Systems and methods for determining combustion properties of wellhead gas

Patent metadata

Field	Value
Publication number	US-9778237-B2
Application number	US-201514631036-A
Country	US
Kind code	B2
Filing date	Feb 25, 2015
Priority date	Feb 27, 2014
Publication date	Oct 3, 2017
Grant date	Oct 3, 2017

Abstract

Disclosed are methods, systems, and computer-readable mediums for determining combustion properties of wellhead gas. A methane concentration of a gas mixture is measured. A non-methane hydrocarbon concentration of the gas mixture is measured. An inert concentration of the gas mixture is calculated. A first surrogate for the non-methane hydrocarbon concentration is selected, where the first surrogate is selected as propane if the methane concentration is greater than a first threshold, and where the first surrogate is selected as pentane if the methane concentration is less than or equal to the first threshold. A methane number of the gas mixture is determined, where the methane number is based on the methane concentration, the first surrogate, and the inert concentration.

First claim

What is claimed is:

1. A method comprising:
measuring a methane concentration of a gas mixture;
measuring a non-methane hydrocarbon concentration of the gas mixture;
calculating an inert concentration of the gas mixture;
selecting a first surrogate for the non-methane hydrocarbon concentration; and
determining, using a computing device, a methane number of the gas mixture, wherein the methane number is based on the methane concentration, the first surrogate, and the inert concentration;
wherein the first surrogate is selected as propane if the methane concentration is greater than a first threshold, and wherein the first surrogate is selected as pentane if the methane concentration is less than or equal to the first threshold.

2. The method of claim 1 , wherein the first threshold is 50 percent.

3. The method of claim 1 , further comprising:
selecting a second surrogate for the non-methane hydrocarbon concentration; and
determining, using the computing device, a lower heating value of the gas mixture, wherein the lower heating value is based on the methane concentration, the second surrogate, and the inert concentration.

4. The method of claim 3 , wherein the second surrogate is selected as a combination of ethane and propane when the methane concentration is greater than a second threshold, and wherein the second surrogate is selected as pentane when the methane concentration is less than or equal to the second threshold.

5. The method of claim 4 , wherein the second threshold is 20 percent.

6. The method of claim 4 , wherein the combination of ethane and propane comprises 30 percent ethane and 70 percent propane.

7. The method of claim 1 , wherein the gas mixture comprises internal combustion engine gas.

8. A system comprising:
one or more computing devices configured to:
measure a methane concentration of a gas mixture;
measure a non-methane hydrocarbon concentration of the gas mixture;
calculate an inert concentration of the gas mixture;
select a first surrogate for the non-methane hydrocarbon concentration; and
determine a methane number of the gas mixture, wherein the methane number is based on the methane concentration, the first surrogate, and the inert concentration;
wherein the first surrogate is selected as propane if the methane concentration is greater than a first threshold, and wherein the first surrogate is selected as pentane if the methane concentration is less than or equal to the first threshold.

9. The system of claim 8 , wherein the one or more computing devices are further configured to:
select a second surrogate for the non-methane hydrocarbon concentration; and
determine a lower heating value of the gas mixture, wherein the lower heating value is based on the methane concentration, the second surrogate, and the inert concentration.

10. The system of claim 9 , wherein the second surrogate is selected as a combination of ethane and propane when the methane concentration is greater than a second threshold, and wherein the second surrogate is selected as pentane when the methane concentration is less than or equal to the second threshold.

11. The system of claim 10 , wherein the combination of ethane and propane comprises 30 percent ethane and 70 percent propane.

12. A method comprising:
measuring a methane concentration of a gas mixture;
measuring a non-methane hydrocarbon concentration of the gas mixture;
calculating an inert concentration of the gas mixture;
selecting a first surrogate for the non-methane hydrocarbon concentration, wherein the first surrogate is selected as propane if the methane concentration is greater than a first threshold, and wherein the first surrogate is selected as pentane if the methane concentration is less than or equal to the first threshold; and
determining, using a computing device, a methane number of the gas mixture, wherein the methane number is based on the methane concentration, the first surrogate, and the inert concentration;
selecting a second surrogate for the non-methane hydrocarbon concentration, wherein the second surrogate is selected as a combination of ethane and propane when the methane concentration is greater than a second threshold, and wherein the second surrogate is selected as pentane when the methane concentration is less than or equal to the second threshold;
determining a thermal conductivity of an approximated mixture comprising the methane concentration, the second surrogate, and the inert concentration;
determining a difference between the approximated mixture thermal conductivity and a thermal conductivity of the gas mixture;
adjusting the second surrogate based on a third threshold and the difference between the approximated mixture thermal conductivity and the gas mixture thermal conductivity; and
determining, using the computing device, a lower heating value of the gas mixture, wherein the lower heating value is based on the methane concentration, the second surrogate, and the inert concentration.

13. The method of claim 12 , wherein adjusting the second surrogate based on the third threshold and the difference comprises adjusting the second surrogate to be propane.

14. The method of claim 12 , wherein adjusting the second surrogate based on the third threshold and the difference comprises adjusting the second surrogate to be a combination of pentane and hexane.

15. The method of claim 13 , wherein the combination of pentane and hexane comprises 50 percent pentane and 50 percent hexane.

16. The method of claim 12 , wherein adjusting the second surrogate based on the third threshold and the difference comprises adjusting the second surrogate to be a combination of propane and pentane.

17. The method of claim 16 , wherein the combination of propane and pentane comprises 20 percent propane and 80 percent pentane.

18. The method of claim 12 , wherein the third threshold is 10 percent.

Assignees

• Cummins Inc

Inventors

• Li Shu
• Lapointe Leon A
• Gupta Aniket
• Schneider Matthew L

Classifications

• G01N33/0036 Primary

  specially adapted to detect a particular component (physical analysis of gaseous biological material G01N33/497) · CPC title

• G01N33/225 Primary

  Gaseous fuels, e.g. natural gas · CPC title

• G01N25/18

  by investigating thermal conductivity (by calorimetry G01N25/20; by measuring change of resistance of an electrically-heated body G01N27/18) · CPC title