Sacrificial coating for intermediate transfer member of an indirect printing apparatus

Patent metadata

Field	Value
Publication number	US-9783697-B2
Application number	US-201615369962-A
Country	US
Kind code	B2
Filing date	Dec 6, 2016
Priority date	Sep 23, 2014
Publication date	Oct 10, 2017
Grant date	Oct 10, 2017

Abstract

A coating composition for an image transfer member in an aqueous ink imaging system. The coating composition includes at least one hydrophilic polymer, at least one hygroscopic material, at least one oil-in-water emulsion and at least one surfactant.

First claim

What is claimed is:

1. A coating composition for an image transfer member in an aqueous ink imaging system, the composition made by mixing ingredients comprising:
at least one hydrophilic polymer;
at least one hygroscopic material;
at least one oil-in-water emulsion comprising an emulsified oil selected from the group consisting of a silicone oil, a perfluoroether oil and mixtures thereof; and
at least one surfactant.

2. The coating composition of claim 1 , wherein the at least one hydrophilic polymer is selected from the group consisting of polyvinyl alcohol, a copolymer of vinyl alcohol and alkene monomers, poly(vinylpyrrolidinone) (“PVP”), poly(ethylene oxide), hydroxyethyl cellulose, cellulose acetate, poly(ethylene glycol), copolymers of poly(ethylene glycol), polyacrylamide (PAM), poly(N-isopropylacrylamide) (“PNIPAM”), poly(acrylic acid), polymethacrylate, acrylic polymers, maleic anhydride copolymers, sulfonated polyesters, polysaccharides, waxy maize starches and the mixtures thereof.

3. The coating composition of claim 1 , wherein the at least one hydrophilic polymer is polyvinyl alcohol having a hydrolysis degree ranging from about 75% to about 99.5% and weight average molecular weight ranging from about 8000 to about 30,000 g-mole −1 .

4. The coating composition of claim 1 , wherein the at least one hydrophilic polymer is selected from waxy maize starches comprising more than 90 weight percent amylopectin.

5. The coating composition of claim 1 , wherein the at least one oil-in-water emulsion is present in an amount ranging from about 0.05% to about 8% by weight relative to the total composition weight.

6. The coating composition of claim 1 , wherein the at least one hygroscopic material is selected from the group consisting of glycerol, sorbitol, glycols, vinyl alcohols, xylitol, maltitol, polymeric polyols, glyceryl triacetate, glycouril, ionic liquids and mixtures thereof.

7. The coating composition of claim 1 , wherein the oil-in-water emulsion comprises the silicone oil, the silicone oil having a viscosity of less than 1000 centipoises.

8. The coating composition of claim 1 , wherein the surfactant comprises at least one nonionic surfactant with hydrophile lipophile balance (HLB) value from 4 to 15.

9. The coating composition of claim 1 , wherein the surfactant comprises a mixture of a first surfactant and a second surfactant, the first surfactant having a hydrophile lipophile balance (“HLB”) value ranging from about 8 to about 15 and the second surfactant having an HLB value ranging from about 4 to about 10, the HLB value for the first surfactant being higher that the HLB value for the second surfactant.

10. The coating composition of claim 1 , wherein the surfactant is a secondary alcohol ethoxylate.

11. The coating composition of claim 1 , wherein the surfactant is a branched secondary alcohol ethoxylate with 6 to 12 moles of ethylene oxide (EO).

12. A coating composition for an image transfer member in an aqueous ink imaging system, the composition made by mixing ingredients comprising:
at least one hydrophilic polymer selected from the group consisting of polyvinyl alcohol, a copolymer of vinyl alcohol and alkene monomers, waxy maize starches and the mixtures thereof;
at least one hygroscopic material selected from the group consisting of glycerol, sorbitol, ethylene glycol and mixtures thereof;
at least one oil-in-water emulsion comprising an emulsified oil selected from the group consisting of a silicone oil, a perfluoroether oil, a hydrocarbon oil and mixtures thereof; and
at least one surfactant, the at least one surfactant comprising a secondary alcohol ethoxylate.

13. The coating composition of claim 12 , wherein the at least one hydrophilic polymer is polyvinyl alcohol having a hydrolysis degree ranging from about 75% to about 99.5% and weight average molecular weight ranging from about 8000 to about 30,000 g-mole −1 .

14. The coating composition of claim 13 , wherein the oil-in-water emulsion comprises the silicone oil, the silicone oil having a viscosity of less than 1000 centipoises.

15. The coating composition of claim 12 , wherein the at least one hydrophilic polymer is selected from waxy maize starches comprising more than 90 weight percent amylopectin.

16. The coating composition of claim 12 , wherein the oil-in-water emulsion comprises the hydrocarbon oil, the hydrocarbon oil being a mineral oil selected from the group consisting of paraffinic oils, naphthenic oils, aromatic oils and mixtures thereof.

17. The coating composition of claim 12 , wherein the at least one surfactant has a hydrophile lipophile balance (HLB) value of from 4 to 15.

18. The coating composition of claim 12 , wherein the at least one surfactant comprises a mixture of a first surfactant and a second surfactant, the first surfactant having a hydrophile lipophile balance (“HLB”) value ranging from about 8 to about 15 and the second surfactant having an HLB value ranging from about 4 to about 10, the HLB value for the first surfactant being higher that the HLB value for the second surfactant.

19. The coating composition of claim 12 , wherein the secondary alcohol ethoxylate is a branched secondary alcohol ethoxylate with 6 to 12 moles of ethylene oxide (EO).

Assignees

• Xerox Corp

Inventors

• Sisler Gordon
• Song Guiqin
• Breton Marcel P
• Yang Suxia

Classifications

• C09D139/06

  Homopolymers or copolymers of N-vinyl-pyrrolidones · CPC title

• C09D133/10

  Homopolymers or copolymers of methacrylic acid esters · CPC title

• C09D103/02

  Starch; Degradation products thereof, e.g. dextrin · CPC title

• C08K5/5419

  containing at least one Si—C bond · CPC title

• C08K5/06

  Ethers; Acetals; Ketals; Ortho-esters · CPC title