Process scheme to improve divalent metal salts removal from mono ethylene glycol (MEG)

Patent metadata

Field	Value
Publication number	US-9790153-B2
Application number	US-201113295666-A
Country	US
Kind code	B2
Filing date	Nov 14, 2011
Priority date	Nov 14, 2011
Publication date	Oct 17, 2017
Grant date	Oct 17, 2017

Abstract

A MEG reclamation process includes the step of increasing above 2,000 ppm the divalent metal salts concentration of a rich (wet) MEG feed stream flowing into a precipitator. The increasing step includes routing a salts-saturated MEG slipstream from the flash separator it to the precipitator. The slipstream may be mixed with a fresh water feed stream, a portion of the rich MEG feed stream, or some combination of the two. The rich MEG feed stream also may be split into two streams, with a portion of the stream being heated and routed to the flash separator and the other portion being combined as above with the removed slipstream. The process can be performed on the slipstream after dilution and prior to entering the precipitator or after being loaded into the precipitator. Removal of the insoluble salts may be done in either a batch or continuous mode.

First claim

What is claimed is:

1. A process for removing divalent metals from a rich mono-ethylene glycol (“MEG”) feed stream, the process comprising:
removing a salt-saturated MEG stream from a liquid inventory of a flash separator;
routing a rich MEG feed stream to a precipitator upstream of the flash separator;
increasing a divalent metal salts concentration of the rich MEG feed stream by adding to the rich MEG feed stream the removed salt-saturated MEG stream recycled from the flash separator before the rich MEG feed stream enters the precipitator;
chemically reacting the increased divalent metal salt concentrated rich MEG feed stream with a precipitating agent so that insoluble salts are formed at precipitator operating conditions;
removing an insoluble salts stream from the precipitator; and
removing a divalent metal salts-saturated MEG stream from the precipitator; and
routing the divalent metal salts-saturated MEG stream into the flash separator.

2. A process according to claim 1 wherein the removed salt-saturated MEG stream is diluted before entering the precipitator to adjust at least one of a precipitator feed and a divalent salts concentration.

3. A process according to claim 1 further comprising mixing the removed salt-saturated MEG stream with at least one of a fresh water feed stream and a first portion of the rich MEG feed stream.

4. A process according to claim 1 further comprising:
splitting the rich MEG feed stream into a first portion and a second portion;
heating the second portion of the rich MEG feed stream; and
routing the heated second portion to the flash separator.

5. A process according to claim 4 further comprising the heating step occurring before the increasing step and mixing the heated second portion with the divalent metal salts-saturated MEG stream.

6. A process according to claim 1 further comprising adjusting the temperature of the removed salt-saturated MEG stream prior to the removed salt-saturated MEG stream entering the precipitator.

7. A process according to claim 1 further comprising the removing step from the flash separator being operated in a batch mode.

8. A process according to claim 7 wherein the removing step from the flash separator occurs when a divalent metal salts concentration within the flash separator reaches a preset value.

9. A process according to claim 1 further comprising the removing step from the flash separator being operated in a continuous mode.

10. A process according to claim 1 further comprising the increasing step increasing the divalent metal salts concentration to about 25,000 ppm.

11. A process according to claim 1 further comprising maintaining a divalent metal salts concentration in the flash separator below 60,000 ppm.

12. A process according to claim 11 wherein the divalent metal salts concentration is in a range of 30,000 to 50,000 ppm.

13. A process according to claim 1 further comprising preventing the precipitating agent from entering the flash separator by the step of using the precipitating agent as a limiting reactant.

14. A process according to claim 1 further comprising the increasing step including:
cooling the increased divalent metal salt concentrated rich MEG feed stream.

15. A process according to claim 1 further comprising the increasing step including heating the increased divalent metal salt concentrated rich MEG feed stream.

16. A process for removing divalent metals from a rich mono-ethylene glycol (“MEG”) feed stream, the process comprising:
removing a salt-saturated MEG stream from a liquid inventory of a flash separator;
routing the removed salt-saturated MEG stream into a precipitator upstream of the flash separator;
chemically reacting the removed salt-saturated MEG stream in the precipitator with a precipitating agent so that insoluble salts are formed at precipitator operating conditions;
removing an insoluble salts stream from the precipitator; and
removing a lower salt-saturated MEG stream from the precipitator, the lower salt-saturated MEG stream having a lower salt concentration than the salt-saturated MEG stream removed from the liquid inventory of the flash separator; and
routing the removed lower salt-saturated MEG stream into the flash separator.

17. A process for removing divalent metals from a rich mono-ethylene glycol (“MEG”) feed stream, the process comprising:
increasing a divalent metal salts concentration of a rich MEG feed stream when the rich MEG feed stream enters a precipitator vessel by adding to the rich MEG feed stream a salt-saturated MEG stream removed from a downstream flash separator arranged to receive a lean MEG stream exiting the precipitator vessel.

Assignees

• Caires Fernandez Luis Eduardo
• Cameron Int Corp

Inventors

• Caires Fernandez Luis Eduardo

Classifications

• B01D2257/204

  Inorganic halogen compounds · CPC title

• C07C29/76 Primary

  by physical treatment · CPC title

• B01D1/30

  Accessories for evaporators {; Constructional details thereof} · CPC title

• B01D9/0063

  Control or regulation (control per se G05) · CPC title

• C07C31/202

  Ethylene glycol · CPC title