Process for the coating of textiles

Patent metadata

Field	Value
Publication number	US-9783926-B2
Application number	US-201214355087-A
Country	US
Kind code	B2
Filing date	Oct 16, 2012
Priority date	Oct 18, 2011
Publication date	Oct 10, 2017
Grant date	Oct 10, 2017

Abstract

A process for the production of coated textiles comprises at least the steps of a) bringing a textile substrate into contact with an aqueous dispersion A comprising at least one salt and at least one modified cellulose, b) bringing a textile substrate into contact with an aqueous dispersion B comprising at least one polymer selected from the group consisting of polyurethane, polyacrylate and polybutadiene and c) precipitation of the polyurethane in or on the textile substrate. The salt of dispersion A is an organic onium salt of one or more elements of the fifth main group of the periodic table of the elements. The invention further relates to a coated textile obtainable by a process according to the invention and to the use of organic onium salts of one or more elements of the fifth main group of the periodic table of the elements for the production of coated textiles.

First claim

The invention claimed is:

1. A process for the production of a coated textile, comprising at least the steps of
a) first, bringing a textile substrate into contact with an aqueous dispersion A consisting essentially of at least one salt and at least one modified cellulose,
b) subsequently, bringing a textile substrate into contact with an aqueous dispersion B comprising at least one polymer selected from the group consisting of polyurethane, polyacrylate and polybutadiene, and
c) precipitating the polyurethane in or on the textile substrate,
wherein the salt of dispersion A is an organic onium salt of one or more elements of the fifth main group of the periodic table of the elements.

2. The process according to claim 1 , wherein the salt of dispersion A is selected from the group consisting of tertiary ammonium salts, quaternary ammonium salts, tertiary phosphonium salts and quaternary phosphonium salts.

3. The process according to claim 1 , wherein the salt of dispersion A is selected from the group consisting of (chloro-hydroxyalkyl)trialkylammonium salts, trialkyl[(trialkoxysilyl)alkyl]ammonium salts, trialkylalkoxyl ammonium salts, trialkylammonium epihydrinamine salts, monoammonium salts of N,N,N′,N′-tetrakis(2-hydroxyalkyl)alkylenediamine and diammonium salts of N,N,N′,N′-tetrakis(2-hydroxyalkyl)alkylenediamine.

4. The process according to claim 1 , wherein the organic onium salt is present in dispersion A in an amount of ≧0.01% by weight to ≦15% by weight, based on the total amount of dispersion A.

5. The process according to claim 1 , wherein the modified cellulose is a compound selected from the group consisting of methylcellulose, ethylcellulose, propylcellulose, hydroxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, carboxymethylcellulose, carboxyethylcellulose and carboxypropylcellulose.

6. The process according to claim 1 , wherein the modified cellulose is present in dispersion A in an amount of ≧10 ppm by weight to ≦25% by weight, based on the total amount of dispersion A.

7. The process according to claim 1 , wherein the textile substrate is a woven fabric, knitted fabric or nonwoven based on natural and/or synthetic fibers.

8. The process according to claim 1 , wherein the polyurethane is precipitated in step c) in a bath containing water and/or by heating to a temperature in the range from ≧80° C. to ≦180° C.

9. The process according to claim 1 , further comprising the step of at least partially removing excess liquids after step a) and/or after step b).

10. A process for the production of a coated textile, consisting of the steps of
a) first, bringing a textile substrate into contact with an aqueous dispersion A essentially consisting of at least one salt and at least one modified cellulose, wherein the salt is selected from the group consisting of (chloro-hydroxyalkyl)trialkylammonium salts, trialkyl[(trialkoxysilyl)alkyl]ammonium salts, trialkylalkoxyl ammonium salts, trialkylammonium epihydrinamine salts, monoammonium salts of N,N,N′,N′-tetrakis(2-hydroxyalkyl)alkylenediamine and diammonium salts of N,N,N′,N-tetrakis(2-hydroxyalkyl)alkylenediamine,
a1) partially removing excess liquids,
b) subsequently, bringing a textile substrate into contact with an aqueous dispersion B comprising at least one polymer selected from the group consisting of polyurethane, polyacrylate and polybutadiene,
b1) partially removing excess liquids,
and
c) precipitating the polyurethane in or on the textile substrate.

Assignees

• Bayer Ip Gmbh
• Covestro Deutschland Ag

Inventors

• Irnich Rolf
• Xuehui Zhao

Classifications

• D06N3/10

  with styrene-butadiene copolymerisation products {or other synthetic rubbers or elastomers except polyurethanes} · CPC title

• D06N2211/28

  Artificial leather · CPC title

• D06M15/05 Primary

  Cellulose or derivatives thereof · CPC title

• D06M15/227

  of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated · CPC title

• D06N3/183

  the layers are one next to the other · CPC title