Process for producing synthesis gas

Patent metadata

Field	Value
Publication number	US-9790433-B2
Application number	US-201715443467-A
Country	US
Kind code	B2
Filing date	Feb 27, 2017
Priority date	Mar 8, 2016
Publication date	Oct 17, 2017
Grant date	Oct 17, 2017

Abstract

A process for producing hydrocarbons is disclosed in which a first feed substream and a second feed substream are obtained from a hydrocarbonaceous feed stream, of which the first feed substream is converted by means of partial oxidation or autothermal reforming to a first synthesis gas stream and the second feed substream is converted by means of steam reforming to a second synthesis gas stream and subsequently combined with the first synthesis gas stream to give a third synthesis gas stream, of which at least a first portion is converted by Fischer-Tropsch synthesis to a crude product stream comprising hydrocarbons of different chain lengths, from which light hydrocarbons are separated in a tail gas, in order to recycle them and use them in the partial oxidation or autothermal reforming. The characteristic feature here is that unsaturated hydrocarbons are separated from at least a portion of the tail gas.

First claim

What we claim is:

1. A process for producing hydrocarbons, in which a first feed substream and a second feed substream are obtained from a hydrocarbonaceous feed stream, of which the first feed substream is converted by means of partial oxidation or autothermal reforming to a first synthesis gas stream and the second feed substream is converted by means of steam reforming to a second synthesis gas stream and subsequently combined with the first synthesis gas stream to give a third synthesis gas stream, of which at least a first portion of the third synthesis gas stream is converted by Fischer-Tropsch synthesis to a crude product stream comprising hydrocarbons of different chain lengths, from which light hydrocarbons are separated in a tail gas, in order to recycle them and use them in the partial oxidation or autothermal reforming, characterized in that unsaturated hydrocarbons are separated from at least a portion of the tail gas by a cryogenic separation method in order to obtain a stream which is substantially free of unsaturated hydrocarbons as a feed for the partial oxidation or autothermal reforming.

2. The process according to claim 1 , characterized in that the unsaturated hydrocarbons separated from the at least one portion of the tail gas are used for underfiring within the process or are released for a credit as a product for physical or thermal utilization.

3. The process according to claim 1 , characterized in that the ratio of the volume flow rates of the first feed substream and the second feed substream is set in order to set the ratio of hydrogen and carbon monoxide in the third synthesis gas stream.

4. The process according to claim 1 , characterized in that the ratio of the volume flow rates of the first synthesis gas and the second synthesis gas before the first synthesis gas and the second synthesis gas are combined to give the third synthesis gas stream is altered by branching off one or more substreams under closed-loop control, in order to set the ratio of hydrogen and carbon monoxide in the third synthesis gas stream.

5. The process according to claim 3 , characterized in that the ratio of hydrogen to carbon monoxide in the third synthesis gas stream is set to a value in the range from 1.5 to 2.5.

6. The process according to claim 1 , characterized in that the third synthesis gas stream is cooled in a cooling unit with water to raise steam which is subsequently used to generate electrical energy, and the steam, after superheating in the waste heat system of the steam reformer, is expanded in a steam turbine coupled to an electrical generator.

7. The process according to claim 1 , characterized in that the third synthesis gas stream is divided into a first synthesis gas substream and a second synthesis gas substream, and the first synthesis gas substream is used as feed for the Fischer-Tropsch synthesis, while the second synthesis gas substream is subjected to a water-gas shift reaction in order to reduce the CO content in the second synthesis gas substream and to increase the hydrogen content.

8. The process according to claim 7 , characterized in that the second synthesis gas substream, after the water-gas shift reaction, is subjected to a pressure swing adsorption to obtain a hydrogen-rich stream and a purge gas stream laden with removed gas components.

9. The process according to claim 8 , characterized in that the hydrogen-rich stream is used for hydrogenation of heavy hydrocarbons obtained in the Fischer-Tropsch synthesis and/or for desulphurization of the feed stream or one or both feed substreams.

Assignees

• Heinzel Albrecht
• Mabrouk Rachid
• Linde Ag

Inventors

• Heinzel Albrecht
• Mabrouk Rachid

Classifications

• C01B2203/0211

  containing a non-catalytic reforming step · CPC title

• C01B3/36

  using oxygen; using mixtures containing oxygen as gasifying agents · CPC title

• C10G2300/202

  Heteroatoms content, i.e. S, N, O, P · CPC title

• C10G2300/42

  Hydrogen of special source or of special composition · CPC title

• C01B2203/0255

  containing a non-catalytic partial oxidation step · CPC title