3-acyloxymethyl-3-butenyl carboxylate compound and method for producing 4-alkyl-3-methylenebutyl carboxylate
US-9499468-B2 · Nov 22, 2016 · US
US9783480B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9783480-B2 |
| Application number | US-201615284750-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 4, 2016 |
| Priority date | Oct 30, 2013 |
| Publication date | Oct 10, 2017 |
| Grant date | Oct 10, 2017 |
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Provided is a method that can produce phenyl(meth)acrylate inexpensively and at high yields. The phenyl(meth)acrylate production method of the present invention reacts (meth)acrylic acid with carbonic acid diphenyl. Further, the phenyl(meth)acrylate composition of the present invention contains 90-99.999 wt % phenyl(meth)acrylate and 0.001-10% carbonic acid diphenyl. Or, the phenyl(meth)acrylate composition of the present invention contains 90-99.999 wt % phenyl(meth)acrylate and 0.001-10 wt % of a specified compound.
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What is claimed is: 1. A phenyl (meth)acrylate composition, comprising: phenyl (meth)acrylate in a range of 90 mass % to 99.999 mass %; and diphenyl carbonate in a range of 0.001 mass % to 10 mass %. 2. The phenyl (meth)acrylate composition according to claim 1 , comprising: phenyl (meth)acrylate in a range of 95 mass % to 99.999 mass %; and diphenyl carbonate in a range of 0.001 mass % to 5 mass %. 3. The phenyl (meth)acrylate composition according to claim 1 , comprising: phenyl (meth)acrylate in a range of 98 mass % to 99.999 mass %; and diphenyl carbonate in a range of 0.001 mass % to 2 mass %. 4. The phenyl (meth)acrylate composition according to claim 1 , comprising: phenyl (meth)acrylate in a range of 99 mass % to 99.999 mass %; and diphenyl carbonate in a range of 0.001 mass % to 1 mass %. 5. The phenyl (meth)acrylate composition according to claim 1 , comprising: phenyl (meth)acrylate in a range of 99.5 mass % to 99.999 mass %; and diphenyl carbonate in a range of 0.001 mass % to 0.5 mass %. 6. The phenyl (meth)acrylate composition according to claim 1 , wherein the total mass of phenyl (meth)acrylate and diphenyl carbonate is 100 mass % of the phenyl (meth)acrylate composition. 7. The phenyl (meth)acrylate composition according to claim 2 , wherein the total mass of phenyl (meth)acrylate and diphenyl carbonate is 100 mass % of the phenyl (meth)acrylate composition. 8. The phenyl (meth)acrylate composition according to claim 3 , wherein the total mass of phenyl (meth)acrylate and diphenyl carbonate is 100 mass % of the phenyl (meth)acrylate composition. 9. The phenyl (meth)acrylate composition according to claim 4 , wherein the total mass of phenyl (meth)acrylate and diphenyl carbonate is 100 mass % of the phenyl (meth)acrylate composition. 10. The phenyl (meth)acrylate composition according to claim 5 , wherein the total mass of phenyl (meth)acrylate and diphenyl carbonate is 100 mass % of the phenyl (meth)acrylate composition.
Use of additives, e.g. for stabilisation · CPC title
Acrylic acid esters; Methacrylic acid esters · CPC title
being mineral ester groups · CPC title
having unsaturation outside the rings · CPC title
by reacting carboxylic acids or symmetrical anhydrides with ester groups or with a carbon-halogen bond (preparation from carboxylic acid halides C07C67/14) · CPC title
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