Clay mineral supported catalysts

Patent metadata

Field	Value
Publication number	US-9782751-B2
Application number	US-201615205301-A
Country	US
Kind code	B2
Filing date	Jul 8, 2016
Priority date	May 9, 2013
Publication date	Oct 10, 2017
Grant date	Oct 10, 2017

Abstract

Disclosed is a hydrocarbon gas reforming supported catalyst, and methods for its use, that includes a catalytic material capable of catalyzing the production of a gaseous mixture comprising hydrogen (H 2 ) and carbon monoxide (CO) from a hydrocarbon gas and a clay support material comprising a clay mineral, wherein the catalytic material is chemically bonded to the clay support material, and wherein the chemical bond is a M1-M2 bond, where M1 is a metal from the catalytic material and M2 is a metal from the clay support material, or the chemical bond is a M1-O bond, where M1 is a metal from the catalytic material and oxygen (O) is from the clay support material, wherein the supported catalyst comprises at least 70% or more by weight of the clay support material.

First claim

The invention claimed is:

1. A hydrocarbon gas reforming supported catalyst comprising:
(a) a catalytic material capable of catalyzing the production of a gaseous mixture comprising hydrogen (H 2 ) and carbon monoxide (CO) from a hydrocarbon gas; and
(b) a clay support material comprising a clay mineral,
wherein the catalytic material is chemically bonded to the clay support material, and wherein the chemical bond is a M1-M2 bond, where M1 is a metal from the catalytic material and M2 is a metal from the clay support material, or the chemical bond is a M1-O bond, where M1 is a metal from the catalytic material and oxygen (O) is from the clay support material,
wherein the supported catalyst comprises at least 70% or more by weight of the clay support material.

2. The hydrocarbon gas reforming supported catalyst of claim 1 , wherein the clay mineral comprises a 1:1 silicate layer or 2:1 silicate layer.

3. The hydrocarbon gas reforming supported catalyst of claim 2 , wherein the clay mineral comprises a 1:1 silicate layer.

4. The hydrocarbon gas reforming supported catalyst of claim 3 , wherein the clay mineral is a kaolin mineral.

5. The hydrocarbon gas reforming supported catalyst of claim 4 , wherein the kaolin mineral is kaolinite.

6. The hydrocarbon gas reforming supported catalyst of claim 1 , wherein the supported catalyst comprises at least 80% or more by weight of the clay support material.

7. The hydrocarbon gas reforming supported catalyst of claim 6 , further comprising at least 1%, or more by weight of the catalytic material.

8. The hydrocarbon gas reforming supported catalyst of claim 1 , wherein the clay support material is in particulate or powdered form.

9. The hydrocarbon gas reforming supported catalyst of claim 8 , wherein the particle size of the clay support material ranges from 5 to 300 μm.

10. The hydrocarbon gas reforming supported catalyst of claim 1 , wherein the clay support material is in non-powdered form or has a fabricated geometry.

11. The hydrocarbon gas reforming supported catalyst of claim 10 , wherein the fabricated geometry is a pellet, foam, honeycomb, or monolith.

12. The hydrocarbon gas reforming supported catalyst of claim 1 , wherein the catalytic material is a metal catalyst or metal oxide catalyst comprising Pt, Pd, Au, Ag, Ir, Ni, Co, Rh, Ru, La, Mg, Ca, Sr, Ba, Li, Na, K, Fe, Sn, Cu, Zn, Zr, Mo, Nb, Bi, or Mn, or any combination thereof.

13. The hydrocarbon gas reforming supported catalyst of claim 12 , wherein the metal catalyst comprises Ni, Pt, Rh, or Ru or any combination thereof.

14. The hydrocarbon gas reforming supported catalyst of claim 1 , wherein the clay mineral is a purified or isolated clay mineral or a synthetic clay mineral.

15. The hydrocarbon gas reforming supported catalyst of claim 1 , wherein the supported catalyst comprises at least 1%, or more by weight of the catalytic material.

16. The hydrocarbon gas reforming supported catalyst of claim 1 , wherein the catalytic material is dispersed on the surface of the clay support material.

17. The hydrocarbon gas reforming supported catalyst of claim 1 , wherein the catalytic material comprises a pyrochlore of:
A x B y−z C z O 7
wherein, A is a trivalent ion of an element of La, Ce, Nd, Bi, Sc, or Y, where 0≦x≦2, B is a tetravalent ion of an element of Zr, Pt, Pd, Ni, Mo, Rh, Ru, or Ir, where 0≦y−z≦2, C is a bivalent, trivalent or tetravalent ion of Ba, Ca, Cu, Mg, Ru, Rh, Pt, Pd, Ni, Co, or Mo, where 0≦z≦2.

18. The hydrocarbon gas reforming supported catalyst of claim 1 , wherein the catalytic material comprises La 2 Ni 0.11 Zr 1.89 O 7 or La 2 Rh 0.11 Zr 1.85 O 7 and the clay support material comprises kaolinite.

19. A method of producing the hydrocarbon gas reforming supported catalyst of claim 1 comprising obtaining a composition comprising:
(a) a continuous phase comprising a solvent and a catalytic material capable of catalyzing the production of a gaseous mixture comprising hydrogen (H 2 ) and carbon monoxide (CO) from a hydrocarbon gas, wherein the catalytic material is solubilized in the solvent; and
(b) a dispersed phase comprising a clay mineral in powdered or particulate form; and
evaporating the solvent from said composition, wherein the hydrocarbon gas reforming supported catalyst is produced, and wherein the catalytic material is chemically bonded to the support material, and wherein the chemical bond is a M1-M2 bond, where M1 is a metal from the catalytic material and M2 is a metal from the clay support material, or the chemical bond is a M1-O bond, where M1 is a metal from the catalytic material and oxygen (O) is from the clay support material.

20. A method of catalytically reforming a reactant gas mixture comprising:
(a) providing a reactant gas mixture comprising a hydrocarbon and an oxidant;
(b) providing the hydrocarbon gas reforming supported catalyst of claim 1 ; and
(c) contacting the reactant gas mixture with the hydrocarbon gas reforming supported catalyst under conditions sufficient to produce a gaseous mixture comprising hydrogen (H 2 ) and carbon monoxide (CO).

Assignees

• Sabic Global Technologies Bv

Inventors

• D'Souza Lawrence
• Viswanath Vinu

Classifications

• B01J2235/15

  X-ray diffraction · CPC title

• B01J35/735

  Pyrochlore-type A2B2O7 · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/50

  characterised by their shape or configuration · CPC title

• B01J23/63

  with rare earths or actinides · CPC title