Colored low-polarizing films, colored low-polarizing sheets, and colored low-polarizing lenses, and methods thereof

Patent metadata

Field	Value
Publication number	US-9784895-B2
Application number	US-201414762291-A
Country	US
Kind code	B2
Filing date	Jan 21, 2014
Priority date	Jan 25, 2013
Publication date	Oct 10, 2017
Grant date	Oct 10, 2017

Abstract

A colored low-polarizing film of a desired color is produced by causing a polyvinyl alcohol film to swell with water, stretching, dyeing with an organic dichroic dye, and drying it; a polarizing sheet including the film and transparent sheets attached to both sides of the film by an adhesive; and an injection-molded polarizing lens obtained by causing the sheet to curve to impart spherical or aspherical surfaces to obtain a curved polarizing lens and injecting a transparent resin onto the concave surface of the lens. The dye includes a dichroic organic dye and a coloration organic dye, wherein the dichroic composition includes a combination of dichroic dyes having a dichroic ratio of 13 or higher, wherein the coloration dye composition includes a combination of dyes having an extremely low dichroic ratio, of 4 or less, or substantially having no dichroic ratio.

First claim

The invention claimed is:

1. A colored low-polarizing film produced by causing, a polyvinyl alcohol film to swell with water, uniaxially stretching it, dyeing it with a dichroic organic dye composition and a coloration organic dye composition, and drying it,
wherein the dichroic organic dye composition comprises a combination of dichroic organic dyes having a dichroic ratio of 13 or higher, wherein the coloration organic dye composition comprises a combination of dyes having an extremely low dichroic ratio, of 4 or less, or substantially having no dichroic ratio, wherein the dichroic organic dyes of the dichroic organic dye composition are selected so as to be colorless and contribute to obtain the polarizing degree of interest, wherein the dyes of the coloration organic dye composition are selected so as to have color of interest, wherein because of a low or no dichroic ratio of the coloration organic dye composition, the film shows a small change in color tone during a heating process, and wherein the polarizing degree of the film is 45% to less than 90%.

2. The colored low-polarizing film of claim 1 , wherein the dichroic organic dye composition is used in an amount necessary to obtain the lower limit of the required dichroic ratio.

3. The colored low-polarizing film of claim 1 , wherein the coloration organic dye composition is used in an amount such that the transmittance of the film is 8% to 50% and is at least 5% less than the transmittance of a polarizing film obtained by using the dichroic organic dye composition only.

4. A method for producing a colored low-polarizing film by causing a polyvinyl alcohol film to swell with water, uniaxially stretching it, dyeing it with a a dichroic organic dye composition and a coloration organic dye composition, and drying it,
wherein the dichroic organic dye composition comprises a combination of dichroic organic dyes having a dichroic ratio of 13 or higher, wherein the coloration organic dye composition comprises a combination of dyes having an extremely low dichroic ratio of 4 or less or substantially having no dichroic ratio, wherein the dichroic organic dyes of the dichroic organic dye composition are selected so as to be colorless and contribute to obtain the polarizing degree of interest, wherein the dyes of the coloration organic dye composition are selected so as to have color of interest, wherein because of the low or no dichroic ratio of the coloration organic dye composition, the film shows the small change in color tone during a heating process, and
wherein the polarization degree of the film is 45% to less than 90%.

5. The method for producing the colored low-polarizing film of claim 4 , wherein the dichroic organic dye composition and the coloration organic dye composition are used in a separated aqueous solution.

6. The method for producing the colored low-polarizing film of claim 4 , wherein the dichroic organic dye composition is used in an amount necessary to obtain the lower limit of the required dichroic ratio.

7. The method for producing the colored low-polarizing film of claim 4 , wherein the coloration organic dye composition is used in an amount such that the transmittance of the film is 8% to 50% and is at least 5% less than the transmittance of a polarizing film obtained by using the dichroic organic dye composition only.

