Method for lignin separation from black liquor

Patent metadata

Field	Value
Publication number	US-9777033-B2
Application number	US-201214385263-A
Country	US
Kind code	B2
Filing date	Mar 16, 2012
Priority date	Mar 16, 2012
Publication date	Oct 3, 2017
Grant date	Oct 3, 2017

Abstract

The method is for separation of lignin from original black liquor (BL IN ) that has a first precipitation phase (PR1/PR2) for precipitation of lignin by a first acidification using acidifier, CO 2 , at alkaline conditions, then separating a lignin cake with subsequent suspension of the lignin cake in a strong acid in order to leach out metals from the lignin followed by dewatering and obtaining a clean lignin product LP. Lignin germ particles (LG) are added to the original black liquor in the first precipitation stage, preferably between two phases in said precipitation stage, in order to increase lignin particle growth on such lignin germ particles instead of spontaneous nucleation of lignin particles in said original black liquor. This results in improved filterability in subsequent dewatering and lignin cake formation and hence an increased lignin yield.

First claim

We claim:

1. A method for separation of lignin from original black liquor having a first pH value, comprising the following phases in sequence:
adding a first acidifier charge to the original black liquor in a first precipitation phase to decrease the first pH value of the original black liquor to a second pH level whereby less than 10% of the total lignin content is precipitated, the second pH level being at least 1 pH unit below that of the first pH value;
adding lignin germ particles to the acidified black liquor after the first precipitation phase to be present during a second precipitation phase;
adding a second acidifier charge to the acidified original black liquor, containing lignin germ particles, from the first precipitation phase in the second precipitation phase to decrease the pH value to a third pH level whereby more than 20% of the total lignin content is additionally precipitated as growth on lignin germ particles added after the first precipitation phase and growth of nucleus particles precipitated in the second precipitation phase, the third pH level being at least 0.1 pH units below that of the second pH value;
wherein the second pH level is above pH 7 and below 11.5;
followed by a separation phase, separating the precipitated lignin as a lignin cake from a remaining liquid phase of the acidified original black liquor; and
the added lignin germ particles increasing lignin particle growth on the lignin germ particles instead of spontaneous nucleation of lignin particles in the acidified black liquor.

2. The method according to claim 1 wherein the lignin germ particles added are at least in part a fraction obtained from the lignin cake.

3. The method according to claim 2 wherein the fraction obtained from the lignin cake is the smaller lignin particles in the lignin cake.

4. The method according to claim 1 wherein the lignin germ particles added are lignin powder having a uniform particle size.

5. The method according to claim 4 wherein the lignin powder has a particle size in the range of 0.1 to 1 millimeter.

Assignees

• Ohman Fredrik
• Theliander Hans
• Tomani Per
• Axegard Peter
• Valmet Oy

Inventors

• Ohman Fredrik
• Theliander Hans
• Tomani Per
• Axegard Peter

Classifications

• C08H8/00 Primary

  Macromolecular compounds derived from lignocellulosic materials {(pretreatment thereof B27N)} · CPC title

• D21C11/04

  of alkali lye · CPC title

• D21C11/0007

  Recovery of by-products, i.e. compounds other than those necessary for pulping, for multiple uses or not otherwise provided for (volatile compounds obtained by decomposition of spent liquors in order to regenerate them D21C11/125; compounds obtained by fractionating the liquors in order to regenerate them D21C11/0042) · CPC title

• Y02E50/10

  Biofuels, e.g. bio-diesel · CPC title

• C08H6/00

  Macromolecular compounds derived from lignin, e.g. tannins, humic acids · CPC title