Highly thermal conductive nanocomposites

Patent metadata

Field	Value
Publication number	US-9783424-B2
Application number	US-201414311775-A
Country	US
Kind code	B2
Filing date	Jun 23, 2014
Priority date	Aug 6, 2008
Publication date	Oct 10, 2017
Grant date	Oct 10, 2017

Abstract

Disclosed are methods for forming carbon-based fillers as may be utilized in forming highly thermal conductive nanocomposite materials. Formation methods include treatment of an expanded graphite with an alcohol/water mixture followed by further exfoliation of the graphite to form extremely thin carbon nanosheets that are on the order of between about 2 and about 10 nanometers in thickness. Disclosed carbon nanosheets can be functionalized and/or can be incorporated in nanocomposites with extremely high thermal conductivities. Disclosed methods and materials can prove highly valuable in many technological applications including, for instance, in formation of heat management materials for protective clothing and as may be useful in space exploration or in others that require efficient yet light-weight and flexible thermal management solutions.

First claim

What is claimed is:

1. A composite material comprising
a polymeric matrix comprising poly(vinyl alcohol); and
a plurality of carbon nanosheets incorporated in the matrix, the carbon nanosheets having a thickness of between about 2 and about 10 nanometers, the carbon nanosheets including a functional compound bonded to the carbon nanosheets, wherein the functional compound is a polypeptide.

2. The composite material of claim 1 , the composite material including between about 20 vol. % and about 35 vol. % of the carbon nanosheets.

3. The composite material of claim 1 , wherein the polypeptide is a functional protein fragment or an entire protein.

4. The composite material of claim 1 , wherein the functional compound is covalently bonded to the carbon nanosheets.

5. The composite material of claim 1 , wherein the plurality of carbon nanosheets comprise carboxylic acid moieties, and wherein the functional compound is bonded to the carboxylic acid moieties.

6. The composite material of claim 5 , wherein the functional compound is covalently bonded.

7. The composite material of claim 5 , wherein the functional compound is noncovalently bonded.

8. The composite material of claim 1 , wherein the plurality of carbon nanosheets comprise carboxylic acid moieties, and wherein the carboxylic acid moiety population of the carbon nanosheets is about 2 mole %.

9. The composite material of claim 1 , the composite including up to about 80% by weight of the carbon nanosheets.

10. The composite material of claim 1 , the composite material including between about 5 vol. % and about 50 vol. % of the carbon nanosheets.

11. The composite material of claim 1 , the material exhibiting a crossplane thermal diffusivity that is between about one-tenth and about one-fifth of the average in-plane thermal diffusivity.

12. The composite material of claim 1 , the composite including up to 80% by weight of the carbon nanosheets.

13. The composite material of claim 1 , the composite material including between 5 vol. % and 50 vol. % of the carbon nanosheets.

14. The composite material of claim 1 , the material exhibiting a cross-plane thermal diffusivity that is between one-tenth and one-fifth of the average in-plane thermal diffusivity.

15. The composite material of claim 1 , the composite material including between 20 vol. % and 35 vol. of the carbon nanosheets.

Assignees

• Nasa
• Nasa

Inventors

• Sun Ya-Ping
• Connell John W
• Veca Lucia Monica

Classifications

• C09K5/14 Primary

  Solid materials, e.g. powdery or granular · CPC title

• C08K2201/011

  Nanostructured additives · CPC title

• C08K9/04

  Ingredients treated with organic substances {(treated with macromolecular compounds C08K9/08)} · CPC title

• C01B32/152 Primary

  Fullerenes · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title