Nitrous oxide decomposition catalyst

Patent metadata

Field	Value
Publication number	US-9782722-B2
Application number	US-201414908142-A
Country	US
Kind code	B2
Filing date	Jul 29, 2014
Priority date	Jul 31, 2013
Publication date	Oct 10, 2017
Grant date	Oct 10, 2017

Abstract

The present invention provides a catalyst for the decomposition of nitrous oxide, said catalyst comprising oxides of cobalt, zinc and aluminum and an alkali metal promoter.

First claim

That which is claimed is:

1. A catalyst for the decomposition of nitrous oxide, said catalyst comprising oxides of cobalt, zinc, and aluminium and an alkali metal promoter, wherein the catalyst is in the form of an extrudate and has a side crush strength in the range of from 2 to 40 N/mm.

2. The catalyst of claim 1 , wherein the alkali metal promoter is present in at least 0.1 wt % based on the overall weight of the catalyst.

3. The catalyst of claim 1 , wherein the alkali metal promoter is selected from potassium, cesium and mixtures thereof.

4. The catalyst of claim 1 , wherein the catalyst further comprises a binder, selected from the group of alkaline earth metal oxides, rare earth metal oxides, alumina, zinc oxide, magnesium oxide, silica and mixtures thereof.

5. The catalyst of claim 1 , wherein the cobalt is present in an amount of at least 20 and at most 75 wt % based on the overall weight of the catalyst.

6. The catalyst of claim 1 , wherein the zinc is present in an amount of at least 3 and at most 20 wt % based on the overall weight of the catalyst.

7. The catalyst of claim 1 , wherein the aluminum, excluding any aluminum present in the binder, is present in an amount of at least 2 and at most 20 wt % based on the overall weight of the catalyst.

8. A catalyst for the decomposition of nitrous oxide, said catalyst comprising oxides of cobalt, zinc, and aluminium and an alkali metal promoter, wherein the catalyst is in the form of a tablet and has a top crush strength (based on a 3 mm×3 mm tablet) in the range of from at least 40 N/tablet to at most 300 N/tablet.

9. The catalyst of claim 8 , wherein the alkali metal promoter is present in at least 0.1 wt % based on the overall weight of the catalyst.

10. The catalyst of claim 8 , wherein the alkali metal promoter is selected from potassium, cesium and mixtures thereof.

11. The catalyst of claim 8 , wherein the catalyst further comprises a binder, selected from the group of alkaline earth metal oxides, rare earth metal oxides, alumina, zinc oxide, magnesium oxide, silica and mixtures thereof.

12. The catalyst of claim 8 , wherein the cobalt is present in an amount of at least 20 and at most 75 wt % based on the overall weight of the catalyst.

13. The catalyst of claim 8 , wherein the zinc is present in an amount of at least 3 and at most 20 wt % based on the overall weight of the catalyst.

14. The catalyst of claim 8 , wherein the aluminum, excluding any aluminum present in the binder, is present in an amount of at least 2 and at most 20 wt % based on the overall weight of the catalyst.

Assignees

• Shell Oil Co

Inventors

• Gopal Srikant
• Klemt Andreas
• Schricker Ralf
• Panchagnula Madhusudhan Rao

Classifications

• B01D2255/2092

  Aluminium · CPC title

• B01D2255/202

  Alkali metals · CPC title

• B01D2258/0283

  Flue gases · CPC title

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• B01J2523/00

  Constitutive chemical elements of heterogeneous catalysts · CPC title