Degradable metal composites, methods of manufacture, and uses thereof

Patent metadata

Field	Value
Publication number	US-9789663-B2
Application number	US-201414151081-A
Country	US
Kind code	B2
Filing date	Jan 9, 2014
Priority date	Jan 9, 2014
Publication date	Oct 17, 2017
Grant date	Oct 17, 2017

Abstract

A metal composite comprises: a first matrix comprising magnesium, a magnesium alloy, or a combination thereof; a second matrix comprising aluminum, an aluminum alloy, steel, a zinc alloy, a tin alloy, or a combination comprising at least one of the foregoing; a corrosion reinforcement material; and a boundary layer disposed between the first matrix and the second matrix; wherein the boundary layer has a thickness of 10 nm to 200 μm.

First claim

The invention claimed is:

1. A metal composite comprising:
a first matrix comprising magnesium, a magnesium alloy, or a combination thereof;
a second matrix compositionally different from the first matrix and comprising aluminum, an aluminum alloy, steel, a zinc alloy, a tin alloy, or a combination comprising at least one of the foregoing;
a corrosion reinforcement material dispersed in the first matrix, the second matrix, or both the first matrix and the second matrix; the corrosion reinforcement material comprising Fe, Ni, Co, Cu, W, Si, Al, Zn, alloys thereof, or a combination comprising at least one of the foregoing; and
a boundary layer disposed between the first matrix and the second matrix;
wherein the boundary layer has a thickness of 10 nm to 200 μm and comprises an intermetallic compound formed from the magnesium or magnesium alloy of the first matrix and a metal or metal alloy of the second matrix.

2. The metal composite of claim 1 , wherein the first matrix comprises a magnesium alloy selected from Mg—Al alloy, Mg—Zn alloy, Mg—Mn alloy, Mg-rare earth metals alloy, Mg—Zn—Y alloy, and a combination comprising at least one of the foregoing alloys.

3. The metal composite of claim 1 , wherein the second matrix comprises Al—Cu alloy, Al—Mn alloy, Al—Si alloy, Al—Mg alloy, Al—Mg—Si alloy, Al—Zn alloy, Al—Li alloy, Al—Cu—Mg—X alloy, Al—Zn—Mg—Cu—X, or a combination comprising at least one of the foregoing, wherein X is Zn, Mn, Si, Cr, Fe, Ni, Ti, V, Cu, Pb, Bi, Zr, or a combination comprising at least one of the foregoing.

4. The metal composite of claim 1 , wherein the corrosion reinforcement material is dispersed in the first matrix.

5. The metal composite of claim 1 , wherein the boundary layer consists of the magnesium or magnesium alloy of the first matrix, the metal or metal alloy of the second matrix, and an intermetallic compound formed from the magnesium or magnesium alloy of the first matrix and the metal or metal alloy of the second matrix.

6. The metal composite of claim 1 , wherein the boundary layer further comprises the corrosion reinforcement material.

7. The metal composite of claim 1 , wherein the first matrix comprises magnesium, the second matrix comprises aluminum, and the boundary layer comprises aluminum, Al 3 Mg 2 , Al 12 Mg 17 , and magnesium.

8. The metal composite of claim 1 , wherein the first matrix comprises a magnesium alloy, the second matrix comprises an aluminum alloy, and the boundary layer comprises the magnesium alloy, the aluminum alloy, (aluminum alloy) 49 Mg 32 , Al 3 Mg 2 , Al 12 Mg 17 , and the magnesium alloy.

9. The metal composite of claim 1 , wherein the boundary layer has a thickness of 1 to 50 μm.

10. The metal composite of claim 9 , wherein the metal composite comprises 5 to 95 volume percent of the first matrix, and 95 to 5 volume percent of the second matrix, each based on the total volume of the metal composite.

11. The metal composite of claim 10 , wherein the metal composite comprises 0.01 to 10 wt. % of the corrosion reinforcement material, based on the total weight of the metal composite.

12. The metal composite of claim 1 , wherein the boundary layer is substantially continuous.

13. The metal composite of claim 1 , wherein the boundary layer is continuous and the first matrix and the second matrix are discontinuous.

