Use of refrigerants comprising E-1,3,3,3-tetrafluoropropene and at least one tetrafluoroethane for cooling

Patent metadata

Field	Value
Publication number	US-9783720-B2
Application number	US-201113884293-A
Country	US
Kind code	B2
Filing date	Dec 14, 2011
Priority date	Dec 14, 2010
Publication date	Oct 10, 2017
Grant date	Oct 10, 2017

Abstract

Disclosed herein is a method for producing cooling comprising evaporating a liquid refrigerant comprising (a) E-CF 3 CH═CHF and (b) at least one tetrafluoroethane of the formula C 2 H 2 F 4 ; provided that the weight ratio of E-CF 3 CH═CHF to the total amount of E-CF 3 CH═CHF and C 2 H 2 F 4 is from about 0.05 to 0.99, in an evaporator, thereby producing a refrigerant vapor. Also disclosed herein is a method for replacing HCFC-124 or HFC-134a refrigerant in a chiller designed for said refrigerant comprising providing a replacement refrigerant composition comprising (a) E-CF 3 CH═CHF and (b) at least one tetrafluoroethane of the formula C 2 H 2 F 4 ; provided that the weight ratio of E-CF 3 CH═CHF to the total amount of E-CF 3 CH═CHF and C 2 H 2 F 4 is from about 0.05 to 0.99. Also disclosed herein is a chiller apparatus for cooling, said apparatus containing a working fluid comprising a refrigerant comprising (a) E-CF 3 CH═CHF and (b) at least one tetrafluoroethane of the formula C 2 H 2 F 4 ; provided that the weight ratio of E-CF 3 CH═CHF to the total amount of E-CF 3 CH═CHF and C 2 H 2 F 4 is from about 0.05 to 0.99.

First claim

What is claimed is:

1. A method for producing cooling comprising evaporating a liquid refrigerant consisting of (a) E-CF3CH═CHF and (b) CHF2CHF2; provided that the weight ratio of E-CF3CH═CHF to the total amount of E-CF3CH═CHF and CHF2CHF2 is from about 0.05 to 0.68, in an evaporator, thereby producing a refrigerant vapor; wherein the cooling is produced in a chiller comprising said evaporator; and wherein said chiller further comprises a centrifugal compressor.

2. The method of claim 1 further comprising passing a cooling medium through the evaporator, whereby said evaporation of refrigerant cools the cooling medium, and passing the cooled cooling medium from the evaporator to a body to be cooled.

3. The method of claim 2 , wherein the cooling medium is water and the body to be cooled is air for space cooling or the cooling medium is an industrial heat transfer liquid and the body to be cooled is a chemical process stream.

4. The method of claim 2 , further comprising compressing the refrigerant vapor in the centrifugal compressor.

5. The method of claim 1 , wherein the weight ratio of E-CF3CH═CHF to the total amount of E-CF3CH═CHF and CHF2CHF2 is from about 0.6 to less than 0.68.

6. A method for replacing HCFC-124 or HFC-134a refrigerant in a chiller designed for said HCFC-124 or HFC-134a refrigerant comprising providing a replacement refrigerant composition consisting of (a) E-CF3CH═CHF and (b) CHF2CHF2;
provided that the weight ratio of E-CF3CH═CHF to the total amount of E-CF3CH═CHF and CHF2CHF2 is from about 0.05 to 0.68; wherein said chiller comprises a centrifugal compressor.

7. The method of claim 6 , wherein the centrifugal compressor, has an impeller, further comprising adjusting the rotational speed of the impeller.

8. The method of claim 6 , wherein the centrifugal compressor, has an impeller, further comprising replacing the compressor impeller with a different diameter impeller.

9. The method of claim 6 , wherein the weight ratio of E-CF3CH═CHF to the total amount of E-CF3CH═CHF and CHF2CHF2 is from about 0.6 to less than 0.68.

10. A chiller apparatus for cooling, said apparatus containing a working fluid comprising a refrigerant consisting of (a) E-CF3CH═CHF and (b) CHF2CHF2; provided that the weight ratio of E-CF3CH═CHF to the total amount of E-CF3CH═CHF and CHF2CHF2 is from about 0.05 to 0.68; wherein said chiller comprises a centrifugal compressor.

11. The chiller apparatus of claim 10 , wherein the weight ratio of E-CF3CH═CHF to the total amount of E-CF3CH═CHF and CHF2CHF2 is from about 0.6 to less than 0.68.

Assignees

• Kontomaris Konstantinos
• Chemours Co Fc Llc

Inventors

• Kontomaris Konstantinos

Classifications

• C09K2205/126

  Unsaturated fluorinated hydrocarbons · CPC title

• C09K5/045

  containing only fluorine as halogen · CPC title

• C09K2205/22

  All components of a mixture being fluoro compounds · CPC title

• C09K5/00 Primary

  Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion · CPC title

• C09K5/04 Primary

  the change of state being from liquid to vapour or vice versa · CPC title