Thermosensitive recording medium

Patent metadata

Field	Value
Publication number	US-9789721-B2
Application number	US-201414889661-A
Country	US
Kind code	B2
Filing date	May 20, 2014
Priority date	May 22, 2013
Publication date	Oct 17, 2017
Grant date	Oct 17, 2017

Abstract

A primary object of the present invention is to provide a thermosensitive recording material that achieves high recording density and excellent preservability of a recorded part, or to provide a thermosensitive recording material that achieves high recording density, and excellent heat resistant and resistance to thermal background fogging property in a high temperature environment, as well as excellent sticking resistance and resistance to dirt adhesion of head.
The present invention is a thermosensitive recording material having a thermosensitive recording layer containing at least a leuco dye and a developer on a support; the thermosensitive recording material containing, as the developer, a sulfonamide compound represented by general formula (1); (a) the thermosensitive recording material further having a protective layer on the thermosensitive recording layer; the protective layer containing at least one type of adhesive agent selected from the group consisting of water soluble adhesive agents and water dispersible adhesive agents; and at least one of the thermosensitive recording layer or the protective layer containing a water resistance-imparting agent; or (b) the thermosensitive recording layer further containing saturated fatty acid amide represented by general formula (2).

First claim

What is claimed is:

1. A thermosensitive recording material having a thermosensitive recording layer containing at least a leuco dye and a developer on a support; the thermosensitive recording material containing, as the developer, a sulfonamide compound represented by general formula (1) below:

in formula (1), R1 and R2 may be the same or different and each independently represent a hydrogen atom, an alkyl group having from 1 to 4 carbons, an alkoxy group having from 1 to 4 carbons, or a halogen atom;
(a) the thermosensitive recording material further having a protective layer on the thermosensitive recording layer; the protective layer containing an adhesive agent; the adhesive agent being diacetone-modified polyvinyl alcohol; at least one of the thermosensitive recording layer or the protective layer containing a water resistance-imparting agent; and the water resistance-imparting agent being a hydrazide compound;
or
(b) the thermosensitive recording layer further containing saturated fatty acid amide represented by general formula (2):
[Formula 2]
R—CONH 2   (2)

in formula (2), R represents an alkyl group having from 15 to 21 carbons; and the thermosensitive recording layer further containing, as a sensitizer, from 1 to 9 parts by mass of 1,2-di(3-methylphenoxy)ethane per 1 part by mass of the saturated fatty acid amide.

2. The thermosensitive recording material according to claim 1 , wherein the sulfonamide compound represented by general formula (1) is N-[2-(3-phenylureido)phenyl]benzenesulfonamide.

3. The thermosensitive recording material according to claim 1 , wherein the thermosensitive recording layer (a) further contains at least one type of sensitizer selected from the group consisting of 2-naphthyl benzyl ether, di-p-chlorobenzyl oxalate, di-p-methylbenzyl oxalate, 1,2-di(3-methylphenoxy)ethane, 1,2-diphenoxyethane, and diphenyl sulfone.

4. The thermosensitive recording material according to claim 3 , wherein, per 1 part by mass of the saturated fatty acid amide, from 1 to 9 parts by mass of at least one type of sensitizer selected from the group consisting of 2-naphthyl benzyl ether, di-p-chlorobenzyl oxalate, di-p-methylbenzyl oxalate, 1,2-di(3-methylphenoxy)ethane, 1,2-diphenoxyethane, and diphenyl sulfone is contained.

5. The thermosensitive recording material according to claim 1 , wherein a degree of saponification of the modified polyvinyl alcohol is from 85 to 100 mol%.

6. The thermosensitive recording material according to claim 1 , wherein a degree of polymerization of the diacetone-modified polyvinyl alcohol is from 400 to 3000.

7. The thermosensitive recording material according to claim 1 , wherein the hydrazide compound is contained in the thermosensitive recording layer.

8. The thermosensitive recording material according to claim 1 , wherein the saturated fatty acid amide is at least one type selected from the group consisting of palmitic acid amide, stearic acid amide, arachidic acid amide, and behenic acid amide.

9. The thermosensitive recording material according to claim 1 , wherein the saturated fatty acid amide is stearic acid amide.

10. The thermosensitive recording material according to claim 1 , further comprising an undercoat layer containing hollow plastic particles, the undercoat layer being arranged in between the support and the thermosensitive recording layer.

11. The thermosensitive recording material according to claim 1 , further comprising an undercoat layer formed by a blade coating method, the undercoat layer being arranged in between the support and the thermosensitive recording layer.

12. The thermosensitive recording material according to claim 1 , wherein at least one layer that is formed on the support is formed by a curtain coating method.

13. The thermosensitive recording material according to claim 1 , wherein a content of the sulfonamide compound represented by the general formula (1) is from 0.3 to 5 parts by mass per 1 part by mass of the leuco dye.

Assignees

• Oji Holdings Corp

Inventors

• Takano Suguru
• Yamane Kazuo
• Endo Naotaka
• Sakamoto Kazuyuki

Classifications

• B41M5/323

  Organic colour formers, e.g. leuco dyes · CPC title

• B41M5/3336 Primary

  Sulfur compounds, e.g. sulfones, sulfides, sulfonamides · CPC title

• B41M5/3375

  Non-macromolecular compounds · CPC title

• B41M5/423

  characterised by non-macromolecular compounds, e.g. waxes · CPC title

• B41M2205/38

  Intermediate layers; Layers between substrate and imaging layer · CPC title