Processes and treatment systems for treating high phosphorous containing fluids

Patent metadata

Field	Value
Publication number	US-9790110-B2
Application number	US-201514665229-A
Country	US
Kind code	B2
Filing date	Mar 23, 2015
Priority date	Mar 25, 2014
Publication date	Oct 17, 2017
Grant date	Oct 17, 2017

Abstract

Disclosed herein are processes for treating high-P fluid involving (1) providing a high-P containing stream; (2) chemically treating the high-P stream such that a majority of dissolved P in the stream is transformed into a solid form via sorption of P onto particles placed or precipitated within the stream; and (3) removing the solid form containing P from the chemically treated fine solids stream, such that >about 90% of the total P is removed from the high-P fluid. Also disclosed are systems for treating a high-P stream, the systems involving (1) a chemical treatment station operable to chemically treat and transform equal to or greater than about 90% of dissolved P in a high-P stream into a solid form; and (2) a liquid-solid separator station operable to remove the solid form containing P from the chemically treated high-P stream.

First claim

We claim:

1. A process for treating high-phosphorus containing fluid, said method comprising:
(a) providing a high-phosphorus containing fluid wherein said fluid contains dissolved phosphorus and water;
(b) removing any bulk solids in said high-phosphorus containing fluid that are greater than or equal to 30 μm in diameter if said high-phosphorus containing fluid contains bulk solids greater than or equal to 30 μm in diameter;
(c) chemically treating said high-phosphorus containing fluid with iron sulfate and optionally at least one chemical selected from the group consisting of iron chloride, iron oxyhydroxide, aluminum sulfate, aluminum chlorhydrate, calcium oxide, calcium hydroxide, and mixtures thereof such that a majority of dissolved phosphorus in said high-phosphorus containing fluid is transformed into a solid form via sorption of phosphorus onto particles formed from the reaction of said chemical with said water or via sorption of phosphorus onto any solids equal to or greater than 1 μm within said high-phosphorus containing fluid; and
(d) removing said solid form and any other solids equal to or greater than 1 μm from said high-phosphorus containing fluid, such that ≧about 90% of the total phosphorus is removed from said high-phosphorus containing fluid; wherein said process does not involve the removal of nitrogen from said high-phosphorus containing fluid as a first step and said process does not involve a bioreactor; wherein the nitrogen:phosphorus ratio of said high-phosphorus containing fluid after step (d) is at least about 8:1.

2. The process of claim 1 , wherein said bulk solids are removed with an auger press.

3. The process of claim 1 , further including composting said bulk solids.

4. The process of claim 1 , further including blending said bulk solids with said solid form to produce fertilizer.

5. The process of claim 1 , wherein said bulk solids are removed with a centrifuge.

6. The process of claim 1 , wherein said high-phosphorus containing fluid is chemically treated using a batch process.

7. The process of claim 1 , wherein said high-phosphorus containing fluid is chemically treated using a continuous process.

8. The process of claim 1 , wherein said chemically treating includes coagulating said solid form.

9. The process of claim 8 , wherein said coagulating includes adding a polymer coagulate to said solid form.

10. The process of claim 1 , said process comprising (b) removing any bulk solids in said high-phosphorus containing fluid that are greater than or equal to 25 μm in diameter if said high-phosphorus containing fluid contains bulk solids greater than or equal to 25 μm in diameter.

11. The process of claim 1 , wherein the pH of said process is circumneutral.

12. The process of claim 1 , wherein said high-phosphorus containing fluid in (a) contains solids.

13. The process of claim 1 , wherein said high-phosphorus containing fluid in (a) contains animal manure.

14. The process of claim 1 , wherein said high-phosphorus containing fluid in (a) contains acid whey from a yogurt manufacturing facility.

15. The process of claim 1 , wherein the nitrogen:phosphorus ratio of said high-phosphorus containing fluid after step (d) is at least 19:1.

16. The process of claim 1 , said process comprising (c) chemically treating said high-phosphorus containing fluid with iron sulfate and at least one chemical selected from the group consisting of iron chloride, iron oxyhydroxide, aluminum sulfate, aluminum chlorhydrate, calcium oxide, calcium hydroxide, and mixtures thereof.

