Optical element having a coating of high diffusivity

Patent metadata

Field	Value
Publication number	US-9778484-B2
Application number	US-201414270923-A
Country	US
Kind code	B2
Filing date	May 6, 2014
Priority date	May 6, 2013
Publication date	Oct 3, 2017
Grant date	Oct 3, 2017

Abstract

An optical element has a substrate body made from transparent plastic and a coating having multiple layers. The coating includes a hard lacquer layer adjoining the substrate. The coating has a diffusivity ensuring the absorption of water molecules passing through the coating in the substrate and the release of water molecules from the substrate through the coating from an air atmosphere on that side of the coating facing away from the substrate with a flow density which, proceeding from the equilibrium state of the quantity of water molecules absorbed in the substrate in an air atmosphere at 23° C. and 50% relative humidity, brings the setting of the equilibrium state of the quantity of water molecules absorbed in the substrate in an air atmosphere at 40° C. and 95% relative humidity within an interval not more than 10 h longer than for setting this equilibrium under corresponding conditions with an identical uncoated substrate.

First claim

What is claimed is:

1. An optical element comprising:
a substrate body made of a plastic transparent in the visual spectral region;
a coating having a plurality of layers including a hard lacquer layer adjoining said substrate body and further having a first side facing away from said substrate body;
said coating having a diffusivity (D F ) configured to ensure an absorption of water molecules passing through said coating into said substrate body and a release of water molecules from said substrate body through said coating from an air atmosphere arranged on said first side of said coating;
said air atmosphere having a moisture flow density (j D );
said diffusivity (D F ) being further configured to, starting from a first equilibrium state of the amount of water molecules absorbed in said substrate body at an air atmosphere at 23° C. and 50% relative humidity, effect a setting of a second equilibrium state of the amount of water molecules absorbed in said substrate body at an air atmosphere at 40° C. and 95% relative humidity within a first time interval; and,
said first time interval being at most ten hours longer than a second time interval required for a setting of said second equilibrium state starting from said first equilibrium state in an uncoated substrate body identical to said substrate body.

2. The optical element of claim 1 , wherein said hard lacquer layer is treated on said substrate body with a corona discharge.

3. The optical element of claim 1 , wherein said hard lacquer layer is treated on said substrate body with a low-pressure air plasma.

4. The optical element of claim 1 , wherein said hard lacquer layer is treated on said substrate body with a glow discharge.

5. The optical element of claim 1 , wherein said hard lacquer layer is made with a sol-gel hard lacquer composition including a fluorosurfactant as a flow control additive.

6. An optical element comprising:
a substrate body made of a plastic transparent in the visual spectral region;
a coating having a plurality of layers including a hard lacquer layer adjoining said substrate body and further having a first side facing away from said substrate body;
said coating having a diffusivity (D F ) configured to ensure an absorption of water molecules passing through said coating into said substrate body and a release of water molecules from said substrate body through said coating from an air atmosphere arranged on said first side of said coating;
said air atmosphere having a moisture flow density (j D );
said diffusivity (D F ) being further configured to, starting from a first equilibrium state of the amount of water molecules absorbed in said substrate body at an air atmosphere at 23° C. and 50% relative humidity, effect a setting of a second equilibrium state of the amount of water molecules absorbed in said substrate body at an air atmosphere at 40° C. and 95% relative humidity within a first time interval;
said first time interval being at most ten hours longer than a second time interval required for a setting of said second equilibrium state starting from said first equilibrium state in an uncoated substrate body identical to said substrate body;
wherein said hard lacquer layer is treated on said substrate body with a corona discharge or a low-pressure air plasma or a glow discharge, or wherein said hard lacquer layer is made with a sol-gel hard lacquer composition including a fluorosurfactant as a flow control additive;
said coating includes at least one anti-reflection coating having at least one part-layer which was vapor deposited in a vacuum chamber; and,
said part-layer being compressed via ion bombardment.

7. The optical element of claim 6 , wherein said first time interval is at most nine, eight, seven, six, five, four, three or two hours longer than the second time interval.

8. The optical element of claim 6 , wherein said first time interval is at most one hour longer than the second time interval.

