Porous material and method for producing the same

Patent metadata

Field	Value
Publication number	US-9790343-B2
Application number	US-201213558634-A
Country	US
Kind code	B2
Filing date	Jul 26, 2012
Priority date	Jun 12, 2008
Publication date	Oct 17, 2017
Grant date	Oct 17, 2017

Abstract

A method for making a composite and/or structured material includes: forming a lattice construction from a plurality of solid particles, the construction being formed so as to have one or more gaps between the particles; invading the lattice construction with a fluid material such that the fluid material at least partially penetrates the gaps; and, solidifying the material which invaded the lattice construction to form a composite material. In one suitable embodiment, the method further includes removing at least a portion of the lattice construction from the composite material thereby forming at the location of the removed portion one or more pores in the solidified material that invaded the construction.

First claim

What is claimed is:

1. A method of forming a composite material comprising:
(a) forming a first lattice construction from a first plurality of solid particles, said construction being formed so as to have one or more gaps between the first particles, said gaps being at least partially filled with a first fluid material;
(b) controlledly displacing the first fluid material with an invading fluid material such that the extent of penetration of the invading fluid material into the first lattice construction is controlled;
(c) at least partially solidifying the invading fluid material which penetrated the gaps in the first lattice construction to form a composite material;
(d) removing at least a portion of the solid particles from the composite material, thereby forming at the location of the removed portion one or more pores in the solidified invading material;
(e) forming a second lattice construction from a plurality of solid particles, said second construction being formed so as to have one or more gaps between the second particles;
(f) invading the second lattice construction with the invading fluid material such that the invading fluid material at least partially penetrates the gaps in the second lattice construction; and,
(g) at least partially solidifying the invading material which invaded the second lattice construction,
wherein step (b) includes forcing the invading fluid material into the one or more gaps between the particles of the first lattice construction,
wherein the invading fluid material is squeezed between the first and second lattice constructions,
wherein the first and second lattice constructions meet one another so that no extra invading fluid material is left un-penetrated.

2. The method of claim 1 , wherein the composite material is a filtration membrane, tissue scaffold, microfluidics, medical diagnostics, artificial paper, or make up remover.

3. The method of claim 1 , wherein the pore size is greater than 500 microns.

4. The method of claim 1 , wherein the pore size is smaller than 1 micron.

5. The method of claim 1 , wherein the first or second solid particles are a mixture of particles that vary in size, shape or chemical nature.

6. The method of claim 1 , wherein the first fluid is a mixture of fluids.

7. The method of claim 1 , wherein the invading fluid and the first fluid are not miscible.

8. The method of claim 1 , wherein the first fluid is one of a gas, solution, emulsion, suspension or foam.

9. The method of claim 1 , wherein the invading fluid is one of a gas, solution, emulsion, suspension or foam.

10. The method of claim 1 , wherein the invading fluid is solidified by at least one of UV-curing, e-beam curing, cooling or drying.

11. The method of claim 1 , wherein the first or second lattice construction has a prescribed porosity, pore size, and pore-size distribution in accordance with the defined gaps therein.

12. The method of claim 11 wherein the porosity, pore size and pore-size distribution of the first or second lattice construction is controlled by controlling at least one of a size or size distribution of the first or second plurality of particles.

13. The method of claim 11 , wherein a pore structure in the first or second lattice construction is heterogeneous, said pore structure being defined by the prescribed porosity, pore size and pore-size distribution of the first or second lattice construction.

14. The method of claim 1 , wherein the invading fluid material is provided as a single layer or multilayer film or material formed by at least one of coating, printing, extrusion, melting a film or spraying.

15. The method of claim 1 , wherein the first or second lattice construction is a single layer or multilayer construction formed by at least one of wet or dry coating, spraying, printing or phase separation.

16. The method of claim 1 , wherein at least one of a size or size-distribution of the gaps in the second lattice construction is different from that of the first lattice construction.

17. The method of claim 1 , wherein the first or second lattice construction is formed on a substrate surface in a random pattern.

18. The method of claim 1 , said method further comprising:
sizing the first or second particles by at least one of dry-milling, wet-milling, sieving, filtering, crystallization, agglomeration, granulation or palletizing.

19. The method of claim 1 , wherein the invading fluid forms at least one of an imbibition cluster or a drainage cluster.

20. The method of claim 1 , said method being executed in at least one of the following manners: a batch manner, a continuous manner, or using a step and repeat process.

21. The method of claim 1 , wherein the invading fluid material is polymeric material.

22. The method of claim 1 , wherein the first or second plurality of solid particles of the formed first or second lattice construction abut, contact, or touch one or more of their neighboring particles while forming the one or more gaps between the first or second plurality of particles.

23. The method of claim 1 , wherein forcing is applying pressure to the invading fluid.

24. The method of claim 23 , wherein the pressure is applied using at least one of a roller, a laminator, and a press.

25. The method of claim 1 , wherein forcing is applying pressure and heat to the invading fluid.

26. The method of claim 25 , wherein the pressure and heat is applied using at least one of a heated roller, a laminator, and a hot press.

27. The method of claim 1 , wherein the invading fluid fully penetrates the entire thickness of the first or second lattice construction.

28. The method of claim 1 , wherein the extent of penetration of the invading fluid into the first or second lattice construction is controlled such that the invading fluid does not fully penetrate the entire thickness of the lattice construction.

29. The method of claim 1 , wherein step (a) further includes wet-milling the plurality of solid particles in a liquid, then drying off the liquid to form the lattice construction.

30. The method of claim 29 , wherein the liquid is a non-solvent liquid.

31. The method of claim 30 , wherein the non-solvent liquid is selected from the group consisting of alcohols, esters, ketones, aromatics, aliphatics, and liquid polymers.

32. The method of claim 31 , wherein the alcohol is selected from the group consisting of isopropyl alcohol (IPA), propylene glycol, ethylene glycol, and glycerin.

33. The method of claim 1 , wherein the first fluid material is selected from the group consisting of air, alcohols, esters, ketones, aromatics, aliphatics, and liquid polymers.

34. The method of claim 33 , wherein the alcohol is selected from the group consisting of isopropyl alcohol (IPA), propylene glycol, ethylene glycol, and glycerin.

35. The method of claim 1 , wherein steb (b) further includes controlling a pressure and/or a temperature of the invading fluid material.

36. The method of claim 35 , wherein the pressure and/or temperature of the invading fluid material is controlled by at least one of a heated roller, a laminator, and a hot press.

37. The method of claim 1 , wherein the invading fluid is one of a molten polymer, a mon

Assignees

• Mehrabi Ali R
• Mehrabi Reza
• Chica Frank
• Hsiao Janet
• Desantos Avila Juan
• Avery Dennison Corp

Inventors

• Mehrabi Ali R
• Mehrabi Reza
• Chica Frank
• Hsiao Janet
• Desantos Avila Juan

Classifications

• C08J9/26 Primary

  by elimination of a solid phase from a macromolecular composition or article, e.g. leaching out · CPC title

• Y10T428/249955

  Void-containing component partially impregnated with adjacent component · CPC title