8. A colored low-polarizing sheet that comprises a polarizing film produced by causing a polyvinyl alcohol film to swell with water, uniaxially stretching it, dyeing it with a dichroic organic dye composition and a coloration organic dye composition, and drying it, and transparent sheets being attached on both sides of the polarizing film by an adhesive,
wherein the dichroic organic dye composition comprises a combination of dichroic organic dyes having a dichroic ratio of 13 or higher, wherein the coloration organic dye composition comprises a combination of dyes having an extremely low dichroic ratio, of 4 or less, or substantially having no dichroic ratio, wherein the dichroic organic dyes of the dichroic organic dye composition are selected so as to be colorless and contribute to obtain the polarizing degree of interest, wherein the dyes of the coloration organic dye composition are selected so as to have color of interest, wherein because of the low or no dichroic ratio of the coloration organic dye composition, the film shows the small change in color tone during a heating process, and wherein the polarizing film is a colored low-polarizing film of a desired color that has a polarizing degree of 45% to less than 90%.

9. The colored low-polarizing sheet of claim 8 ,
wherein the dichroic organic dye composition and the coloration organic dye composition are used in a separated aqueous solution.

10. The colored low-polarizing sheet of claim 8 ,
wherein the dichroic organic dye composition is used in an amount necessary to obtain the lower limit of the required dichroic ratio.

11. The colored low-polarizing sheet of claim 8 ,
wherein the coloration organic dye composition is used in an amount such that the transmittance of the film is 8% to 50% and is at least 5% less than the transmittance of a polarizing film obtained by using the dichroic organic dye composition only.

12. The colored low-polarizing sheet of claim 8 ,
wherein the transparent sheets are one or more resins selected from the group consisting of: aromatic polycarbonates, polyacrylates, acetylcelluloses, and a composition of an aromatic polycarbonate and an alicyclic polyester.

13. The colored low-polarizing sheet of claim 8 ,
wherein the transparent plastic sheets are an aromatic polycarbonate sheet and the polarizing sheet is from 0.1 mm to 1 mm thick at 3000 nm or higher retardation.

14. The colored low-polarizing sheet of claim 8 ,
wherein the adhesive is a two-liquid-type thermosetting polyurethane resin that consists of a curative agent that comprises a polyurethane prepolymer and a hydroxyl (poly) acrylate.

15. A colored low-polarizing lens obtained by:
(1) laminating a transparent plastic sheet via an adhesive layer to each surface of the colored low-polarizing film of claim 1 to obtain a polarizing sheet,
(2-1) causing the polarizing sheet to curve so as to impart spherical or aspherical surfaces thereto to obtain a curved polarizing lens, or
(2-2) causing the polarizing sheet to curve so as to impart spherical or aspherical surfaces thereto and injecting a transparent resin onto the a concave surface to obtain an injection-molded lens,
wherein the surface of one side of the polarizing sheet is a colored low-polarizing sheet that has 45% to less than 90% of a polarizing degree and that side is curved to make a concave surface.

16. The colored low-polarizing lens of claim 15 ,
wherein the dichroic organic dye composition and the coloration organic dye composition are used in a separated aqueous solution.

17. The colored low-polarizing lens of claim 15 ,
wherein the dichroic organic dye composition is used in an amount necessary to obtain the lower limit of a required dichroic ratio.

18. The colored low-polarizing lens of claim 15 ,
wherein the coloration organic dye composition is used in an amount such that a transmittance of the film is 8% to 50% and is at least 5% less than the transmittance of a polarizing film obtained by using the dichroic organic dye composition only.

19. The colored low-polarizing lens of claim 15 ,
wherein the transparent plastic sheet is one or more selected from the group consisting of: aromatic polycarbonates, polyacrylates, ac

Assignees

• Mitsubishi Gas Chemical Co
• Mgc Filsheet Co Ltd

Inventors

• Kimura Hideaki
• Sasagawa Taisuke
• Akaki Masayuki
• Takano Toshihiko

Classifications

• G02B5/305 Primary

  including organic materials, e.g. polymeric layers · CPC title

• B29D11/00644

  polarizing · CPC title

• G02B5/3033

  in the form of a thin sheet or foil, e.g. Polaroid · CPC title

• B29K2029/04

  PVOH, i.e. polyvinyl alcohol (B29K2031/04 takes precedence) · CPC title

• G02B5/223 Primary

  containing organic substances, e.g. dyes, inks or pigments · CPC title