17. The process of claim 1 , said process comprising (d) removing said solid form and any other solids equal to or greater than 1 μm from said high-phosphorus containing fluid, such that ≧about 95% of the total phosphorus is removed from said high-phosphorus containing fluid.

18. The process of claim 1 , said process comprising (d) removing said solid form and any other solids equal to or greater than 1 μm from said high-phosphorus containing fluid, such that 97% of the total phosphorus is removed from said high-phosphorus containing fluid.

19. A process for treating high-phosphorus containing fluid, said method comprising:
(a) providing a high-phosphorus containing fluid wherein said fluid contains dissolved phosphorus and water;
(b) removing any bulk solids in said high-phosphorus containing fluid that are greater than or equal to 30 μm in diameter if said high-phosphorus containing fluid contains bulk solids greater than or equal to 30 μm in diameter;
(c) chemically treating said high-phosphorus containing fluid with iron sulfate and at least one chemical selected from the group consisting of iron chloride, iron oxyhydroxide, aluminum sulfate, aluminum chlorhydrate, calcium oxide, calcium hydroxide, and mixtures thereof such that a majority of dissolved phosphorus in said high-phosphorus containing fluid is transformed into a solid form via sorption of phosphorus onto particles formed from the reaction of said chemical with said water or via sorption of phosphorus onto any solids equal to or greater than 1 μm within said high-phosphorus containing fluid; and
(d) removing said solid form and any other solids equal to or greater than 1 μm from said high-phosphorus containing fluid, such that ≧about 90% of the total phosphorus is removed from said high-phosphorus containing fluid; wherein said process does not involve the removal of nitrogen from said high-phosphorus containing fluid as a first step and said process does not involve a bioreactor; wherein the nitrogen:phosphorus ratio of said high-phosphorus containing fluid after step (d) is about 8:1.

20. A process for treating high-phosphorus containing fluid, said method consisting of:
(a) providing a high-phosphorus containing fluid wherein said fluid contains dissolved phosphorus and water;
(b) removing any bulk solids in said high-phosphorus containing fluid that are greater than or equal to 30 μm in diameter if said high-phosphorus containing fluid contains bulk solids greater than or equal to 30 μm in diameter;
(c) chemically treating said high-phosphorus containing fluid with iron sulfate and optionally at least one chemical selected from the group consisting of iron chloride, iron oxyhydroxide, aluminum sulfate, aluminum chlorhydrate, calcium oxide, calcium hydroxide, and mixtures thereof such that a majority of dissolved phosphorus in said high-phosphorus containing fluid is transformed into a solid form via sorption of phosphorus onto particles formed from the reaction of said chemical with said water or via sorption of phosphorus onto any solids equal to or greater than 1 μm within said high-phosphorus containing fluid; and
(d) removing said solid form and any other solids equal to or greater than 1 μm from said high-phosphorus containing fluid, such that ≧about 90% of the total phosphorus is removed from said high-phosphorus containing fluid; wherein said process does not involve the removal of nitrogen from said high-phosphorus containing fluid as a first step and said process does not involve a bioreactor; wherein the nitrogen:phosphorus ratio of said high-phosphorus containing fluid after step (d) is about 8:1.

Assignees

• Us Agriculture
• Pennsylvania State Univ
• The Us Sectary Of Agriculture
• Penn State Res Found

Inventors

• Church Clinton
• Bryant Ray B
• Kleinman Peter J
• Hristov Alex

Classifications

• C02F11/121

  by mechanical de-watering · CPC title

• C02F1/44

  by dialysis, osmosis or reverse osmosis {(general membrane separation processes B01D61/00, membrane modules B01D63/00, electrodialysis C02F1/4693, combination of membrane modules and bioreactors C02F3/1268)} · CPC title

• C02F1/56

  Macromolecular compounds · CPC title

• B01J20/046

  containing halogens, e.g. halides · CPC title

• B01J20/0229

  Compounds of Fe · CPC title