Degradant concentration measurement device and acidic gas removal device

Patent metadata

Field	Value
Publication number	US-9782720-B2
Application number	US-201314370891-A
Country	US
Kind code	B2
Filing date	Feb 8, 2013
Priority date	Mar 9, 2012
Publication date	Oct 10, 2017
Grant date	Oct 10, 2017

Abstract

A degradant concentration measurement device 14 according to the invention has an electric conductivity measurement instrument 71 A measuring the electric conductivity of a lean solution 16 that is an acidic gas-absorbing solution and detection means 72 obtaining the concentration of a degradant contained in a lean solution 16 from the measured electric conductivity of the lean solution 16 based on the relationship between the previously-obtained electric conductivity of the lean solution 16 and the concentration of the degradant contained in the lean solution 16.

First claim

The invention claimed is:

1. An acidic gas removal device, comprising:
an absorption tower in which supply gas supplied to the acidic gas removal device and containing an acidic gas component is brought into contact with an acidic gas-absorbing solution so as to absorb and remove the acidic gas component;
an absorbing solution-regeneration tower in which the acidic gas-absorbing solution absorbing the acidic gas component in the absorption tower is regenerated so as to produce a lean solution; and
a degradant concentration measurement device comprising:
an electric conductivity measurement instrument for measuring an electric conductivity of the acidic gas-absorbing solution that absorbs the acidic gas component contained in the supply gas to the acidic gas removal device, then, is regenerated, circulated again and used; and
detection device for obtaining a concentration of degradant contained in the acidic gas-absorbing solution from the measured electric conductivity of the acidic gas-absorbing solution based on a previously obtained relationship between an electric conductivity of the acidic gas-absorbing solution and a concentration of the degradant contained in the acidic gas-absorbing solution,

wherein a lean solution supply line supplying the lean solution to the absorption tower from the absorbing solution-regeneration tower is provided, an electric conductivity of the lean solution is measured, and a concentration of a degradant is detected, and
wherein the acidic gas removal device further comprises:
a lean solution branching line that extracts some of the lean solution from the lean solution supply line; and
a reclaimer that separates and removes a degradant in the lean solution extracted into the lean solution branching line by distillation using a boiling point difference.

2. The acidic gas removal device according to claim 1 ,
wherein a rich and lean solution heat exchanger exchanging heat between the lean solution and a rich solution is provided in the lean solution supply line, and
the electric conductivity measurement instrument of the degradant concentration measurement device is provided between the heat exchanger and the absorption tower in the lean solution supply line.

3. The acidic gas removal device according to claim 1 ,
wherein an absorbing solution tank for storing the lean solution is provided in the lean solution supply line, and
the degradant concentration measurement device is provided in the absorbing solution tank.

4. The acidic gas removal device according to claim 1 ,
wherein a rich and lean solution heat exchanger exchanging heat between the lean solution and a rich solution is provided in the lean solution supply line, and
the electric conductivity measurement instrument of the degradant concentration measurement device is provided between the heat exchanger and the absorption tower in the lean solution supply line.

5. The acidic gas removal device according to claim 1 , comprising:
control means for controlling at least any one of starting and stopping of an operation of the reclaimer and a supply flow rate of the lean solution supplied to the reclaimer based on the electric conductivity of the lean solution measured in the degradant concentration measurement device.

6. The acidic gas removal device according to claim 5 ,
wherein the control means starts the operation of the reclaimer in a case in which the electric conductivity of the lean solution measured in the degradant concentration measurement device is in a range of 1 mS/cm to 30 mS/cm.

7. The acidic gas removal device according to claim 5 ,
wherein a rich and lean solution heat exchanger exchanging heat between the lean solution and a rich solution is provided in the lean solution supply line, and
the electric conductivity measurement instrument of the degradant concentration measurement device is provided between the heat exchanger and the absorption tower in the lean solution supply line.

8. The acidic gas removal device according to claim 5 ,
wherein the control means
determines whether or not the electric conductivity of the lean solution measured in the degradant concentration measurement device is equal to or less than a prescribed value so as to determine whether or not to start the operation of the reclaimer, and,
after the starting of the operation of the reclaimer, determines whether or not the electric conductivity of the lean solution in the reclaimer measured in the degradant concentration measurement device is equal to or more than the prescribed value so as to determine the operation of the reclaimer.

9. The acidic gas removal device according to claim 8 ,
wherein the control means starts the operation of the reclaimer in a case in which the electric conductivity of the lean solution measured in the degradant concentration measurement device is in a range of 1 mS/cm to 30 mS/cm.

10. The acidic gas removal device according to claim 8 ,
wherein a rich and lean solution heat exchanger exchanging heat between the lean solution and a rich solution is provided in the lean solution supply line, and
the electric conductivity measurement instrument of the degradant concentration measurement device is provided between the heat exchanger and the absorption tower in the lean solution supply line.

11. The acidic gas removal device according to claim 5 ,
wherein the control means
determines whether or not the electric conductivity of the lean solution measured in the degradant concentration measurement device is equal to or less than a prescribed value so as to determine whether or not to start the operation of the reclaimer, and,
after the starting of the operation of the reclaimer, determines whether or not the electric conductivity of the lean solution in the reclaimer measured in the degradant concentration measurement device has a decreasing tendency and adjusts the supply flow rate of the lean solution supplied to the reclaimer.

12. The acidic gas removal device according to claim 11 ,
wherein the control means starts the operation of the reclaimer in a case in which the electric conductivity of the lean solution measured in the degradant concentration measurement device is in a range of 1 mS/cm to 30 mS/cm.

Assignees

• Mitsubishi Heavy Ind Ltd

Inventors

• Yukumoto Atsuhiro
• Horizoe Kouji
• Kato Yudai
• Hirayama Haruaki
• Ishida Kazuo

Classifications

• Y02P20/152

  Cross-Sectional Technologies · mapped topic

• G01N33/0027

  concerning the detector · CPC title

• C10L3/102

  of acid contaminants · CPC title

• B01D53/1475

  Removing carbon dioxide · CPC title

• C10L2290/541

  Absorption of impurities during preparation or upgrading of a fuel · CPC title