Alkylation reaction using delaminated zeolite supports as catalysts
US-2016122260-A1 · May 5, 2016 · US
US9783461B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9783461-B2 |
| Application number | US-201514919591-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 21, 2015 |
| Priority date | Nov 4, 2014 |
| Publication date | Oct 10, 2017 |
| Grant date | Oct 10, 2017 |
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Provided is an improved process for olefin oligomerization allowing one to realize superior selectivity. The process comprises contacting a hydrocarbon feed comprised of straight and branched chain olefins under oligomerization conditions with a catalyst comprising delaminated SSZ-70. The delaminated SSZ-70 offers a zeolite layer with a single unit cell of thickness in one dimension, allowing for elimination of mass transfer in comparison with regular SSZ-70. The result is superior selectivity.
Opening claim text (preview).
What is claimed is: 1. An oligomerization process comprising reacting an olefin feed comprising at least one olefin having from 2 to 21 carbon atoms under oligomerization conditions with a catalyst comprising delaminated SSZ-70 having a layer with a single unit cell of thickness in one dimension. 2. The process of claim 1 , wherein the olefin feed comprises straight and branched chain olefins. 3. The process of claim 1 , wherein the olefin feed comprises ethylene. 4. The process of claim 1 , wherein the oligomerization conditions include a temperature in a range of from 0° C. to 500° C. 5. The process of claim 1 , wherein the catalyst further comprises at least one transition metal. 6. The process of claim 5 , wherein the catalyst comprises at least one Group VIII metal. 7. The process of claim 1 , wherein the delaminated SSZ-70 is a delaminated Al-SSZ-70 material. 8. The process of claim 1 , wherein the delaminated SSZ-70 is a delaminated B-SSZ-70 material. 9. The process of claim 1 , wherein a product comprising a mixture of alpha-olefins containing from 4 to 54 carbon atoms is recovered. 10. The process of claim 1 , wherein the reaction is conducted in the liquid phase.
Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation · CPC title
Acid treatment · CPC title
Reaction with organic or organometallic compounds · CPC title
to destroy the molecular sieve structure or part thereof · CPC title
not in framework positions · CPC title
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