Method for producing ultrafine tungsten powder

Patent metadata

Field	Value
Publication number	US-9789538-B2
Application number	US-201314652163-A
Country	US
Kind code	B2
Filing date	Sep 20, 2013
Priority date	Dec 17, 2012
Publication date	Oct 17, 2017
Grant date	Oct 17, 2017

Abstract

A method for finely powdering tungsten powder, which includes: a process for classifying a material tungsten powder into a fine powder having a relatively small average particle diameter and a coarse powder having a relatively large average particle diameter; an oxidation process for forming an oxide film on the particle surface of the coarse powder; and an alkali treatment process for removing the oxide film formed in the oxidation process and a natural oxide film formed on the fine powder with an alkali aqueous solution. Also disclosed is a method for producing ultrafine tungsten powder, which includes obtaining tungsten powder having an average particle diameter of 0.04 to 0.4 μm and a BET specific surface area of 5 to 15 m 2 /g by the above method for finely powdering.

First claim

The invention claimed is:

1. A method for finely powdering tungsten powder, comprising:
a classification process for classifying a material tungsten powder into a fine powder having a relatively small average particle diameter and a coarse powder having a relatively large average particle diameter;
an oxidation process for forming an oxide film on the particle surface of the coarse powder having a relatively large average particle diameter; and
an alkali treatment process for removing the oxide film formed in the oxidation process and a natural oxide film formed on the fine powder with an alkali aqueous solution.

2. A method for finely powdering tungsten powder, comprising:
a classification process, repeating once or more of a step of classifying a material tungsten powder into a fine powder having a relatively small average particle diameter and a coarse powder having a relatively large average particle diameter;
an oxidation process for forming an oxide film on the particle surface of the coarse powder obtained by the classification; and
an alkali treatment process for removing the oxide film formed in the oxidation process and a natural oxide film formed on the fine powder, which is obtained in the above multiple steps of classification, with an alkali aqueous solution.

3. A method for finely powdering tungsten powder, wherein a process of finely powdering an ultrafine tungsten powder obtained by the method of finely powdering tungsten powder claimed in claim 1 is conducted once or more according to the method for finely powdering tungsten powder claimed in claim 1 .

4. The method for finely powdering tungsten powder as claimed in claim 1 , wherein the classification process is performed by elutriation.

5. The method for finely powdering tungsten powder as claimed in claim 1 , wherein the oxidation is a treatment of conducting electrolytic oxidation of a tungsten powder in an electrolyte solution while stirring.

6. The method for finely powdering tungsten powder as claimed in claim 5 , wherein the electrolytic solution is an aqueous solution of persulfuric acid or mineral acid.

7. The method for finely powdering tungsten powder as claimed in claim 6 , wherein the mineral acid is selected from phosphoric acid, nitric acid, hydrochloric acid, boric acid and sulfuric acid.

8. The method for finely powdering tungsten powder as claimed in claim 6 , wherein the mineral acid is phosphoric acid or boric acid.

9. The method for finely powdering tungsten powder as claimed in claim 1 , wherein the oxidation process is a process of oxidizing a tungsten powder by dispersing the tungsten powder in an aqueous solution containing an oxidizing agent.

10. The method for finely powdering tungsten powder as claimed in claim 9 , wherein the oxidizing agent is selected from manganese(VII) compounds, chrome(VI) compounds, halogen acid compounds, peroxoacid compounds and salts thereof, peroxides, and persulfuric acid compounds.

11. The method for finely powdering tungsten powder as claimed in claim 10 , wherein the oxidizing agent is selected from hydrogen peroxide, potassium persulfate and ammonium persulfate.

12. The method for finely powdering tungsten powder as claimed in claim 1 , wherein the alkaline aqueous solution is an aqueous solution of sodium hydroxide or an aqueous solution of potassium hydroxide.

13. A method for producing ultrafine tungsten powder, comprising obtaining tungsten powder having an average particle diameter of 0.04 to 0.5 μm by a process including the method claimed in claim 1 .

14. A method for producing ultrafine tungsten powder, comprising obtaining tungsten powder having a BET specific surface area of 3 to 15 m 2 /g by a process including the method claimed in claim 1 .

15. A method for producing ultrafine tungsten powder, comprising obtaining tungsten powder having an average particle diameter of 0.04 to 0.4 μm and a BET specific surface area of 5 to 15 m 2 /g by a process including the method claimed in claim 1 .

Assignees

• Showa Denko Kk
• Show A Denko K K

Inventors

• Naito Kazumi
• Yabe Shoji

Classifications

• B22F1/16

  Metallic particles coated with a non-metal (coated with lubricating or binding agents or with organic material B22F1/10) · CPC title

• C23C8/02

  Pretreatment of the material to be coated (C23C8/04 takes precedence) · CPC title

• H01G9/0525

  Powder therefor · CPC title

• H01G9/052

  Sintered electrodes · CPC title

• B22F1/02 Primary

  Operations & Transport · mapped topic