14. The metal composite of claim 1 , wherein the second matrix comprises an aluminum alloy, steel, a zinc alloy, a tin alloy, or a combination comprising at least one of the foregoing.

15. The metal composite of claim 1 , wherein the first matrix, the second matrix or both the first matrix and the second matrix further comprise a secondary phase, the second phase comprising carbides, nitrides, oxides, precipitates, dispersoids, or a combination comprising at least one of the foregoing.

16. The metal composite of claim 1 , wherein the first matrix comprises a magnesium alloy, the second matrix comprises an aluminum alloy, and the boundary layer consists of the magnesium alloy, the aluminum alloy, and one or more intermetallic compound formed from the magnesium or magnesium alloy of the first matrix and the aluminum or aluminum alloy of the second matrix.

17. A metal composite comprising:
10 to 90 volume percent of first matrix comprising a magnesium alloy based on the total volume of the metal composite;
90 to 10 volume percent of a second matrix compositionally different from the first matrix and comprising an aluminum alloy based on the total volume of the metal composite;
0.01 to 10 wt % of a corrosion reinforcement material comprising Fe, Ni, Co, Cu, W, Si, Zn, alloys thereof, or a combination comprising at least one of the foregoing, based on the total weight of the metal composite; the corrosion reinforcement material dispersed in the first matrix, the second matrix, or both the first matrix and the second matrix and
a boundary layer disposed between the first matrix and the second matrix; the boundary layer having a thickness of 1 micron to 50 microns and comprising an intermetallic compound formed from magnesium or the magnesium alloy of the first matrix and aluminum or the aluminum alloy of the second matrix.

18. The metal composite of claim 17 , wherein the corrosion reinforcement material is further disposed between the boundary layer and the first matrix.

19. The metal composite of claim 17 , wherein the corrosion reinforcement material is further disposed between the boundary layer and the second matrix.

20. The metal composite of claim 17 , wherein the corrosion reinforcement material is dispersed in the first matrix.

21. The metal composite of claim 17 , wherein the corrosion reinforcement material is dispersed in the first matrix.

22. The metal composite of claim 17 , wherein the boundary layer consists of the magnesium alloy, the aluminum alloy, and the intermetallic compound.

23. The metal composite of claim 17 , wherein the boundary layer is substantially continuous.

24. The metal composite of claim 17 , wherein the metal composite comprises 0.1 to 6 wt. % of the corrosion reinforcement material, based on the total weight of the metal composite.

25. A method of making a metal composite according to claim 1 , the method comprising:
dispersing a corrosion reinforcement material in a first metallic component, a second metallic component or both; wherein the first metallic component comprises a plurality of particles of magnesium, a magnesium alloy, or a combination thereof; and the second metallic component comprises a plurality of particles of aluminum, an aluminum alloy, steel, a zinc alloy, a tin alloy, or a combination comprising at least one of the foregoing;
combining the first metallic component with the second metallic component; and
applying a predetermined temperature to the combination thereby forming a metal composite according to claim 1 .

26. The method of claim 25 , wherein the predetermined temperature is a temperature less than the melting temperature of the first metallic component and the melting temperature of the second metallic component.

27. The method of claim 25 , comprising applying a predetermined temperature of 300 to 500° C. for up to 8 hours to the combination.

Assignees

• Zhang Zhihui
• Xu Zhiyue
• Baker Hughes Inc

Inventors

• Zhang Zhihui
• Xu Zhiyue

Classifications

• B22F1/16

  Metallic particles coated with a non-metal (coated with lubricating or binding agents or with organic material B22F1/10) · CPC title

• C22C23/00

  Alloys based on magnesium · CPC title

• Y10T428/12708

  Sn-base component · CPC title

• C22C21/12

  with copper as the next major constituent · CPC title

• B32B15/01 Primary

  all layers being exclusively metallic {(making layered metal workpieces by pressure cladding B23K20/22; making coatings with a metallic material characterised by its composition C23C30/00)} · CPC title