Method to generate high LSG low-emissivity coating with same color after heat treatment

Patent metadata

Field	Value
Publication number	US-9790127-B2
Application number	US-201313804766-A
Country	US
Kind code	B2
Filing date	Mar 14, 2013
Priority date	Mar 14, 2013
Publication date	Oct 17, 2017
Grant date	Oct 17, 2017

Abstract

Low emissivity panels can include a separation layer of Zn 2 SnO x between multiple infrared reflective stacks. The low emissivity panels can also include NiNbTiO x as barrier layer. The low emissivity panels have high light to solar gain, color neutral, together with similar observable color before and after a heat treatment process.

First claim

What is claimed is:

1. A coated article including a coating supported by a glass substrate, the coating comprising at least the following layers moving away from the glass substrate:
a layer comprising zinc, tin, and oxygen having a thickness between 10 nm and 40 nm;
a seed layer comprising zinc oxide;
an infrared (IR) reflecting layer comprising silver located on and directly contacting the seed layer comprising zinc oxide,
a barrier layer located on and directly contacting the first IR reflecting layer, the barrier layer comprising nickel, niobium, titanium and oxygen, wherein the oxygen content of the barrier layer is from 10 to 30 atomic %,
another layer comprising zinc, tin and oxide over at least the barrier layer;
another IR reflecting layer comprising silver located over at least the another layer comprising zinc, tin oxide;
a first layer comprising silicon nitride located over at least the another IR reflecting layer; and
a layer comprising tin oxide and a second layer comprising silicon nitride located over said first layer comprising silicon nitride, wherein the layer comprising tin oxide is located between and directly contacting the first layer comprising silicon nitride and the second layer comprising silicon nitride, and wherein the second layer comprising silicon nitride is located further from the glass substrate than any of the other recited layers of the coating.

2. The coated article as in claim 1 wherein the light-to-solar gain (LSG) value of the coated article is greater than 1.8.

3. The coated article of claim 1 , wherein the coated article is heat treated.

4. A heat treated coated article including a low-E coating supported by a glass substrate, the low-E coating comprising at least the following layers from the glass substrate outwardly:
a first layer over at least the glass substrate, wherein the first layer comprises zinc tin oxide and has a thickness between 10 nm and 40 nm;
a second layer formed over the first layer, wherein the second layer comprises zinc oxide and has a thickness between 3 nm and 10 nm;
a third layer formed over the second layer, wherein the third layer comprises silver and has a thickness between 8 nm and 12 nm;
a fourth layer formed over the third layer, wherein the fourth layer comprises nickel, niobium, titanium and oxygen and has a thickness between 1 nm and 5 nm, wherein the oxygen content of the fourth layer is from 10 to 30 atomic %;
a fifth layer formed over the fourth layer, wherein the fifth layer comprises zinc tin oxide in contact with the fourth layer and has a thickness between 50 nm and 100 nm;
a sixth layer formed over the first through fifth layers, wherein the sixth layer comprises zinc oxide and has a thickness between 3 nm and 10 nm;
a seventh layer formed above the sixth layer, wherein the seventh layer comprises silver in contact with the sixth layer and has a thickness between 14 nm and 18 nm;
an eighth layer formed above the seventh layer, wherein the eighth layer comprises nickel, niobium, titanium and oxygen and has a thickness between 1 nm and 5 nm, wherein the oxygen content of the eighth layer is from 10 to 30 atomic %;
a ninth layer formed above the eighth layer, wherein the ninth layer comprises zinc tin oxide and has a thickness between 10 nm and 40 nm;
wherein the coated article, measured monolithically, has a visible transmission of at least 80%; and
wherein the coated article has a glass side reflective AE* value of no greater than 1.6 and a transmissive AE* value of no greater than 1.5 due to the heat treatment which was at at least 580 degrees C.

5. The coated article as in claim 4 wherein the thickness of the first layer is 20 nm, the thickness of the fifth layer is 80 nm, and the thickness of the ninth layer is 20 nm.

6. The coated article as in claim 4 wherein the thickness of the third layer is 10 nm, and the thickness of the seventh layer is 16 nm.

7. The coated article as in claim 4 further comprising:
a tenth layer formed between the substrate and the first layer, wherein the tenth layer comprises silicon nitride and has a thickness between 10 nm and 30 nm; and
an eleventh layer formed above the ninth layer, wherein the eleventh layer comprises silicon nitride and has a thickness between 10 nm and 30 nm.

8. A heat treated coated article comprising:
a substrate;
a first layer formed directly on the substrate, wherein the first layer comprises silicon nitride and has a thickness of between 10 nm and 30 nm;
a second layer formed directly on the first layer, wherein the second layer comprises zinc tin oxide and has a thickness between 10 nm and 40 nm;
a third layer formed directly on the second layer, wherein the third layer comprises zinc oxide and has a thickness between 3 nm and 10 nm;
a fourth layer formed directly on the third layer, wherein the fourth layer comprises silver and has a thickness between 8 nm and 12 nm;
a fifth layer formed directly on the fourth layer, wherein the fifth layer comprises nickel niobium titanium oxide and has a thickness between 1 nm and 5 nm, wherein the oxygen content of the fifth layer is from 10 to 30 atomic %;
a sixth layer formed directly on the fifth layer, wherein the sixth layer comprises zinc tin oxide and has a thickness between 50 nm and 100 nm;
a seventh layer formed directly on the sixth layer, wherein the seventh layer comprises zinc oxide and has a thickness between 3 nm and 10 nm;
an eighth layer formed directly on the seventh layer, wherein the eighth layer comprises silver and has a thickness between 14 nm and 18 nm;
an ninth layer formed directly on the eighth layer, wherein the ninth layer comprises nickel niobium titanium oxide and has a thickness between 1 nm and 5 nm;
a tenth layer formed directly on the ninth layer, wherein the tenth layer comprises zinc tin oxide and has a thickness between 10 nm and 40 nm;
an eleventh layer formed directly on the tenth layer, wherein the eleventh layer comprises silicon nitride and has a thickness of between 10 nm and 30 nm;
wherein the coated article, measured monolithically, has a visible transmission of at least 80%; and
wherein the coated article has a glass side reflective AE* value of no greater than 1.6 and a transmissive AE* value of no greater than 1.5 due to the heat treatment which was at at least 580 degrees C.

9. The coated article as in claim 8 wherein the second layer has a thickness of 20 nm, the sixth layer has a thickness of 80 nm, and the tenth layer has a thickness of 20 nm.

10. The coated article as in claim 8 wherein each of the third layer and the seventh layer has a thickness of 5 nm, each of the fifth layer and the ninth layer has a thickness of 3 nm, and each of the first layer and the eleventh layer has a thickness of 20 nm.

11. The coated article as in claim 8 wherein the fourth layer has a thickness of 10 nm and the eighth layer has a thickness of 16 nm.

Assignees

• Intermolecular Inc
• Guardian Industries
• Intermolecular Inc
• Guardian Glass Llc

Inventors

• Ding Guowen
• Cheng Jeremy
• Ju Tong
• Le Minh Huu
• Lingle Phil
• Schweigert Daniel
• Sun Zhi-Wen Wen
• Zhang Guizhen

Classifications

• C03C17/3639 Primary

  Multilayers containing at least two functional metal layers · CPC title

• Y10T428/24975

  No layer or component greater than 5 mils thick · CPC title

• C03C17/36

  at least one coating being a metal · CPC title

• C03C17/366 Primary

  Low-emissivity or solar control coatings · CPC title

• C03C17/3652

  the coating stack containing at least one sacrificial layer to protect the metal from oxidation · CPC title