Generating and maintaining conductivity of microfractures in tight formations by generating gas and heat

Patent metadata

Field	Value
Publication number	US-9790774-B2
Application number	US-201415033217-A
Country	US
Kind code	B2
Filing date	Jan 2, 2014
Priority date	Jan 2, 2014
Publication date	Oct 17, 2017
Grant date	Oct 17, 2017

Abstract

Methods for creating or enhancing a fracture in a subterranean formation include introducing a pad fluid into a formation at a rate and pressure sufficient to create or enhance at least one fracture therein. The pad fluid can include a pad base fluid, micro-proppant particulates, a gas-generating chemical, and an activator, and wherein either the gas-generating chemical or the activator or both are encapsulated. The methods can include placing the micro-proppant particulates, etc. into the fracture; releasing the activator from its encapsulation; reacting the gas-generating chemical and the activator in the fracture so as to generate gas and heat, thereby creating or enhancing at least one microfracture therein; introducing a fracturing fluid into the formation, wherein the fracturing fluid comprises a fracturing base fluid and macro-proppant particulates and placing the macroproppant particulates into the fracture so as to form a proppant pack therein.

First claim

The invention claimed is:

1. A method comprising:
(a) introducing a pad fluid into a subterranean formation at a rate and pressure sufficient to create or enhance at least one fracture therein,
wherein the pad fluid comprises a pad base fluid, micro-proppant particulates, a gas-generating chemical, and an activator, and
wherein either the gas-generating chemical or the activator or both are encapsulated;

(b) placing the micro-proppant particulates, the gas-generating chemical, and the activator into the at least one fracture;
(c) releasing either the gas-generating chemical or the activator or both from encapsulation;
(d) reacting the gas-generating chemical and the activator in the at least one fracture so as to generate gas and heat, thereby creating or enhancing at least one microfracture therein;
(e) introducing a fracturing fluid into the subterranean formation,
wherein the fracturing fluid comprises a fracturing base fluid and macro-proppant particulates; and

(f) placing the macro-proppant particulates into the at least one fracture so as to form a proppant pack therein.

2. The method of claim 1 , further comprising repeating steps (a) through (f) at a second treatment interval.

3. The method of claim 1 , wherein the micro-proppant particulates have a size in the range of from about 1 μm to about 150 μm.

4. The method of claim 1 , further comprising providing a hydrojetting tool connected to a tubular member within the subterranean formation and introducing at least one of the pad fluid and the fracturing fluid into the subterranean formation through the hydrojetting tool.

5. The method of claim 1 , further comprising providing a hydrojetting tool connected to a tubular member within the subterranean formation, so as to create an annulus between the tubular member and the subterranean formation and introducing at least one of the pad fluid and the fracturing fluid into the subterranean formation through the annulus.

6. The method of claim 1 , wherein the micro-proppant particulates are coated with a surface modification agent, the surface modification agent holding the gas-generating chemical and/or the activator onto the micro-proppant particulates.

7. The method of claim 6 , wherein the surface modification agent is selected from the group consisting of a non-aqueous tackifying agent; an aqueous tackifying agent; a silyl-modified polyamide compound; a binder; a curable resin composition; and any combination thereof.

8. The method of claim 1 , wherein the gas-generating chemical comprises a first component and a second component, the first component comprising an ammonium-containing compound and the second component comprising a nitrite-containing compound.

9. The method of claim 1 , wherein the gas-generating chemical is selected from the group consisting of an azo-based compound; a hydrazide-based compound; or any combination thereof.

10. The method of claim 1 , wherein at least one of the pad fluid and the fracturing fluid is introduced into the subterranean formation using a pump.

11. A method comprising:
(a) introducing a first pad fluid into a subterranean formation at a rate and pressure sufficient to create or enhance at least one fracture therein,
wherein the first pad fluid comprises a first pad base fluid, micro-proppant particulates, and either a gas-generating chemical or an activator;
(b) placing the micro-proppant particulates and the gas-generating chemical or the activator present in the first pad fluid into the at least one fracture;
(c) introducing a second pad fluid into the subterranean formation,
wherein the second pad fluid comprises a second pad base fluid and either of the gas-generating chemical or the activator that is not present in the first pad base fluid;

(d) reacting the gas-generating chemical and the activator in the at least one fracture so as to generate gas and heat, thereby creating or enhancing at least one microfracture therein;
(e) introducing a fracturing fluid into the subterranean formation,
wherein the fracturing fluid comprises a fracturing base fluid and macro-proppant particulates; and

(f) placing the macro-proppant particulates into the at least one fracture so as to form a proppant pack therein.

12. The method of claim 11 , further comprising repeating steps (a) through (f) at a second treatment interval.

13. The method of claim 11 , wherein either the gas-generating chemical or the activator or both are encapsulated.

14. The method of claim 11 , wherein the micro-proppant particulates have a size in the range of from about 1 μm to about 150 μm.

15. The method of claim 11 , further comprising providing a hydrojetting tool connected to a tubular member within the subterranean formation and introducing at least one of the first pad fluid, the second pad fluid, and the fracturing fluid into the subterranean formation through the hydrojetting tool.

16. The method of claim 11 , further comprising providing a hydrojetting tool connected to a tubular member within the subterranean formation, so as to create an annulus between the tubular member and the subterranean formation and introducing at least one of the first pad fluid, the second pad fluid, and the fracturing fluid into the subterranean formation through the annulus.

17. The method of claim 11 , wherein the gas-generating chemical comprises a first component and a second component, the first component comprising an ammonium-containing compound and the second component comprising a nitrite-containing compound.

18. The method of claim 11 , wherein the gas-generating chemical is selected from the group consisting of an azo-based compound; a hydrazide-based compound; or any combination thereof.

19. The method of claim 11 , wherein the micro-proppant particulates are coated with a surface modification agent, the surface modification agent holding either the gas-generating chemical or the activator onto the micro-proppant particulates.

20. The method of claim 11 , wherein at least one of the first pad fluid, the second pad fluid, and the fracturing fluid is introduced into the subterranean formation using a pump.

Assignees

• Halliburton Energy Services Inc

Inventors

• Nguyen Philip D
• Vo Loan

Classifications

• E21B43/2605

  using gas or liquefied gas · CPC title

• C09K8/592

  Compositions used in combination with generated heat, e.g. by steam injection · CPC title

• E21B43/267 Primary

  reinforcing fractures by propping · CPC title

• E21B43/26

  by forming crevices or fractures · CPC title

• C09K8/805

  Coated proppants · CPC title