Ionomer resin composition, optical film, polarizing plate, and liquid crystal display apparatus

Patent metadata

Field	Value
Publication number	US-9777092-B2
Application number	US-201514900284-A
Country	US
Kind code	B2
Filing date	May 25, 2015
Priority date	Jun 9, 2014
Publication date	Oct 3, 2017
Grant date	Oct 3, 2017

Abstract

[Objects] Provided is an ionomer resin composition that, when molded into a film shape, is small in both of orientational birefringence and photoelastic birefringence and excellent in transparency, heat resistance, flexibility, and size stability. Additionally, provided are an optical film including the ionomer resin composition, a polarizing plate including the optical film, and a liquid crystal display apparatus including the same.
[Solution] An ionomer resin composition according to the present invention is an ionomer resin composition obtained by reacting an acrylic thermoplastic resin (X) including a chain alkyl (meth)acrylate unit (a), an N-substituted maleimide unit (b), and an unsaturated acid and/or unsaturated acid anhydride unit (c) with a metal compound (Y), in which the acrylic thermoplastic resin (X) includes the chain alkyl (meth)acrylate unit (a), the N-substituted maleimide unit (b), and the unsaturated acid and/or unsaturated acid anhydride unit (c) in a total amount of 80% by mass or more, and contents of the structural units (a), (b), and (c) with respect to 100 parts by mass in total of the acrylic thermoplastic resin (X) except for the unsaturated acid and/or unsaturated acid anhydride unit (c) are from 65 to 87 parts by mass, from 1 to 30 parts by mass, and from 0.1 to 5 parts by mass, respectively.

First claim

The invention claimed is:

1. An ionomer resin composition obtained by reacting an acrylic thermoplastic resin (X) comprising a chain alkyl (meth)acrylate unit (a), an N-substituted maleimide unit (b), and an unsaturated acid and/or unsaturated acid anhydride unit (c) with a metal compound (Y),
wherein the acrylic thermoplastic resin (X) comprises the chain alkyl (meth)acrylate unit (a), the N-substituted maleimide unit (b), and the unsaturated acid and/or unsaturated acid anhydride unit (c) in a total amount of 80% by mass or more; and
wherein the content of the structural unit (a) with respect to 100 parts by mass in total of the acrylic thermoplastic resin (X) is from 65 to 87 parts by mass,
the content of the structural unit (b) with respect to 100 parts by mass in total of the acrylic thermoplastic resin (X) is from 1 to 30 parts by mass, and
the content of the structural unit (c) with respect to 100 parts by mass in total of the acrylic thermoplastic resin (X) is from 0.1 to 5 parts by mass.

2. The ionomer resin composition according to claim 1 , wherein a chain alkyl group in the chain alkyl (meth)acrylate unit (a) has from 1 to 6 carbon atoms.

3. The ionomer resin composition according to claim 1 , wherein the N-substituted maleimide unit (b) includes an N-aromatic group-substituted maleimide unit and/or N-alkyl group-substituted maleimide unit.

4. The ionomer resin composition according to claim 1 , wherein the N-substituted maleimide unit (b) includes an N-phenyl maleimide unit and/or N-cyclohexyl maleimide unit.

5. The ionomer resin composition according to claim 1 , wherein the unsaturated acid and/or unsaturated acid anhydride unit (c) is selected from the group consisting of a (meth)acrylate unit and a maleic anhydride unit.

6. The ionomer resin composition according to claim 1 , wherein the acrylic thermoplastic resin (X) further comprises a structural unit (d) obtained from a monomer represented by the following formula (1):

wherein, in the formula (1), R 1 represents a hydrogen atom or a methyl group, and R 2 represents a group having a cyclic structure.

7. The ionomer resin composition according to claim 6 , wherein R 2 in the formula (1) is a group having an alicyclic structure or a group having an aromatic ring.

8. The ionomer resin composition according to claim 1 , wherein the ionomer resin composition is obtained by reacting 100 parts by mass of the acrylic thermoplastic resin (X) with from 0.01 to 10 parts by mass of the metal compound (Y).

9. The ionomer resin composition according to claim 1 , wherein the metal compound (Y) is at least one selected from the group consisting of an organic acid metal salt, a metal carbonate, and an inorganic acid metal salt.

10. The ionomer resin composition according to claim 1 , wherein the metal compound (Y) is a metal stearate.

11. An optical film comprising the ionomer resin composition according to claim 1 .

12. The optical film according to claim 11 , wherein the optical film is a stretched film obtained by stretching an unstretched film made of a resin material comprising the ionomer resin composition in at least a uniaxial direction.

13. The optical film according to claim 11 , wherein an absolute value of an in-plane phase difference Re with respect to light having a wavelength of from 400 to 800 nm is 10.0 nm or less, and an absolute value of a thickness direction phase difference Rth with respect to the light having the wavelength of from 400 to 800 nm is 10.0 nm or less.

14. The optical film according to claim 11 , wherein an absolute value of a photoelastic coefficient C is 5.0×10 −2 (/Pa) or less.

15. The optical film according to claim 11 , wherein a number of times of folding in MIT folding endurance test, measured based on JIS P8115, is 50 times or more.

16. The optical film according to claim 11 , wherein absolute values of size change rates in an MD direction and a TD direction after allowing the optical film to stand in an atmosphere with 100° C. for 100 hours are 1.00% or less.

17. A polarizing plate comprising the optical film according to claim 11 .

18. A liquid crystal display apparatus comprising the polarizing plate according to claim 17 .

Assignees

• Jx Nippon Oil & Energy Corp

Inventors

• Matsuo Akira
• UCHIZAWA Sayako

Classifications

• G02F1/133528

  Polarisers · CPC title

• C08F2810/50

  wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority · CPC title

• C08K5/098

  Metal salts of carboxylic acids · CPC title

• G02F1/1335

  Structural association of cells with optical devices, e.g. polarisers or reflectors · CPC title

• C08F2800/20

  as weight or mass percentages · CPC title