08L33/068

  containing glycidyl groups · CPC title