Process for purifying (hydro)fluoroalkenes

Patent metadata

Field	Value
Publication number	US-9790152-B2
Application number	US-201715407871-A
Country	US
Kind code	B2
Filing date	Jan 17, 2017
Priority date	Oct 15, 2009
Publication date	Oct 17, 2017
Grant date	Oct 17, 2017

Abstract

A process for removing one or more undesired (hydro)halocarbon compounds containing a ═CF 2 moiety from a (hydro)fluoroalkene that does not contain a ═CF 2 moiety, the process comprising contacting a composition comprising the (hydro)fluoroalkene and one or more undesired (hydro)halocarbon compounds with an aluminum-containing absorbent, activated carbon, or a mixture thereof, wherein the or each undesired (hydro)halocarbon compound is present in an amount of from about 0.1 to about 1000 ppm, based on the weight of the composition comprising the R-1234yf and one or more undesired (hydro)halocarbon compounds.

First claim

We claim:

1. A process for removing one or more undesired (hydro)halocarbon compounds containing a ═CF 2 moiety from a (hydro)fluoroalkene that does not contain a ═CF 2 moiety, the process comprising contacting a composition comprising the (hydro)fluoroalkene and one or more undesired (hydro)halocarbon compounds with an aluminium-containing adsorbent, activated carbon, or a mixture thereof,
wherein the or each undesired (hydro)halocarbon compound is present in an amount of from about 0.1 to about 1000 ppm, based on the weight of the composition comprising the (hydro)fluoroalkene and one or more undesired (hydro)halocarbon compounds.

2. The process according to claim 1 wherein the (hydro)fluoroalkene is a C 3-7 (hydro)fluoroalkene.

3. The process according to claim 2 wherein the C 3-7 (hydro)fluoroalkene is a hydrofluoropropene.

4. The process according to claim 3 wherein the hydrofluoropropene is a trifluoropropene or a tetrafluoropropene.

5. The process according to claim 4 wherein the trifluoropropene is 3,3,3-trifluoropropene (R-1243zf).

6. The process according to claim 4 wherein the tetrafluoropropene is E/Z-1,3,3,3-tetrafluoropropene (R-1234ze) or 2,3,3,3-tetrafluoropropene (R-1234yf).

7. The process according to claim 1 wherein the or each (hydro)halocarbon is selected from the group consisting of (hydro)fluoroalkenes and (hydro)chlorofluorocarbon (CFC) species.

8. The process according to claim 1 wherein the aluminium-containing adsorbent is porous and comprises alumina or aluminosilicate.

9. The process according to claim 8 wherein the alumina comprises acidic functionality.

10. The process according to claim 8 wherein the aluminosilicate is a molecular sieve having pore sizes in the range 3 to 12 Angstroms.

11. The process according to claim 1 wherein the activated carbon is impregnated with an additive selected from the group consisting of a metal, a metal compound, a base and a mixture thereof.

12. The process according to claim 11 wherein the additive is an alkali metal salt.

13. The process according to claim 12 wherein the alkali metal salt is a base.

14. The process according to claim 1 wherein following the contacting step, the resulting composition comprises the (hydro)fluoroalkene and from about 0 to about 10 ppm of die or each undesired (hydro)halocarbon compounds.

15. The process according to claim 1 wherein the composition comprising the (hydro)fluoroalkene and one or more undesired (hydro)halocarbon compounds is a product stream from a process for producing the (hydro)fluoroalkene.

16. The process for removing one or more undesired (hydro)halocarbon compounds from a (hydro)fluoroalkene according to claim 15 , wherein the process is combined with one or more additional purification steps.

17. The process according to claim 7 , wherein the (hydro)chlorofluorocarbon (CFC) species is a (hydro)chlorofluoroalkene.

18. The process according to claim 10 , wherein the molecular sieve is a zeolite.

Assignees

• Mexichem Amanco Holding Sa

Inventors

• Sharratt Andrew P
• Mcguinness Claire E
• Hayes John

Classifications

• C07C17/25

  by splitting-off hydrogen halides from halogenated hydrocarbons · CPC title

• C07B63/00

  Purification; Separation (separation of optically-active compounds C07B57/00); Stabilisation; Use of additives · CPC title

• C07C17/23

  by dehalogenation · CPC title

• C07C17/389 Primary

  by adsorption on solids · CPC title

• C07C17/206

  the other compound being HX · CPC title