9. The optical element of claim 6 , wherein said coating has a scratch-resistance corresponding to a Bayer value (Z B ) as determined in an expanded Bayer-test characterizing the scratch resistance of said coating, wherein Z B ≧8.

10. The optical element of claim 9 , wherein Z B ≧14.

11. The optical element of claim 6 , wherein said part-layer is compressed via an ion bombardment at I≧30 μA/cm 2 at the location of the part-layer during the duration of a vapor depositing process for generating said part-layer.

12. The optical element of claim 6 , wherein said coating includes at least one of a quartz layer made essentially of SiO 2 with a layer thickness d≧100 nm and a mixed layer made of SiO 2 and Al 2 O 3 with a layer thickness d≧100 nm.

13. The optical element of claim 6 , wherein said coating has a plurality of pores.

14. The optical element of claim 13 , wherein said pores are at least one of microscopic and mesoscopic.

15. The optical element of claim 13 , wherein:
said coating defines a coating surface at said first side; and,
said pores are configured as holes extending from said coating surface at least to said hard lacquer layer.

16. The optical element of claim 15 , wherein said holes have a diameter DL≦5 μm.

17. The optical element of claim 15 , wherein said holes have a diameter DL≦0.2 μm.

18. The optical element of claim 14 , wherein said pores are arranged irregularly in said coating.

19. The optical element of claim 14 , wherein said pores are arranged in a translationally symmetrical manner with a spatial frequency (k) and said spatial frequency (k) is at least one of k>>1/400 nm and k<<1/800 nm.

20. The optical element of claim 14 , wherein said mesoscopic pores are made by an application of a particle beam to at least one of said coating and at least one of said layers of said coating.

21. The optical element of claim 20 , wherein said particle beam includes at least one of noble gas atoms, carbon atoms and gold atoms.

22. The optical element of claim 14 , wherein said mesoscopic pores are made by an application of pulsed laser light to at least one of said coating and at least one of said layers of said coating.

23. The optical element of claim 6 , wherein said plurality of layers includes at least one interior layer, the optical element further including:
foreign matter deposited on at least one of said interior layer and said hard lacquer layer; and,
said foreign matter being at least one of foreign molecules and nano-particles.

24. The optical element of claim 6 , wherein said plurality of layers includes at least one interior layer, the optical element further including:
a foreign structure applied to at least one of said interior layer and said hard lacquer layer.

25. A method for making an optical element or component comprising the steps of:
providing a substrate body made from a transparent plastic;
applying a coating having a plurality of layers on the substrate body, the coating including a hard lacquer layer which adjoins the substrate body and is generated by applying a sol-gel hard lacquer composition onto the substrate body, the coating having a further optical layer configured as at least a part-layer of an antireflection coating and arranged on the hard lacquer layer; and,
at least one of:
depositing foreign structures on the hard lacquer layer prior to the application of the further optical layer;
attaching foreign structures to an interior layer of the coating via at l

Assignees

• Zeiss Carl Vision Int Gmbh

Inventors

• Hugenberg Norbert
• Haidl Markus
• Von Blanckenhagen Bernhard
• Holz Lothar
• Kraus Stefan
• Macionczyk Frank
• Krause Michael
• Green Erwin
• Winter Karl-Heinz
• Gloege Thomas
• Faul Silvia
• Petereit Anja
• Peng Bin
• Puetz Joerg
• Kiefer Patrick
• Hanssen Adalbert
• Krieger Michael
• Neuffer Andreas
• Stroisch Marc

Classifications

• B29D11/00432

  Auxiliary operations, e.g. machines for filling the moulds (B29D11/00125 takes precedence) · CPC title

• B29D11/00009

  Production of simple or compound lenses · CPC title

• B29D11/00865

  Applying coatings; tinting; colouring (printing, marking or copying processes B41M; identification in general G09F3/00; producing decorative effects in general B44C; positioning or marking of lenses B24B13/0055) · CPC title

• G02C7/02 Primary

  Lenses; Lens systems {; Methods of designing lenses} · CPC title

• G02C7/022

  Ophthalmic lenses having special refractive features achieved by special materials or material structures (G02C7/049 takes precedence) · CPC title