Transparent conductive film, heater, touch panel, solar battery, organic EL device, liquid crystal device, and electronic paper

Patent metadata

Field	Value
Publication number	US-9786410-B2
Application number	US-201214005976-A
Country	US
Kind code	B2
Filing date	Mar 21, 2012
Priority date	Mar 28, 2011
Publication date	Oct 10, 2017
Grant date	Oct 10, 2017

Abstract

There are provided a transparent conductive film, as well as a heater, a touch panel, a solar battery, an organic EL device, a liquid crystal device, and an electronic paper that are provided with the transparent conductive film, the transparent conductive film being capable of easing a decline in optical transmittance when graphene is laminated, and of achieving optical transmittance higher than an upper limit of optical transmittance of a single layer of graphene. The transparent conductive film includes a single-layered conductive graphene sheet. The single-layered conductive graphene sheet includes a first region and a second region, the first region being configured of graphene, and the second region being surrounded by the first region and having optical transmittance that is higher than optical transmittance of the first region.

First claim

The invention claimed is:

1. A transparent conductive film, comprising:
a single-layered first conductive graphene sheet including a first region and a second region,
wherein the first region is configured of graphene, and the second region is surrounded by the first region,
wherein the second region is configured of a light transmissive material, and
wherein a first optical transmittance of the second region is higher than a second optical transmittance of the first region.

2. The transparent conductive film according to claim 1 , wherein the light transmissive material comprises at least one of graphene oxide, transparent polymer material, or inorganic material.

3. The transparent conductive film according to claim 1 , wherein the first region includes a region modified based on doping.

4. The transparent conductive film according to claim 1 , wherein a width of a narrowest part of the first region is larger than 10 nanometers.

5. The transparent conductive film according to claim 1 , wherein a width of a narrowest part of the first region is 15 nanometers or larger.

6. The transparent conductive film according to claim 1 , wherein a width of a narrowest part of the first region is 30 nanometers or larger.

7. The transparent conductive film according to claim 1 , wherein a layout of the second region has regularity in a region expressed by a unit in square micrometer order.

8. The transparent conductive film according to claim 1 , wherein a third optical transmittance of the single-layered first conductive graphene sheet is 97.7 percent or higher.

9. The transparent conductive film according to claim 1 , further comprising a plurality of the single-layered first conductive graphene sheets.

10. The transparent conductive film according to claim 9 , wherein the second regions in the respective plurality of the single-layered first conductive graphene sheets are laid out not to face one another.

11. The transparent conductive film according to claim 9 , wherein the second regions in the respective plurality of the first conductive graphene sheets face one another.

12. The transparent conductive film according to claim 1 , further comprising a single-layered second conductive graphene sheet, wherein the single-layered second conductive graphene sheet is configured of graphene and have no opening.

13. A heater, comprising:
a transparent conductive film configured to serve as an electrode provided for heat generation, the transparent conductive film comprising:
a single-layered first conductive graphene sheet including a first region and a second region,
wherein the first region is configured of graphene, and the second region is surrounded by the first region,
wherein the second region is configured of a light transmissive material, and
wherein a first optical transmittance of the second region is higher than a second optical transmittance of the first region.

14. A touch panel, comprising:
a transparent conductive film configured to serve as an electrode, the transparent conductive film comprising:
a single-layered first conductive graphene sheet including a first region and a second region,
wherein the first region is configured of graphene, and the second region is surrounded by the first region,
wherein the second region is configured of a light transmissive material, and
wherein a first optical transmittance of the second region is higher than a second optical transmittance of the first region.

15. A solar battery comprising:
a transparent conductive film configured to serve as an electrode, the transparent conductive film comprising:
a single-layered first conductive graphene sheet including a first region and a second region,
wherein the first region is configured of graphene, and the second region is surrounded by the first region,
wherein the second region is configured of a light transmissive material, and
wherein a first optical transmittance of the second region is higher than a second optical transmittance of the first region.

16. An organic electroluminescence device comprising:
a transparent conductive film configured to serve as an electrode, the transparent conductive film comprising:
a single-layered first conductive graphene sheet including a first region and a second region,
wherein the first region is configured of graphene, and the second region is surrounded by the first region,
wherein the second region is configured of a light transmissive material, and
wherein a first optical transmittance of the second region is higher than a second optical transmittance of the first region.

17. A liquid crystal device comprising:
a transparent conductive film configured to serve as an electrode, the transparent conductive film comprising:
a single-layered first conductive graphene sheet including a first region and a second region,
wherein the first region is configured of graphene, and the second region is surrounded by the first region,
wherein the second region is configured of a light transmissive material, and
wherein a first optical transmittance of the second region is higher than a second optical transmittance of the first region.

18. An electronic paper comprising:
a transparent conductive film configured to serve as an electrode, the transparent conductive film comprising:
a single-layered first conductive graphene sheet including a first region and a second region,
wherein the first region is configured of graphene, and the second region is surrounded by the first region,
wherein the second region is configured of a light transmissive material, and
wherein a first optical transmittance of the second region is higher than a second optical transmittance of the first region.

Assignees

• Shimizu Keisuke
• Kobayashi Toshiyuki
• Kimura Nozomi
• Izuha Kyoko
• Sony Corp

Inventors

• Shimizu Keisuke
• Kobayashi Toshiyuki
• Kimura Nozomi
• Izuha Kyoko

Classifications

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• G02F2201/121

  common or background · CPC title

• G02F1/13439

  characterised by their electrical, optical, physical properties; materials therefor; method of making · CPC title

• Y10T428/24802

  Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] · CPC title