Titanium or titanium alloy plate excellent in balance between press formability and strength

Patent metadata

Field	Value
Publication number	US-9790576-B2
Application number	US-200913130497-A
Country	US
Kind code	B2
Filing date	Dec 10, 2009
Priority date	Dec 12, 2008
Publication date	Oct 17, 2017
Grant date	Oct 17, 2017

Abstract

Disclosed is a titanium or titanium alloy plate rolled in one direction, wherein a lubricating film is coated on the surface and the coefficient of sliding friction of the lubricating film-coated surface is controlled to less than 0.15. The elongation (L-El) of the titanium or titanium alloy plate in the rolling direction and the r value (T-r) in the direction perpendicular to the rolling direction have the following relation (1).

( T - r )/( L - El )≧0.07  (1)

First claim

The invention claimed is:

1. A titanium or titanium alloy plate, comprising a titanium or titanium alloy base plate having been rolled in one direction and a lubrication film applied on a surface of the titanium or titanium alloy base plate,
wherein the surface of the lubrication film has a coefficient of sliding friction less than 0.15, and
wherein the titanium or titanium alloy base plate has an elongation in the rolling direction (L-El) and a r value in a direction perpendicular to the rolling direction (T-r) as determined by the ASTM E8 protocol, and wherein:
( T - r )/( L - El )≧0.07.

2. The titanium or titanium alloy plate according to claim 1 , wherein the titanium or titanium alloy base plate has a thickness of from 0.3 to 1.0 mm.

3. The titanium or titanium alloy plate according to claim 1 , wherein
0.2≧( T - r )/( L - El )≧0.07.

4. The titanium or titanium alloy plate according to claim 1 , wherein said plate is a titanium alloy plate.

5. The titanium or titanium alloy plate according to claim 1 , wherein said plate is a titanium plate.

6. The titanium or titanium alloy plate according to claim 1 , wherein the lubrication film is an alkali-soluble lubrication film comprising a surface-treating composition, and
wherein the surface-treating composition comprises a copolymer (A), a colloidal silica (B), and a wax mixture (C), wherein
the copolymer (A) is synthesized from monomer components comprising a constitutional unit (A-1) derived from an α,β-ethylenically unsaturated carboxylic acid and a constitutional unit (A-2) derived from an α,β-ethylenically unsaturated carboxylic acid ester.

7. The titanium or titanium alloy plate according to claim 1 , wherein the lubrication film is an alkali-soluble lubrication film comprising a surface-treating composition, and
wherein the surface-treating composition comprises a copolymer (A), a colloidal silica (B), and a wax mixture (C), wherein
the copolymer (A) is synthesized from monomer components comprising a constitutional unit (A-1) derived from an α,β-ethylenically unsaturated carboxylic acid and a constitutional unit (A-2) derived from an α,β-ethylenically unsaturated carboxylic acid ester,
the colloidal silica (B) has a particle size of from 40 to 50 nm, and
the wax mixture (C) comprises a spherical polyethylene wax with an average particle size of 1 μm (C-1) and a spherical polyethylene wax with an average particle size of 0.6 μm (C-2).

8. The titanium or titanium alloy plate according to claim 7 , wherein the C-2 in wax mixture (C) comprises 30 to 50 percent by mass of wax mixture C.

9. The titanium or titanium alloy plate according to claim 7 , wherein the wax C-1 has a softening point of from 113° C. to 132° C. and the wax C-2 has a softening point of from 113° C. to 132° C.

10. The titanium or titanium alloy plate according to claim 7 , wherein the surface of the alkali-soluble lubrication film has a coefficient of static friction of 0.15 or less and a coefficient of sliding friction of 0.15 or less, and wherein a value obtained by subtracting the coefficient of sliding friction from the coefficient of static friction is from −0.02 to +0.02.

11. The titanium or titanium alloy plate according to claim 7 , wherein the surface-treating composition comprises the copolymer (A) from 70 to 90 percent by mass, the colloidal silica (B) from 5 to 20 percent by mass, and the wax mixture (C) from 3.5 to 10 percent by mass, based on the total mass (100 percent by mass) of the copolymer (A), the colloidal silica (B), and the wax mixture (C).

12. The titanium or titanium alloy plate according to claim 7 , wherein A-1 is derived from methacrylic acid, and comprises from 20 to 40 percent by mass of copolymer (A).

13. The titanium or titanium alloy plate according to claim 7 , wherein the copolymer (A) has an acid value of 150 mgKOH/g or more.

14. The titanium or titanium alloy plate according to claim 7 , wherein the alkali-soluble lubrication film has a mass of coating of from 0.6 to 1.5 g/m 2 .

Assignees

• Fujita Akihisa
• Oyama Hideto
• Itsumi Yoshio
• Nakamoto Tadashige
• Yamamoto Kayo
• Kobe Steel Ltd

Inventors

• Fujita Akihisa
• Oyama Hideto
• Itsumi Yoshio
• Nakamoto Tadashige
• Yamamoto Kayo

Classifications

• B05D2502/00

  Acrylic polymers · CPC title

• C22F1/183

  of titanium or alloys based thereon · CPC title

• B05D2701/10

  withstanding draw and redraw process, punching · CPC title

• B05D7/16

  using synthetic lacquers or varnishes · CPC title

• Y10T428/31678

  Of metal · CPC title