Non-dispersive process for oil recovery

Patent metadata

Field	Value
Publication number	US-9782726-B2
Application number	US-201313918766-A
Country	US
Kind code	B2
Filing date	Jun 14, 2013
Priority date	Jan 15, 2010
Publication date	Oct 10, 2017
Grant date	Oct 10, 2017

Abstract

A method of recovering one or more insoluble oils from a liquid source using one or more membrane or membrane contactors, comprising the steps of: pumping the liquid source comprising the one or more oils to the membranes or membrane contactors, contacting the liquid source with a first surface of the membrane or membrane contactors, coalescing the one or more oils within the liquid source onto the first surface of the membrane contactors, pumping one or more recovery fluids through the membrane or membrane contactors in contact with the second surface of the membrane or membrane contactors, and removing a first stream of oil coalesced from the second surface of the membranes or membrane contactors.

First claim

What is claimed is:

1. A method of recovering one or more insoluble oils from an aqueous mixture using one or more membrane contactors, comprising the steps of:
pumping, from a growth environment, the aqueous mixture comprising the one or more insoluble oils into contact with a first surface of the one or more membrane contactors, wherein the aqueous mixture does not contain an amount of solvent sufficient to disperse the insoluble oils, and wherein the aqueous mixture comprises one or more organisms that include at least one of intact cells, lysed cells, apoptotic cells, necrotic cells, wherein the aqueous mixture comprises two or more different organisms, wherein the aqueous mixture comprises a yeast, algae or bacteria, or wherein the aqueous mixture comprises organisms capable of secreting oil or causing accumulation of oil outside living cells;
coalescing the one or more insoluble oils from the aqueous mixture onto the first surface of the one or more membrane contactors, wherein the one or more membrane contactors are filed with a recovery fluid coalescing the one or more insoluble oils;
collecting a stream of coalesced insoluble oil from a second surface of the one or more membrane contactors, wherein the stream comprises coalesced insoluble oil and the recovery fluid; and
returning the aqueous mixture to the growth environment after the one or more insoluble oils are separated from the aqueous mixture.

2. The method of claim 1 , wherein the aqueous mixture is subjected to the pumping within 1, 2, 4, 6, 8, 12, 24, 26, 48 or 72 hours from production.

3. The method of claim 1 , wherein the aqueous mixture comprises one or more organisms that are genetically modified to render them capable of secreting hydrophobic components, one or more organisms that are capable of causing accumulation of the hydrophobic components outside living cells, or one or more organisms that are capable of causing accumulation of the hydrophobic components outside living cells upon induction with one or more chemical probes, exogenous agents, or pharmaceuticals, or combinations thereof.

4. The method of claim 1 , further comprising:
contacting the one or more organisms with chemical probes, exogenous agents, or pharmaceuticals, whereby a metabolism of the one or more organisms is modified, and wherein at least one organism causes accumulation of the one or more insoluble oils outside living cells.

5. The method of claim 1 , wherein 45%, 50%, 55%, 60%, 65%, 70%, 75%, 80%, 85%, 90%, 95%, 98%, 99% or 100% of the one or more insoluble oils in the aqueous mixture are recovered.

6. The method of claim 1 , wherein returning the aqueous mixture to the growth environment includes returning the one or more organisms to the growth environment to for oil production.

7. The method of claim 1 , wherein the one or more membrane contactors comprise a material selected from at least one of polyethylene, polypropylene, polyolefins, polyvinyl chloride (PVC), amorphous Polyethylene terephthalate (PET), polyolefin copolymers, poly(etheretherketone) type polymers, surface modified polymers, or surface modified polymers comprising polymers modified chemically at one or more halogen groups by corona discharge or by ion embedding techniques.

8. The method of claim 1 , wherein the stream comprising the coalesced insoluble oil and the recovery fluid is not counterflowing.

