Ligand compound, a preparation method thereof, a transition metal compound, and a preparation method thereof

Patent metadata

Field	Value
Publication number	US-9790240-B2
Application number	US-201314649486-A
Country	US
Kind code	B2
Filing date	Nov 19, 2013
Priority date	Dec 11, 2012
Publication date	Oct 17, 2017
Grant date	Oct 17, 2017

Abstract

The present invention relates to a novel ligand compound, a preparation method thereof, a transition metal compound including the ligand compound, and a preparation method thereof. The ligand compound of novel structure according to the present invention and the transition metal compound including the same may be used as a polymerization reaction catalyst for preparing olefin polymers.

First claim

What is claimed is:

1. A transition metal compound, represented by the following Chemical Formula 2:

in Chemical Formula 2,
n is an integer of 1 to 2;
R 1 to R 16 are equal to or different from each other, and are independently hydrogen, a C 1 -C 20 alkyl, a C 1 -C 20 alkoxy, a C 2 -C 20 alkenyl, a C 6 -C 20 aryl, a C 7 -C 20 alkylaryl, a C 7 -C 20 arylalkyl, a C 3 -C 20 cycloalkyl, a C 5 -C 20 heteroring, or silyl, and 2 or more adjacent groups among R 1 to R 16 can be connected together via a C 1 -C 20 alkyl group or a C 6 -C 20 aryl group to form a ring;
R 17 is hydrogen, a halogen, a C 1 -C 20 alkyl, a C 6 -C 20 aryl, or a C 1 -C 20 alkoxy;
Q is carbon or silicon;
M is a Group 4 transition metal; and
X 1 and X 2 are equal to or different from each other, and are independently a halogen, a C 1 -C 20 alkyl, a C 2 -C 20 alkenyl, a C 6 -C 20 aryl, a C 7 -C 20 alkylaryl, a C 7 -C 20 arylalkyl, a C 1 -C 20 alkylamino, a C 6 -C 20 arylamino, or a C 1 -C 20 alkylidene group.

2. The transition metal compound according to claim 1 , wherein R 1 to R 16 are independently hydrogen, a C 1 -C 20 alkyl, a C 6 -C 20 aryl, a C 7 -C 20 alkylaryl, a C 7 -C 20 arylalkyl, or a C 5 -C 20 heteroring, and R 17 is a C 1 -C 20 alkyl or a C 6 -C 20 aryl.

3. The transition metal compound according to claim 1 , wherein the M is a metal selected from the group consisting Ti, Zr, and Hf.

4. The transition metal compound according to claim 1 , wherein the transition metal compound represented by Chemical Formula 2 is represented by any one of the following structural formulae:

Assignees

• Lg Chemical Ltd

Inventors

• Jang Jae Kwon
• Han Hyo Jung
• Han Ki Won
• Kim Seul Ki
• Lee Eun Jung
• Lee Choong Hoon
• Park In Sung

Classifications

• C08F4/65912

  in combination with an organoaluminium compound · CPC title

• C07F7/00

  Compounds containing elements of Groups 4 or 14 of the Periodic Table · CPC title

• C07F7/003

  without C-Metal linkages · CPC title

• C07F7/0812 Primary

  comprising a heterocyclic ring · CPC title

• C07F17/00

  Metallocenes · CPC title