Use of catalyst prepared with a subgroup VI element for the production of organic chemicals and fuels from lignin

Patent metadata

Field	Value
Publication number	US-9789473-B2
Application number	US-201514791999-A
Country	US
Kind code	B2
Filing date	Jul 6, 2015
Priority date	Jan 8, 2013
Publication date	Oct 17, 2017
Grant date	Oct 17, 2017

Abstract

A process for the production of organic chemicals and fuels from lignin in the presence of a molybdenum or tungsten based catalyst, comprising mixing the lignin with the catalyst and a solvent in a sealed reactor, introducing an inert gas or hydrogen to the reactor to replace oxygen therein, and heating the sealed reactor to perform a depolymerization reaction at a reaction temperature of above 200° C. to obtain liquid products, which include aromatic compounds, esters, alcohols, monophenols and benzyl alcohols.

First claim

The invention claimed is:

1. A process for the production of organic chemicals and fuels from lignin, comprising
mixing the lignin with a molybdenum based catalyst and a solvent in a sealed reactor,
introducing an inert gas to the reactor to replace oxygen therein, and
heating the sealed reactor to perform a depolymerization reaction at a reaction temperature of 230-350° C. for 0.5-12 h to obtain liquid products comprising alcohols, esters, monophenols, benzyl alcohols and arenes;
wherein the solvent is selected from the group consisting of deionized water, ethanol and a mixture of deionized water and ethanol;
wherein the molybdenum based catalyst is a supported or an unsupported catalyst comprising molybdenum as an active metal;
wherein the supported catalyst is expressed as A x B y /C, wherein A represents molybdenum which has a loading amount of 1-80 wt. % of the supported catalyst, B represents carbon, phosphorus or nitrogen, and C represents the support of the catalyst selected from the group consisting of aluminum oxide (Al 2 O 3 ), activated carbon (AC), silicon dioxide (SiO 2 ), silicon carbide (SiC), zeolites and nano-carbon fiber, 0<x≦2 and 0<y≦3;
wherein the unsupported catalyst is expressed as A x B y , wherein A represents molybdenum, B represents carbon, phosphorus or nitrogen, 0<x≦2, and 0<y≦3;
wherein the lignin includes alkali lignin, Klason lignin, milled wood lignin and organosolv lignin;
wherein the inert gas is nitrogen, argon or helium; and
wherein the mixture of deionized water and ethanol comprises 10-50% of ethanol by volume.

2. The process of claim 1 , wherein the sealed reactor is adapted to receive both liquid and solid or slurry feeds, and continuous distillation is used to maintain continuous reaction.

3. The process of claim 1 , wherein,
a mass ratio of the lignin and solvent is 1:200-1:10;
a mass ratio of the lignin and catalyst is between 1:1 and 200:1;
the sealed reactor has an initial reaction pressure of 0-6 MPa at room temperature of 20-25° C., and
the reaction proceeds at 260-300° C. for 2-6 h under a stirring rate of 100-1500 r/min.

4. The process of claim 3 , wherein the mass ratio of the lignin and solvent is 1:100-1:80.

5. The process of claim 3 , wherein the mass ratio of the lignin and catalyst is between 10:1 and 100:1.

6. The process of claim 1 , wherein the catalyst further comprises a promoter Z which has a loading amount of 0.1-15 wt. % of the catalyst and is selected from the group consisting of Fe, Ni, Co, Ru, W, Cu, Cr and Pt.

Assignees

• Univ Tianjin

Inventors

• Li Yongdan
• Ma Rui
• Ma Xiaolei
• Hao Wenyue

Classifications

• B01J23/28

  Molybdenum · CPC title

• C07C67/00

  Preparation of carboxylic acid esters · CPC title

• B01J23/8993

  with chromium, molybdenum or tungsten · CPC title

• C07C29/00

  Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring · CPC title

• B01J27/22

  Carbides · CPC title