9. The method of claim 1 , wherein the recovery fluid comprises previously coalesced insoluble oil.

10. A method of recovering one or more insoluble oils from an aqueous mixture using one or more membrane contactors, comprising the steps of:
pumping the aqueous mixture comprising the one or more insoluble oils into contact with a first surface of the one or more membrane contactors, wherein the aqueous mixture does not contain an amount of solvent sufficient to disperse the insoluble oils and
wherein the aqueous mixture comprises one or more organisms that include at least one of intact cells, lysed cells, apoptotic cells, necrotic cells, or
wherein the aqueous mixture comprises two or more different organisms, wherein at least one of the organisms produces oil, or
wherein the aqueous mixture comprises a yeast, algae or bacteria, or
wherein the aqueous mixture comprises organisms capable of secreting oil or causing accumulation of oil outside living cells, or
wherein the aqueous mixture comprises one or more organisms that are genetically modified to render them capable of secreting hydrophobic components, or
wherein the aqueous mixture comprises one or more organisms that are capable of causing accumulation of the hydrophobic components outside living cells, or
wherein the aqueous mixture comprises one or more organisms that are capable of causing accumulation of hydrophobic components outside living cells upon induction with one or more chemical probes, exogenous agents, or pharmaceuticals, or combinations thereof;

coalescing the one or more insoluble oils from the aqueous mixture onto the first surface of the one or more membrane contactors, wherein the one or more membrane contactors are filled with a recovery fluid coalescing the oils; and
collecting a stream of coalesced insoluble oil from a second surface of the one or more membrane contactors, wherein the stream comprises coalesced insoluble oil and the recovery fluid.

11. The method of claim 10 , further comprising:
contacting the one or more organisms with chemical probes, exogenous agents, or pharmaceuticals, whereby a metabolism of the one or more organisms is modified, and wherein at least one organism causes accumulation of the one or more insoluble oils outside living cells.

12. The method of claim 10 , wherein the stream comprising the coalesced insoluble oil and the recovery fluid is not counterflowing.

13. The method of claim 10 , wherein the recovery fluid comprises previously coalesced insoluble oil.

14. A method of recovering one or more insoluble oils from an aqueous mixture using one or more membrane contactors, comprising the steps of:
pumping the aqueous mixture comprising the one or more insoluble oils from a growth environment for organisms including algae, bacteria or yeast, wherein the aqueous mixture does not contain an amount of solvent sufficient to disperse the insoluble oils;
contacting a first surface of the one or more membrane contactors with the aqueous mixture, wherein the aqueous mixture comprises a growth media and the one or more insoluble oils produced by the growth environment;
coalescing the one or more insoluble oils from the aqueous mixture onto the first surface of the one or more membranes or membrane contactors, wherein the one or more membrane contactors are filled with a recovery fluid coalescing the one or more insoluble oils;
removing a first stream from the one or more membrane contactors, wherein the first stream comprises the growth media and organisms, wherein the organisms can continue to produce the one or more insoluble oils; and
removing a second stream from a second surface of one or more membrane contactors, wherein the second stream comprises the one or more insoluble oils and the recovery fluid.

15. The method of claim 14 , further comprising feeding or pumping the first stream to the growth environment to for oil production by the organisms.

16. The method of claim 14 , wherein the one or more membrane contactors comprise a material selected from at least one of polyethylene, polypropylene, polyolefins, polyvinyl chloride (PVC), amorphous Polyethylene terephthalate (PET), polyolefin copolymers, poly(etheretherketone) type polymers, surface modi

Assignees

• Univ Texas
• Organic Fuels Algae Tech Llc

Inventors

• Seibert Frank
• Truscott Stacy S
• Briggs Stephen William
• Kipp Peter B

Classifications

• C11B3/001

  by a combination of two or more of the means hereafter · CPC title

• B01D63/02 Primary

  Hollow fibre modules · CPC title

• C11B3/006

  by extraction · CPC title

• C11B1/04

  of vegetable raw material {(C11B1/025 takes precedence)} · CPC title

• C11B1/02

  Pretreatment · CPC title